Article
Engineering, Chemical
Zhirong Hu, Yilin Yang, Xiong-Fei Zhang, Chuan Xu, Jianfeng Yao
Summary: In this study, composite membranes were prepared by integrating two-dimensional MXene nanosheets into a nanocellulose matrix, which improved the interfacial property and solubility selectivity, resulting in a high-performance CO2 separation.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)
Review
Chemistry, Multidisciplinary
Hadi Rouhani, Yunpan Ying, Dan Zhao
Summary: Smart membranes based on two-dimensional materials are gaining attention for their ability to change properties in response to environmental stimuli. Future studies should focus on addressing issues such as complex fabrication, long-term stability, and simultaneous response to multiple environmental stimuli.
Review
Engineering, Chemical
Kai Qu, Kang Huang, Zhi Xu
Summary: MXene-based membranes exhibit excellent flux and selectivity, and can be further enhanced through strategies such as crosslinking and construction of nanochannels to meet practical application requirements. MXene nanosheets can also serve as additives in hybrid membranes, with potential extended applications as scaffolds.
FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING
(2021)
Article
Physics, Multidisciplinary
Mohammed Gounzari, Youssef Belkassmi, Abdelhadi Kotri, Mohamed Bouzelmad, Lahcen El Maimouni
Summary: A molecular dynamics simulation was conducted to study the mechanical properties of nanoporous two-dimensional Ti3C2 MXene membranes. It was found that the ultimate strength of the membranes decreases with an increase in the nanoporous surface and the separation distance in the armchair direction, but increases with a decrease in the separation distance following the zigzag direction.
CHINESE JOURNAL OF PHYSICS
(2022)
Article
Nanoscience & Nanotechnology
Yawen Zhang, Dongyun Chen, Najun Li, Qingfeng Xu, Hua Li, Jinghui He, Jianmei Lu
Summary: In this study, stable lamellar membranes were prepared by electrostatic attraction and hydrogen bond formation between polycation polyethyleneimine (PEI) and negatively charged MXene. The interlayer d-spacing of the membrane could be changed by adjusting the suspension pH, allowing for precise molecular separation and high organic solvent penetration. Moreover, the insertion of PEI did not hinder the passage of water molecules. The optimized MXene-PEI membranes showed excellent channel stability.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Review
Agricultural Engineering
Ching Yoong Loh, Wenyuan Ye, Shengqiong Fang, Jiuyang Lin, Ailiang Gu, Xinyu Zhang, Andrew D. Burrows, Ming Xie
Summary: Waste management and climate change are global issues, and the waste-to-hydrogen process offers a solution by producing renewable hydrogen fuel. By using two-dimensional materials as substitutes for conventional membranes, the limitations of current polymeric membranes can potentially be overcome.
BIORESOURCE TECHNOLOGY
(2022)
Article
Chemistry, Multidisciplinary
Jilong Wang, Yaqi Fan, Jingang Jiang, Zheng Wan, Shuyue Pang, Yejun Guan, Hao Xu, Xiao He, Yanhang Ma, Aisheng Huang, Peng Wu
Summary: Membrane separation is an energy-efficient and environmentally friendly process that can achieve highly permeable and selective mixture separation. Two-dimensional molecular sieving membranes with unique nanopores and low transport resistance are desirable, but limited by the availability of recognized zeolite nanosheets. A newly reported swollen layered zeolite, ECNU-28, with high hydrogen selectivity offers promise for hydrogen purification and greenhouse gas capture.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Engineering, Chemical
Xilu Hong, Zong Lu, Yali Zhao, Luxi Lyu, Li Ding, Yanying Wei, Haihui Wang
Summary: A new freestanding MXene-ZIF-8 dual-layered membrane was reported for efficient hydrogen separation, synthesized rapidly using electrophoretic deposition and fast current-driven synthesis techniques. The membrane exhibited significantly improved gas separation performance within a short period of time.
JOURNAL OF MEMBRANE SCIENCE
(2022)
Review
Chemistry, Physical
Liheng Dai, Kang Huang, Yongsheng Xia, Zhi Xu
Summary: The current energy crisis has driven the development of new energy sources and energy storage/conversion devices, with membranes, especially two-dimensional materials, playing a key role in ensuring stable and efficient operation. The review focuses on the recent progress of 2D membranes, including graphene oxide, MXenes, MOFs, COFs, and zeolite nanosheets, used in membrane separation and battery separators in energy field applications. Challenges and future prospects of using 2D membranes in energy sectors are also highlighted.
