期刊
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
卷 66, 期 3, 页码 295-304出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0036023621030190
关键词
closo-decaborate anion; cyclic voltammetry; electrochemical oxidation
资金
- Russian Foundation for Basic Research [19-29-08047, 20-3370217]
This work focuses on the theoretical and experimental study of the electrochemical characteristics of the closo-decaborate anion. The regions of electrochemical transformations of the [B10H10](2-) anion in non-aqueous solvents of different structures were investigated using cyclic voltammetry, revealing the formation of a dimerization product, the [B20H18](2-) anion, under conditions of anodic oxidation. Additionally, the electrochemical synthesis was first used for the synthesis of the octadecahydroeicosaborate anion.
The work is devoted to the theoretical and experimental study of the electrochemical characteristics of the closo-decaborate anion. The regions of electrochemical transformations of the [B10H10](2-) anion for non-aqueous solvents of different structures (acetonitrile, dichloromethane, and tetrahydrofuran) have been studied by the method of cyclic voltammetry. It has been shown that, under the conditions of anodic oxidation, a dimerization product, the [B20H18](2-) anion, is formed. For the synthesis of octadecahydroeicosaborate anion, electrochemical synthesis has been used for the first time.
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