Highly Diastereo- and Enantioselective Synthesis of Tetrahydrobenzo[b]azocines via Palladium-Catalyzed [4 + 4] Cycloaddition

Gold(I)-Catalyzed Highly Diastereo- and Enantioselective Cyclization-[4+3] Annulation Cascades between 2-(1-Alkynyl)-2-alken-1-ones and Anthranils

(2020) Rahul Dadabhau Kardile et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium‐Catalyzed Asymmetric [4+2] Cycloaddition of 2‐Methylidenetrimethylene Carbonate with Alkenes: Access to Chiral Tetrahydropyran‐Fused Spirocyclic Scaffolds

(2020) Biming Mao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Huisgen Reaction: Milestones of the 1,3‐Dipolar Cycloaddition

(2020) Martin Breugst et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Advances in the Total Synthesis of Natural Products Containing Eight-Membered Carbocycles (2009–2019)

(2020) Ya-Jian Hu et al.   CHEMICAL REVIEWS

Rh-Catalyzed C–H Amination/Annulation of Acrylic Acids and Anthranils by Using −COOH as a Deciduous Directing Group: An Access to Diverse Quinolines

(2020) Yang Gao et al.   ORGANIC LETTERS

Late-Stage Diversification of Natural Products

(2020) Benke Hong et al.   ACS Central Science

Forging Odd-Membered Rings: Palladium-Catalyzed Asymmetric Cycloadditions of Trimethylenemethane

(2020) Barry M. Trost et al.   ACCOUNTS OF CHEMICAL RESEARCH

Stereoselective access to [5.5.0] and [4.4.1] bicyclic compounds through Pd-catalysed divergent higher-order cycloadditions

(2020) Li-Cheng Yang et al.   Nature Chemistry

Palladium-Catalyzed Asymmetric Decarboxylative [4+2] Dipolar Cycloaddition of 4-Vinyl-1,3-dioxan-2-ones with α,β-Disubstituted Nitroalkenes Enabled by a Benzylic Substituted P,N-Ligand

(2020) Juan Du et al.   ORGANIC LETTERS

Gold-Catalyzed Intermolecular Formal [4 + 2 + 2]-Cycloaddition of Anthranils with Allenamides

(2020) Cheng Wang et al.   ORGANIC LETTERS

Construction of Medium-Sized Rings by Gold Catalysis

(2020) Ronald L. Reyes et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Enantioselective Cycloadditions of Aliphatic 1,4-Dipoles: Access to Chiral Cyclohexanes and Spiro [2.4] heptanes

(2020) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold(I)-Catalyzed 1,3-Carbofunctionalizations of Anthranils with Vinyl Propargyl Esters To Yield 1,3-Dihydrobenzo[c]-isoxazoles

(2019) Manisha Skaria et al.   ORGANIC LETTERS

Copper-Catalyzed Oxidative [4 + 2]-Cyclization Reaction of Glycine Esters with Anthranils: Access to 3,4-Dihydroquinazolines

(2019) Jie Ren et al.   ORGANIC LETTERS

Strategies for the Diversity-Oriented Synthesis of Macrocycles

(2019) Kim T. Mortensen et al.   CHEMICAL REVIEWS

An overview of late-stage functionalization in today’s drug discovery

(2019) Michael Moir et al.   Expert Opinion on Drug Discovery

Base-Mediated [3 + 4]-Cycloaddition of Anthranils with Azaoxyallyl Cations: A New Approach to Multisubstituted Benzodiazepines

(2019) Juan Feng et al.   ORGANIC LETTERS

Acyl Migration versus Epoxidation in Gold Catalysis: Facile, Switchable, and Atom-Economic Synthesis of Acylindoles and Quinoline Derivatives

(2019) Xianhai Tian et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Expanding the Frontiers of Higher-Order Cycloadditions

(2019) David McLeod et al.   ACCOUNTS OF CHEMICAL RESEARCH

Gold‐Catalyzed Iminations of Terminal Propargyl Alcohols with Anthranils with Atypical Chemoselectivity for C(1)‐Additions and 1,2‐Carbon Migration

(2019) Manisha Skaria et al.   CHEMISTRY-A EUROPEAN JOURNAL

Practical Synthesis of Benzimidazo[1,2-a]quinolines via Rh(III)-Catalyzed C–H Activation Cascade Reaction from Imidamides and Anthranils

