The metallic 1T-WS2 as cocatalysts for promoting photocatalytic N2 fixation performance of Bi5O7Br nanosheets

Recently, widespread attention has been devoted to the typical layered BiOCl or BiOBr because of the suitable nanostructure and band structure. However, owing to the fast carrier recombination, the photocatalytic performance of BiOX materials is not so satisfactory. Loading 1T phase WS2 nanosheets (NSs) onto Bi5O7Br NSs can improve the photocatalytic N-2 fixation activity. Among these, the obtained 1T-WS2@Bi5O7Br composites with optimum 5% 1T-WS2 NSs display a significantly improved photocatalytic N-2 fixation rate (8.43 mmol L-1 h(-1) g(-1)), 2.51 times higher than pure Bi5O7Br (3.36 mmol L-1 h(-1) g(-1)). And the outstanding stability of 1T-WS2@Bi5O7Br-5 composites is also achieved. Exactly, the photoexcited electrons from Bi5O7Br NSs are quickly transferred to conductive 1T phase WS2 as electron acceptors, which can promote the separation of carriers. In addition, 1T-WS2 NSs can provide abundant active sites on the basal and edge planes, which can promote the efficiency of photocatalytic N-2 fixation. This work offers a novel solution to improve the photocatalytic performance of Bi5O7Br NSs. (C) 2021 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.

Automated summary

By loading 1T phase WS2 nanosheets onto Bi5O7Br nanosheets, the photocatalytic N-2 fixation activity was significantly improved, achieving outstanding stability and efficiency.