GREEN ENERGY & ENVIRONMENT
(2021)
Article
Engineering, Chemical
Mide Luo, Zong Lu, Yali Zhao, Yufei Wang, Yanying Wei, Haihui Wang
Summary: In this work, tubular 2D MXene membranes were successfully prepared on commercial porous stainless steel substrates via fast electrophoretic deposition. The prepared membranes showed advantages of simple operation, high membrane assembly efficiency, and ease for scale-up. These tubular MXene membranes exhibited excellent gas separation performance with high hydrogen permeance and selectivity. Importantly, this work provides valuable reference for the development of other 2D material-based membranes for future applications.
Review
Chemistry, Multidisciplinary
Ajit Khosla, Sonu, Hafiz Taimoor Ahmed Awan, Karambir Singh, Gaurav, Rashmi Walvekar, Zhenhuan Zhao, Ajeet Kaushik, Mohammad Khalid, Vishal Chaudhary
Summary: This article introduces the use and potential of MXene-polymer hybrid membranes in environmental remediation, emphasizing their excellent physicochemical properties and adsorptive behavior. The paper reviews the fabrication routes of these hybrid membranes and their applications in water purification, gas separation, radiation shielding, and more.
Review
Engineering, Environmental
Muhammad Bilal Asif, Sidra Iftekhar, Tahir Maqbool, Biplob Kumar Pramanik, Shamas Tabraiz, Mika Sillanpaa, Zhenghua Zhang
Summary: The application and research of two-dimensional (2D) membranes in water purification have made significant progress, especially in materials like graphene. However, challenges remain in industrial production, particularly in large-scale fabrication of nanoporous membranes and ensuring membrane stability.
CHEMICAL ENGINEERING JOURNAL
(2022)
Review
Engineering, Chemical
Wei Wang, Yanying Wei, Jiang Fan, Jiahao Cai, Zong Lu, Li Ding, Haihui Wang
Summary: 2D materials are promising for preparing high-performance membranes for separation applications by achieving promising molecular sieving performance through precise control of interlayer nano-channels or pore sizes. Many high permeability and selectivity 2D membranes have been reported, demonstrating excellent separation performance. The challenges and future directions for wide utilization of 2D membranes are important topics for further discussion.
FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING
(2021)
Article
Chemistry, Multidisciplinary
Yunpan Ying, Zhengqing Zhang, Shing Bo Peh, Avishek Karmakar, Youdong Cheng, Jian Zhang, Lifei Xi, Chris Boothroyd, Yeng Ming Lam, Chongli Zhong, Dan Zhao
Summary: The study demonstrates the use of pressure-responsive ultrathin membranes for CO2 separation, by controlling gas permeation direction to achieve CO2-induced gate opening and closing behaviors, resulting in significantly increased CO2 permeance and selectivity.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Review
Engineering, Chemical
Wenjia Luo, Changzheng Wang, Minghu Jin, Fei Li, Huan Li, Zhixun Zhang, Xi Zhang, Youqian Liang, Guoxian Huang, Tao Zhou
Summary: This article introduces the importance of the green and low-carbon development concept and the urgency to develop efficient CCS technology. Membrane separation technology has become the main direction of carbon capture technology, and the combination of ionic liquids and 2D laminate materials is a current research trend. The article also discusses the properties and separation mechanisms of ionic liquids in CO2 separation and the application of gas separation membranes constructed with different ionic liquids and 2D laminate materials for CO2 capture.
SEPARATION AND PURIFICATION TECHNOLOGY
(2024)
Article
Chemistry, Applied
Fida Hussain Memon, Faisal Rehman, Jaewook Lee, Faheeda Soomro, Muzaffar Iqbal, Shah Masaud Khan, Akbar Ali, Khalid Hussain Thebo, Kyung Hyun Choi
Summary: This comprehensive review summarizes the different fabrication methods of TMDC-based membranes and introduces recent modification strategies to improve their microstructural properties. The applications of TMDCs-based membranes in wastewater treatment, desalination, proton exchange, gas separation, and energy devices are extensively discussed. The current engineering hurdles and research directions for improving the separation efficiency, stability, and permeability of these membranes are highlighted.
SEPARATION AND PURIFICATION REVIEWS
(2023)
Article
Chemistry, Organic
Anwar Ali Chandio, Shahabuddin Memon, Ayaz Ali Memon, Aamna Balouch, Roomia Memon, Khalid Hussain Thebo, Fakhar N. Memon, Muhammad Hassan Agheem, Safia Sanam Memon, Aijaz Ali Otho
Summary: The CuO nanoparticles functionalized with the diamide derivative of calix[4] arene were used as a catalyst for the synthesis of p-aminophenol. The catalyst showed high efficiency in the conversion process.
