4.7 Article

Heavy metal contamination status and source apportionment in sediments of Songhua River Harbin region, Northeast China

期刊

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
卷 24, 期 4, 页码 3214-3225

出版社

SPRINGER HEIDELBERG
DOI: 10.1007/s11356-016-7132-0

关键词

Heavy metal contamination; Sediments; Songhua River; Risk assessment; Source apportionment

资金

  1. Major Science and Technology Program for Water Pollution Control and Management [2013ZX07201007, 2014ZX07201012]
  2. State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology [2014DX03, QA201609-02]
  3. Specialized Research Fund for the Doctoral Program of Higher Education [20112302110060]
  4. Funds for Creative Research Groups of China [51121062]
  5. Heilongjiang Postdoctoral Science Foundation [LBH-Z14093]
  6. Fundamental Research Funds for the Central Universities [HIT.NSRIF.2015096]

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The Songhua River represents one of the seven major river systems in China. It flows through Harbin city with 66 km long, locating in the northern China with a longer winter time. This paper aimed to study concentration distributions, stability, risk assessment, and source apportionment of heavy metals including chromium (Cr), cadmium (Cd), lead (Pb), mercury (Hg), arsenic (As), copper (Cu), zinc (Zn), and nickel (Ni) in 11 selected sections of the Songhua River Harbin region. Results showed that Cr, Cd, Pb, Hg, and As exceeded their respective geochemical background values in sediments of most monitoring sections. Compared with other important rivers and lakes in China, Cr, Hg, Cd, and As pollutions in surface sediments were above medium level. Further analysis of chemical speciation indicated that Cr and As in surface sediments were relatively stable while Pb and Cd were easily bioavailable. Correlation analysis revealed sources of these metals except As might be identical. Pollution levels and ecological risks of heavy metals in surface sediments presented higher in the mainstream region (45 degrees 47.0' N similar to 45 degrees 53.3' N, 126 degrees 37.0' E similar to 126 degrees 42.1' E). Source apportionment found Hejiagou and Ashi River were the main contributors to metal pollution of this region. Thus, anthropogenic activities along the Hejiagou and Ashi River should be restricted in order to protect the Songhua River Harbin region from metal contamination.

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