Novel broad-spectrum-driven g-C3N4 with oxygen-linked band and porous defect for photodegradation of bisphenol A, 2-mercaptophenthiazole and ciprofloxacin

Abundant active oxygen free radicals could efficiently remove refractory organic pollutants. In previous research, the original carbon nitride can form more hydrogen peroxide, however, owing to the limitation of its band structure, the original carbon nitride cannot decompose the hydrogen peroxide to generate more active oxygen free radicals. Herein, this work reports a simple bottom-up synthesis method, which synthesize a broad-spectrum-response carbon nitride (CN-CA) with oxygen-linked band and porous defect structure, while adjusting the band structure, and the introduction of the oxygen-linked band structure can also decompose the hydrogen peroxide produced by the original carbon nitride to form more active oxygen free radicals. Instrumental characterization and analysis of experimental results revealed the important role of oxygen-linked band and porous defects in adjusting the CN-CA energy band structure and improving its visible light absorption. The optimal CN-CA displays an outstanding photocatalytic degradation ability, that degradation rate of bisphenol A (BPA) reaches 99.8% within 150 min, the reaction rate constant of which is 6.77 times higher than that of pure g-C3N4, as also demonstrated with 2-mercaptophenthiazole (MBT) and ciprofloxacin (CIP). Meanwhile, the excellent degradation performance under blue LED (450-462 nm) and green LED (510-520 nm) exhibits the broad-spectrum characteristics of CN-CA. The degradation pathways of BPA and MBT were analyzed via HPLC-MS. Moreover, the primary active species were detected as O-center dot(2)-, (OH)-O-center dot and h(+) based on the trapping experiments and ESR. This research provides a new strategy for g-C3N4 modified by porous defects and oxygen-linked band structure for environmental remediation. (C) 2020 Elsevier Ltd. All rights reserved.

Automated summary

This research presents a simple synthesis method to prepare a broad-spectrum-response carbon nitride (CN-CA) with oxygen-linked band and porous defect structure, which shows excellent photocatalytic degradation ability for refractory organic pollutants. The introduction of oxygen-linked band structure enables CN-CA to decompose hydrogen peroxide and generate more active oxygen free radicals, leading to a significantly higher degradation rate for bisphenol A (BPA). The study provides a new strategy for environmental remediation by modifying g-C3N4 with porous defects and oxygen-linked band structure.