期刊
CATALYSIS TODAY
卷 383, 期 -, 页码 74-83出版社
ELSEVIER
DOI: 10.1016/j.cattod.2021.03.024
关键词
Clean biogas; Reforming; Open-cell foam; Rh; Ni
资金
- Spanish Ministry of Science and Innovation [BES-2014-069010]
The valorisation of clean biogas by steam reforming over metal open-cell foam-based structured catalysts was studied, showing that Rh-based catalysts exhibit superior activity and stability compared to Ru catalysts, leading to reduced carbon deposition and increased biogas valorisation and productivity.
The valorisation of clean biogas (CH4/CO2 = 60/40 v/v) by steam reforming over metal open-cell foam-based structured catalysts was investigated. NiCrAl foams were coated by RuMgAl or RhMgAl hydrotalcite-type compounds through electrodeposition to obtain, after calcination, a thin and stable catalytic film of oxides. The active sites for the reforming reactions are highly dispersed Rh or Ru nanoparticles stabilized by a strong metal support interaction, large Ni particles segregated from the support during reduction and reaction, and Rh/Ni bimetallic particles formed by the interaction of the two formers. Rh-based catalysts show superior activity and stability with the time on stream than Ru catalysts, and a low carbon deposition, which is mainly ascribable to the presence of large Ni particles. In comparison to a pelletized catalyst, the structured catalysts are allowed to operate at high space velocities and low Steam to CH4 ratio, increasing the biogas valorisation and thus the productivity.
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