期刊
MOLECULAR CATALYSIS
卷 503, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.mcat.2021.111415
关键词
Cooperative catalysis; Molybdenum catalysis; Organocatalysis; Amines; Imines
资金
- National Natural Science Foundation of China [21868033]
- Xinjiang Bingtuan Young and Middle-Aged Leading Scientists Program [2020CB027]
- Shihezi Young and MiddleAged Leading Scientists Program [2019RC01]
A new catalytic system consisting of Mo(CO)6 and organocatalyst has been discovered for N-alkylation of alcohols with amines, showing high activity, tolerance, and selectivity. The cooperative catalysis mechanism was elucidated through control experiments.
Multi-amino groups and nitrogen donors compound was discovered as an organocatalyst for N-alkylation of alcohols with amines in the presence of Mo(CO)6. The Mo(CO)6/organocatalyst binary system has shown to be a highly active catalyst for the N-alkylation reaction between alcohols and amines with excellent tolerance of variable starting materials bearing different functional groups. Of particular note, this method possessing a superiority selectivity in the synthesis of N-alkylated amines or imines, which can be controlled by the reaction temperature. The cooperative catalysis mechanism in combination of Mo(CO)6 with organocatalyst was elucidated by control experiments.
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