POLYCYCLIC AROMATIC COMPOUNDS
(2023)
Article
Materials Science, Multidisciplinary
Meher-Un-Nisa Khilji, Noor Ahmed Nahyoon, Mujahid Mehdi, Khalid Hussain Thebo, Nasrullah Mahar, Ayaz Ali Memon, Najma Memon, Nadir Hussain
Summary: A novel nanocomposite of magnesium oxide doped graphene oxide (MgO@GO) was synthesized and used as a visible-light driven photocatalyst for the degradation of Rhodamine 6G (Rh6G). The morphology, structure, functional groups, and chemical composition of the photocatalyst were characterized. By combining tungsten light (50 W), stirring, and aeration, a degradation efficiency of 98% for Rh6G (30 mL, 1 ppm) was achieved within 15 minutes.
Article
Biochemistry & Molecular Biology
Faheeda Soomro, Fida Hussain Memon, Muhammad Ali Khan, Muzaffar Iqbal, Aliya Ibrar, Ayaz Ali Memon, Jong Hwan Lim, Kyung Hyon Choi, Khalid Hussain Thebo
Summary: An easy and efficient method was used to fabricate MoO2@GO and WO3@GO nanocomposite membranes with controlled structure and interlayer spacing. These membranes showed good separation for salt and heavy metal ions due to intensive stacking interaction and electrostatic attraction. They exhibited high rejection rates (>70%) for small metal ions such as sodium (Na+) and magnesium (Mg2+) ions, as well as >99% rejection rates for nickel (Ni2+) and lead (Pb2+) ions, with good water permeability of 275 +/- 10 L m(-2) h(-1) bar(-1). We believe that these fabricated membranes have a bright future in next generation desalination and water purification membranes.
Article
Engineering, Chemical
Inamullah Mahar, Faraz Khan Mahar, Nasrullah Mahar, Ayaz Ali Memon, Azhar Ali Ayaz Pirzado, Zeeshan Khatri, Khalid Hussain Thebo, Ayaz Ali
Summary: High contamination of toxic heavy metals such as lead and arsenic in water is a major threat to human health and aquatic life. MXene/Carbon composite-based nanofibers (MXene/CNFs) membrane was synthesized and showed efficient removal of lead and arsenic ions up to their permissible limits. The adsorption results fit well with both the Langmuir and the pseudosecond-order models. The MXene/CNFs composite membrane demonstrated high adsorption capability and good recycling performance.
CHEMICAL ENGINEERING RESEARCH & DESIGN
(2023)
Article
Chemistry, Multidisciplinary
Muhammad Usman Khan, Faisal Rehman, Mohsin Saleem, Hassan Elahi, Tae Hyun Sung, Hamid Jabbar
Summary: This study designs, develops, and validates an 800 mL capacity ultrasonic cleaner driven by a piezoelectric disc actuator. The acoustic spectrum generated inside the tank was measured using a piezoelectric sensor to validate the optimal design and driving frequency. The cleaning effect was tested using aluminum foil perforations, and a proposed image processing technique achieved 97% accuracy in detecting perforation areas.
APPLIED SCIENCES-BASEL
(2023)
Article
Chemistry, Multidisciplinary
Dahar Janwery, Fida Hussain Memon, Ayaz Ali Memon, Muzaffar Iqbal, Fakhar Nisa Memon, Wajid Ali, Kyung-Hyun Choi, Khalid Hussain Thebo
Summary: Significant efforts have been made to develop efficient graphene oxide (GO) lamellar membranes for heavy metal ion separation and water desalination. However, the selectivity for small ions has remained a challenge. In this study, GO was modified using onion extractive (OE) and quercetin, and the resulting membranes showed excellent rejection efficiency for heavy metal ions and good water permeance. The modified membranes also demonstrated high rejection for small ions and effective filtration of river water. Furthermore, the GO/OE composite membrane exhibited superior stability compared to the GO/Q composite and pristine GO-based membranes.
Article
Biochemistry & Molecular Biology
Imtiaz Ali Soomro, Fida Hussain Memon, Waqas Mughal, Muhammad Ali Khan, Wajid Ali, Yong Liu, Kyung Hyun Choi, Khalid Hussain Thebo
Summary: In this study, a three-dimensional computational fluid dynamic model was developed based on published literature data to investigate the impact of temperature and pressure on the performance of proton exchange membrane fuel cells. The results showed that the performance of the fuel cell can be enhanced by adjusting the temperature and operating pressure. It was also found that an increase in temperature leads to a decrease in current density, while fully humidified gas channels and higher reference current density values can improve current density.
