期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2016, 期 28, 页码 4724-4767出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201600484
关键词
Homogeneous catalysis; Glycosylation; Glycosides; Carbohydrates
资金
- University of Toledo
- University of Michigan-Dearborn
Development of efficient, mild, and easily operable stereoselective glycosylations is of critical importance to access sufficient amounts of pure and structurally well-defined carbohydrates for studies of their biological functions. Such studies will facilitate our understanding of the role of complex oligosaccharides and glycoconjugates in biological processes as well as the development of carbohydrate-based effective therapeutic agents. This review highlights recent advances in the transition metal catalyzed stereoselective glycosylations for the synthesis of a variety of structurally complex and biologically significant O-, N-, C-, and S-glycosides.
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