4.6 Article

Microstructure and Properties of Cu-Fe-Cr-Ag Alloy Prepared by Directional Solidification and Upward Continuous Casting

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SPRINGER
DOI: 10.1007/s11661-021-06239-z

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资金

  1. National Key Research and Development Program of China [2016YFB0301400]
  2. National Natural Science Foundation of China [51561008, 51804138, 51761013]
  3. Program for Excellent Young Talents (JXUST)
  4. Program of Qingjiang Excellent Young Talents
  5. Jiangxi University of Science and Technology

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The research found that directionally solidified Cu-Fe-Cr-Ag alloy exhibited excellent mechanical properties and conductivity, with higher tensile strength and conductivity compared to upward continuously casted alloy after cold drawing and isothermal aging. The finer and more uniform Fe dendrites, Cu-Ag eutectic structure, and distribution of Ag around the material contributed to the superior comprehensive performance of the directionally solidified Cu-Fe-Cr-Ag alloy.
A Cu-Fe-Cr-Ag alloy was prepared by directional solidification (DS) and upward continuous casting (UCC) to study the effect of different casting methods on the structure and properties of Cu-Fe-Cr-Ag. The results showed that the directionally solidified Cu-Fe-Cr-Ag alloy had excellent mechanical properties and conductivity. After cold drawing and isothermal aging, the peak tensile strength (789 MPa) and peak conductivity (65.5 pct IACS) of directionally solidified Cu-Fe-Cr-Ag alloy were 21 MPa and 4.7 pct IACS higher, respectively, than those that of the upward continuously casted Cu-Fe-Cr-Ag alloy. Compared to upward continuously casted Cu-Fe-Cr-Ag alloy, the Fe dendrites in directionally solidified Cu-Fe-Cr-Ag alloy were much finer, more uniform, and arranged along the direction of the magnetic field. Cu and Ag formed a Cu-Ag eutectic structure at the edge of the directionally solidified Cu-Fe-Cr-Ag alloy rod. After multi-stage thermomechanical treatment, Ag was mainly distributed around the material and formed a structure similar to Ag-clad Cu. The directionally solidified Cu-Fe-Cr-Ag alloy had a smaller lattice constant and finer Fe fibers. The small lattice constant and Fe fibers and the special distribution of Ag lead to the excellent comprehensive performance of the directionally solidified Cu-Fe-Cr-Ag alloy.

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