Article
Materials Science, Multidisciplinary
Ali Hyder, Jamil Ahmed Buledi, Roomia Memon, Anjum Qureshi, Javed H. Niazi, Amber Rehana Solangi, Shahabuddin Memon, Ayaz Ali Memon, Khalid Hussain Thebo
Summary: This study presents a cost-effective and highly sensitive electrochemical sensor based on a nanocomposite material for the detection of gallic acid (GA). The sensor exhibits exceptional electrochemical response towards GA and demonstrates good recovery results when applied to wine and green tea samples.
DIAMOND AND RELATED MATERIALS
(2023)
Article
Multidisciplinary Sciences
Ali Hyder, Muzamil Thebo, Dahar Janwery, Jamil Ahmed Buledi, Imamdin Chandio, Awais Khalid, Bader S. Al-Anzi, Hanadi A. Almukhlifi, Khalid Hussain Thebo, Fakhar N. Memon, Ayaz Ali Memon, Amber Rehana Solangi, Shahabuddin Memon
Summary: Water pollution caused by organic pollutants is a global concern. A new composite material has been synthesized and found to effectively remove 2,4,6-trichlorophenol from wastewater.
Review
Chemistry, Multidisciplinary
Hyder Ali, Akbar Ali, Jamil Ahmed Buledi, Ayaz Ali Memon, Amber Rehana Solangi, Jun Yang, Khalid Hussain Thebo
Summary: Transition metal carbides and nitrides (MXenes) are a promising material for the separation and removal of toxic pollutants from the environment due to their excellent optical, electrical, chemical, and mechanical properties. This review discusses the synthesis methods and properties of MXenes, including optical, electrical, and mechanical properties. It also examines their photocatalytic properties in antibiotic medication degradation and their potential use as a membrane and adsorbent for removing synthetic dyes and heavy metal ions from wastewater. The technical challenges and prospects for MXenes are also discussed.
MATERIALS CHEMISTRY FRONTIERS
(2023)
Article
Engineering, Environmental
Muhammad Khurram Shahzad, Fida Hussain Memon, Faheeda Soomro, Muzaffar Iqbal, Aliya Ibrar, Ayaz Ali Memon, Jong Hwan Lim, Kyung Hyon Choi, Khalid Hussain Thebo
Summary: This review summarizes the potential of molybdenum sulfide (MoS2)-based lamellar membranes in the treatment of effluent wastewater, seawater desalination, gas separation, energy storage, and fuel cell applications. The current manufacturing methods, advantages, and drawbacks are discussed. The uses of MoS2-based membranes in water desalination, gas separation, proton exchange in fuel cells, and energy storage devices are highlighted. Finally, the benefits, limitations, and future challenges are summarized in detail.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Article
Chemistry, Multidisciplinary
Ashique Hussain Jatoi, Kyung Hwan Kim, Muhammad Ali Khan, Fida Hussain Memon, Muzaffar Iqbal, Dahar Janwery, Shah Nawaz Phulpoto, Anupama Samantasinghar, Kyung Hyun Choi, Khalid Hussain Thebo
Summary: In this study, two-dimensional graphene oxide-based membranes were fabricated by surface modification of graphene oxide with six-armed poly(ethylene glycol) (PEG) at room temperature. The as-modified PEGylated graphene oxide (PGO) membranes showed unique layered structures and large interlayer spacing, which made them suitable for organic solvent nanofiltration. The prepared PGO membrane exhibited superior separation efficiency (>99%) for several dye molecules and had high methanol permeance (155 +/-10 L m(-2) h(-1)), which was 10-100 times higher than pristine GO membranes. The PGO membranes also showed stability for up to 20 days in organic solvent. Therefore, these results suggest that the synthesized PGO membranes with superior separation efficiency can be used for organic solvent nanofiltration in the future.
Article
Engineering, Multidisciplinary
Muhammad Kaleem Shabbir, Wajid Ali, Urooj Khanum, Kashif Hussain Memon, Javeed Akhtar, Muzaffar Iqbal, Fazal Bhutta, J. M. Ashfaq, Kyung Hyun Choi, Khalid Hussain Thebo
Summary: Graphene-based nanocomposites modified with tin oxide and bismuth-doped tin oxide have been synthesized and characterized in this study. The electrochemical tests showed that these nanocomposites exhibit excellent capacitance and cyclic stability.
RESULTS IN ENGINEERING
(2023)