期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 60, 期 25, 页码 14040-14050出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202102552
关键词
3D hollow structures; Li dendrite inhibition; Li metal batteries; seeding-induced deposition; spatial confinement
资金
- NSAF [U1830113]
- National Natural Science Foundation of China [51772313, 21975276]
- National Key R&D Program of China [2016YFB0901600]
- Shanghai Science and Technology Committee [20520710800]
This study proposes a dual modulation strategy using metal-organic framework (MOF) derivative hollow capsules to alleviate dendrite growth and volume expansion of Li metal, significantly improving cycling and discharge performance. The strategy involves consecutive nucleation and confined growth to address deformation issues of Li metal in durable and long-life Li-metal batteries.
A dual modulation strategy of consecutive nucleation and confined growth of Li metal is proposed by using the metal-organic framework (MOF) derivative hollow capsule with inbuilt lithiophilic Au or Co-O nanoparticle (NP) seeds as heterogeneous host. The seeding-induced nucleation enables the negligible overpotential and promotes the inward injection of Li mass into the abundant cavities in host, followed by the conformal plating of Li on the outer surface of host during discharging. This modulation alleviates the dendrite growth and volume expansion of Li plating. The interconnected porous host network enables enhancement of cycling and rate performances of Li metal (a lifespan over 1200 h for Au-seeding symmetric cells, and an endurance of 220 cycles under an ultrahigh current density of 10 mA cm(-2) for corresponding asymmetric cells). The hollow capsules integrated with lithiophilic seeds solve the deformation problem of Li metal for durable and long-life Li-metal batteries.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据