Cooperative Hydrogen Atom Transfer: From Theory to Applications

The merger of decatungstate and copper catalysis to enable aliphatic C(sp3)–H trifluoromethylation

(2020) Patrick J. Sarver et al.   Nature Chemistry

Photoinduced site-selective alkenylation of alkanes and aldehydes with aryl alkenes

(2020) Hui Cao et al.   Nature Communications

Roles of Iron Complexes in Catalytic Radical Alkene Cross-Coupling: A Computational and Mechanistic Study

(2019) Dongyoung Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Concerted proton-electron transfer reactions in the Marcus inverted region

(2019) Giovanny A. Parada et al.   SCIENCE

Total Synthesis of (+)-Pleuromutilin

(2018) Elliot P. Farney et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Remote C–H Functionalization via Selective Hydrogen Atom Transfer

(2018) David Nagib et al.   SYNTHESIS-STUTTGART

Cobalt bis(acetylacetonate)–tert-butyl hydroperoxide–triethylsilane: a general reagent combination for the Markovnikov-selective hydrofunctionalization of alkenes by hydrogen atom transfer

(2018) Xiaoshen Ma et al.   Beilstein Journal of Organic Chemistry

Direct arylation of strong aliphatic C–H bonds

(2018) Ian B. Perry et al.   NATURE

The High Chemofidelity of Metal-Catalyzed Hydrogen Atom Transfer

(2018) Samantha A. Green et al.   ACCOUNTS OF CHEMICAL RESEARCH

Biocatalytic hydrogen atom transfer: an invigorating approach to free-radical reactions

(2018) Yuji Nakano et al.   CURRENT OPINION IN CHEMICAL BIOLOGY

Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis

(2017) Luca Capaldo et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Development of a Bio-Inspired Dual Catalytic System for Alkane Dehydrogenation

(2017) Julian G. West et al.   ISRAEL JOURNAL OF CHEMISTRY

Fe-Catalyzed C–C Bond Construction from Olefins via Radicals

(2017) Julian C. Lo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Toward a mild dehydroformylation using base-metal catalysis

(2017) Dylan J. Abrams et al.   Chemical Science

Site-Selective C–H Functionalization by Decatungstate Anion Photocatalysis: Synergistic Control by Polar and Steric Effects Expands the Reaction Scope

(2017) Davide Ravelli et al.   ACS Catalysis

Mn-, Fe-, and Co-Catalyzed Radical Hydrofunctionalizations of Olefins

(2016) Steven W. M. Crossley et al.   CHEMICAL REVIEWS

Radical Isomerization and Cycloisomerization Initiated by H• Transfer

(2016) Gang Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Modular Terpenoid Construction via Catalytic Enantioselective Formation of All-Carbon Quaternary Centers: Total Synthesis of Oridamycin A, Triptoquinones B and C, and Isoiresin

(2016) Jiajie Feng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ph(i-PrO)SiH2: An Exceptional Reductant for Metal-Catalyzed Hydrogen Atom Transfers

(2016) Carla Obradors et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tuning Reactivity and Selectivity in Hydrogen Atom Transfer from Aliphatic C–H Bonds to Alkoxyl Radicals: Role of Structural and Medium Effects

(2015) Michela Salamone et al.   ACCOUNTS OF CHEMICAL RESEARCH

Kinetic and Thermodynamic Study of the Reduction of 1,1-Diphenylethylene by a Thermally Frustrated Diethyl Ether-BCF Lewis Pair

(2015) Sean M. Whittemore et al.   ISRAEL JOURNAL OF CHEMISTRY

Practical olefin hydroamination with nitroarenes

(2015) J. Gui et al.   SCIENCE

Non-classical selectivities in the reduction of alkenes by cobalt-mediated hydrogen atom transfer

(2015) Xiaoshen Ma et al.   Chemical Science

Acceptorless dehydrogenation of small molecules through cooperative base metal catalysis

(2015) Julian G. West et al.   Nature Communications

Towards a Practical Development of Light-Driven Acceptorless Alkane Dehydrogenation

(2014) Abhishek Dutta Chowdhury et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Convenient Photocatalytic Fluorination of Unactivated CH Bonds

(2014) Shira D. Halperin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Thiyl Radicals in Organic Synthesis

(2014) Fabrice Dénès et al.   CHEMICAL REVIEWS

The Reaction of Cobaloximes with Hydrogen: Products and Thermodynamics

(2014) Deven P. Estes et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Simple, Chemoselective Hydrogenation with Thermodynamic Stereocontrol

(2014) Kotaro Iwasaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Method for the Selective Hydrogenation of Alkenyl Halides to Alkyl Halides

(2014) Sandra M. King et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient C–H/C–N and C–H/C–CO–N Conversion via Decatungstate-Photoinduced Alkylation of Diisopropyl Azodicarboxylate

(2013) Ilhyong Ryu et al.   ORGANIC LETTERS

Applications of Acceptorless Dehydrogenation and Related Transformations in Chemical Synthesis

(2013) C. Gunanathan et al.   SCIENCE

Reactions of the Cumyloxyl and Benzyloxyl Radicals with Strong Hydrogen Bond Acceptors. Large Enhancements in Hydrogen Abstraction Reactivity Determined by Substrate/Radical Hydrogen Bonding

(2012) Michela Salamone et al.   JOURNAL OF ORGANIC CHEMISTRY

Evidence for Formation of a Co–H Bond from (H2O)2Co(dmgBF2)2 under H2: Application to Radical Cyclizations

(2012) Gang Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diverting non-haem iron catalysed aliphatic C–H hydroxylations towards desaturations

(2011) Marinus A. Bigi et al.   Nature Chemistry

Understanding Hydrogen Atom Transfer: From Bond Strengths to Marcus Theory

(2010) James M. Mayer   ACCOUNTS OF CHEMICAL RESEARCH

Hydrogen Evolution Catalyzed by Cobaloximes

(2009) Jillian L. Dempsey et al.   ACCOUNTS OF CHEMICAL RESEARCH

Decatungstate as an efficient photocatalyst in organic chemistry

(2009) Manolis D. Tzirakis et al.   CHEMICAL SOCIETY REVIEWS