期刊
JOURNAL OF ENERGY STORAGE
卷 34, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.est.2020.102169
关键词
Sacrificial template method; Hollow structure; Co3O4; Hybrid supercapacitor
资金
- National Natural Science Foundation of China [11604147, 51702059]
- Foundation of National Laboratory of Solid State Microstructures [M32048]
- Jiangxi Province Key Projects of Science and Technology Support Plan Natural Science [20142BBE50014]
- Foundation of Guangxi Zhuang Autonomous Region of China [2017GXNSFBA198131]
Co3O4 hollow tube arrays designed using a sacrificial template method exhibit larger electrochemical capacity and lower resistance compared to Co3O4 directly grown on a substrate. The unique hollow structure advantage and self-supporting method without binder contribute to the improved performance.
Co3O4 as an electrode material has been widely used for energy storage. However, it has low capacity and is generally associated with poor cycle life and stability. We designed the Co3O4 hollow tube arrays on Ni foam though a facial strategy based on the ZnO sacrificial template method. Benefit from the unique hollow structure advantage and the low resistance brought by the use of self-supporting method without binder. Compared to Co3O4 directly grown on a substrate, the as-prepared hollow Co3O4 structure exhibits large electrochemical capacity of 748.1 C g(-1) at 1 A g(-1), the result is larger than that of pure Co(3)O(4)directly growing on the substrate without adding Zn2+ as the template. Furthermore, a hybrid supercapacitor device Zn@Co//AC reaches the specific energy of 60.91 Wh kg(-1) under the specific power of 450 W kg(-1).
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