期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 861, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2020.157986
关键词
Transition metal oxide; Core-shell hollow microsphere; G-C3N4; Partial reduction; Hybrid device
资金
- National Key R&D Program of China [2018YFB0605405]
- National Natural Science Foundation of China [U1663224]
The construction of NiFe2O4@g-C3N4 core-shell hollow spherical structure and the in situ formation of Fe-Ni alloy have greatly improved the electrical conductivity of the electrode, leading to enhanced electrochemical performance and cycling stability.
Transition metal oxide NiFe2O4 has many advantages such as abundance in nature, easy availability, low toxicity and being environmentally friendly. However, it suffers from poor electrical conductivity which results in unsatisfactory electrochemical performance. In this work, the construction of NiFe2O4@g-C3N4 core-shell hollow spherical structure and the in situ formation of Fe-Ni alloy have been achieved by facile hydrothermal method followed by annealing in 5%H-2/95%Ar. The electrical conductivity of electrode has been greatly improved leading to a specific capacity of 85.3 mAh g(-1) at 1 A g(-1) and a 67.2% capacity retention at 20 A g(-1). A hybrid device exhibits 19.5 Wh kg(-1) in specific energy and 150.1 W kg(-1 )in specific power, and good cycling stability of 100% capacity retention after 10,000 cycles at 6 A g(-1). (C) 2020 Elsevier B.V. All rights reserved.
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