4.7 Article

Enhanced solar-light-driven photocatalytic and photoelectrochemical properties of zinc tungsten oxide nanorods anchored on bismuth tungsten oxide nanoflakes

期刊

CHEMOSPHERE
卷 268, 期 -, 页码 -

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.chemosphere.2020.129346

关键词

Environmental toxic pollutants removal; Eco-friendly; Oxide nanostructure; Photocatalysis; Photoelectrochemical; Solar illumination

资金

  1. National Research Foundation of Korea (NRF) - Korean government, South Korea [2018R1D1A1B07050330, 2017R1C1B2001990]
  2. National Research Foundation of Korea (NRF) - Space Core Technology Development Project, South Korea [2017M1A3A3A03016056]
  3. National Research Foundation of Korea [2017M1A3A3A03016056] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

向作者/读者索取更多资源

The study successfully prepared zinc tungsten oxide and bismuth tungsten oxide nanomaterials through a hydrothermal approach, forming a bismuth tungsten oxide/zinc tungsten oxide composite which showed excellent photocatalytic degradation and photoelectrochemical performance. These nanocomposites have potential important applications in wastewater treatment and energy production.
At present, sustainable water supply and energy generation are the most important challenges faced by humankind globally. Thus, it is crucial to progress ecological techniques for sustainable removal of organic pollutants from wastewater and generation of hydrogen as an alternative to fossil fuels. In this study, zinc tungsten oxide (ZnWO4) nanorods, bismuth tungsten oxide (Bi2WO6 ) nanoflakes, and Bi2WO6/ZnWO4 (BO-ZO) nanocomposites were prepared via a simple hydrothermal approach. X-ray diffraction, scanning electron microscopy, transmission electron microscopy, high-resolution transmission electron microscopy, diffuse reflectance spectroscopy, and electrochemical analyses were conducted to confirm the formation of the BO-ZO heterostructure. The structural and morphological analyses revealed that the ZnWO4 nanorods were moderately dispersed on the Bi2WO6 nanoflakes. The bandgap tuning of BO-ZO nanocomposite confirmed the establishment of the heterostructure with band bending properties. The BO-ZO nanocomposite could degrade 99.52% of methylene blue (MB) within 60 min upon solar-light illumination. The photoelectrochemical (PEC) measurement results showed that the BO-ZO nanocomposite showed low charge-transfer resistance and high photocurrent response with good stability. The BO-ZO photoanode showed a low charge-transfer resistance of 35.33 Omega and high photocurrent density of 0.1779 mA/cm(2) in comparison with Ag/AgCl in a 0.1 M Na2SO3 electrolyte under solar-light illumination. The MB photocatalytic degradation and PEC water oxidation mechanisms of the nanocomposite were investigated. (C) 2020 Elsevier Ltd. All rights reserved.

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