期刊
CEMENT AND CONCRETE RESEARCH
卷 142, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.cemconres.2021.106381
关键词
Calcium aluminate cement; TiO2 photocatalysts; NOx sequestration; Nitrite/nitrate binding; Surface area
资金
- National Science Foundation [CMMI-1362843, EEC-1757579]
This study quantifies NOx uptake efficiency and explores binding mechanisms in CAC materials. Unmodified CAC utilizes surface-related heterogeneous reactions for NOx binding, while TiO2-modified CAC increases NOx uptake through photocatalytic reactions.
This study quantifies NOx uptake efficiency and explores NOx binding mechanisms in calcium aluminate cementitious (CAC) materials. Comparison between unmodified and TiO2-modified CAC separates intrinsic NOx binding mechanisms from those related to photocatalysis. Attributed to surface-related heterogeneous reactions, the NOx binding occurs in unmodified CAC at nitrite-to-nitrate ratio of 1: 1.3 and can be increased with surface area. The photocatalytic reactions in TiO2-modified CAC increase NOx uptake, and similar to 50% of converted NOx resists releasing back into the environment via dissolution. Compared to previously studied ordinary portland cement (OPC) materials, CAC increases NOx uptake capacity and demonstrates a more permanent NOx binding, potentially mitigating concerns related to the release of previously bound N-species in OPC. Examination of the interaction between NOx and a synthetic pure aluminum-bearing phase shows that the permanent NOx uptake in CAC could be largely attributed to the chemical binding of converted NOx within aluminum-bearing phases.
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