期刊
WATER SCIENCE AND TECHNOLOGY
卷 83, 期 5, 页码 1118-1129出版社
IWA PUBLISHING
DOI: 10.2166/wst.2021.055
关键词
attapulgite; hybrids; MOFs; organics removal; photodegradation
资金
- National Natural Science Foundation of China [21865030, 21364012]
The study introduced a hybrid material of attapulgite and metal-organic framework, showing good photocatalytic performance for dye wastewater treatment.
The attapulgite (APT), a typical nano-rod structured clay was introduced to MIL-101(Fe), a typical eco-friendly iron-based Metal-Organic Framework material (MOF), during the preparation by a one-step solvothermal method, which afforded a novel APT and MOF hybrid (APT@MIL). Based on the characterization of SEM, FT-IR and XRD, it was found that the rod-like crystals of APT determined the size of MIL-101(Fe) while maintaining its regular octahedral crystal form, and the crystal size of MIL-101(Fe) in APT@MIL enlarged 4 times. It was also discovered that the rod-like APT were evenly distributed in MIL-101(Fe) crystals. Using APT@MIL as the photocatalyst, some organic dyes were photodegraded in simulated sunlight. The analysis indicated that APT@MIL has high adsorption and photodegradation activity, the removal rate of methylene blue was up to 99.5%. Finally, the photocatalytic activity of APT@MIL was verified by UV-Vis DRS, photoluminescence spectra. The thermodynamic adsorption, kinetic characteristics adsorption, and removal mechanism of APT@MIL are also discussed. In summary, a novel hybrid material APT@MIL was successfully prepared with good adsorption and photocatalytic performance. It is expected to be used in photocatalytic degradation of dye wastewater.
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