(2019) Yao Hu et al.   ORGANIC LETTERS

Gold-Catalyzed Regiospecific C−H Annulation of o -Ethynylbiaryls with Anthranils: π-Extension by Ring-Expansion En Route to N-Doped PAHs

(2018) Zhongyi Zeng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-metal-catalyzed cyclization reactions using vinyl and ethynyl benzoxazinones as dipole precursors

(2018) Tian-Ren Li et al.   TETRAHEDRON LETTERS

Gold-catalyzed (4 + 2)-annulations between α-alkyl alkenylgold carbenes and benzisoxazoles with reactive alkyl groups

(2018) Bhanudas Dattatray Mokar et al.   Chemical Science

Sequential Visible-Light Photoactivation and Palladium Catalysis Enabling Enantioselective [4+2] Cycloadditions

(2017) Miao-Miao Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent Advances in the Synthesis of Hydrogenated Azocine-Containing­ Molecules

(2017) Leonid Voskressensky et al.   SYNTHESIS-STUTTGART

Enantioselective Conjugate Addition Catalyzed by a Copper Phosphoramidite Complex: Computational and Experimental Exploration of Asymmetric Induction

(2017) Ruchuta Ardkhean et al.   ACS Catalysis

Recent Advances in the Catalytic Cycloaddition of 1,n-Dipoles

(2017) Nirupam De et al.   ACS Catalysis

Cooperative Catalysis of Combined Systems of Transition-Metal Complexes with Lewis Acids: Theoretical Understanding

(2016) Wei Guan et al.   CHEMICAL RECORD

The medicinal chemist's toolbox for late stage functionalization of drug-like molecules

(2016) Tim Cernak et al.   CHEMICAL SOCIETY REVIEWS

Recent Advances of Catalytic Asymmetric 1,3-Dipolar Cycloadditions

(2015) Takuya Hashimoto et al.   CHEMICAL REVIEWS

Bioinspired Total Synthesis of Sespenine

(2014) Yu Sun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

1,4-Dipolar cycloadditions and related reactions

(2014) Vijay Nair et al.   TETRAHEDRON

Palladium-Catalyzed Synthesis of 4-Oxaspiro[2.4]heptanes via Central Attack of Oxygen Nucleophiles to π-Allylpalladium Intermediates

(2012) Ryo Shintani et al.   ORGANIC LETTERS

Transition Metal-Catalyzed Decarboxylative Allylation and Benzylation Reactions

(2011) Jimmie D. Weaver et al.   CHEMICAL REVIEWS

Oxidative Intramolecular Bromo-Amination ofN-Alkenyl Sulfonamides via Umpolung of Alkali Metal Bromides

(2011) Katsuhiko Moriyama et al.   JOURNAL OF ORGANIC CHEMISTRY

A family of multicyclic indolosesquiterpenes from a bacterial endophyte

(2011) Ling Ding et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Xiamycin, a pentacyclic indolosesquiterpene with selective anti-HIV activity from a bacterial mangrove endophyte

(2010) Ling Ding et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Mechanistic Investigation of the Palladium-Catalyzed Decarboxylative Cyclization of γ-Methylidene-δ-valerolactones with Isocyanates: Kinetic Studies and Origin of the Site Selectivity in the Nucleophilic Attack at a (π-Allyl)palladium

(2010) Ryo Shintani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total Synthesis of (+)-Manzamine A

(2010) Tatsuya Toma et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The first total synthesis of (±)-apparicine

(2009) M.-Lluïsa Bennasar et al.   CHEMICAL COMMUNICATIONS

Stereoselective Synthesis of Spirooxindoles by Palladium-Catalyzed Decarboxylative Cyclization of γ-Methylidene-δ-valerolactones with Isatins

(2009) Ryo Shintani et al.   ORGANIC LETTERS

Palladium-Catalyzed Decarboxylative [4 + 3] Cyclization of γ-Methylidene-δ-valerolactones with 1,1-Dicyanocyclopropanes

(2009) Ryo Shintani et al.   ORGANIC LETTERS

Palladium-Catalyzed Asymmetric Decarboxylative Lactamization of γ-Methylidene-δ-valerolactones with Isocyanates: Conversion of Racemic Lactones to Enantioenriched Lactams

(2008) Ryo Shintani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Synthesis of Nipecotic Acid Derivatives via Palladium-Catalyzed Decarboxylative Cyclization of γ-Methylidene-δ-valerolactones with Imines

(2008) Ryo Shintani et al.   ORGANIC LETTERS