Palladium-Catalyzed Diastereo- and Enantioselective [3 + 2] Cycloaddition of Vinylcyclopropanes with Azadienes: Efficient Access to Chiral Spirocycles

Protecting-Group-Free Syntheses of ent-Kaurane Diterpenoids: [3+2+1] Cycloaddition/Cycloalkenylation Approach

(2020) Jin Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic [5 + 1]-Cycloadditions of Vinylcyclopropanes and Vinylidenes

(2020) Conner M. Farley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective Ring-Opening Reactions of Cyclopropanes

(2020) Vincent Pirenne et al.   CHEMICAL REVIEWS

Asymmetric (4 + 3) and (4 + 1) Annulations of Isatin-derived Morita–Baylis–Hillman Carbonates to Construct Diverse Chiral Heterocyclic Frameworks

(2020) Ru-Jie Yan et al.   ORGANIC LETTERS

Synthesis of 1,2,3,4‐tetrahydrobenzofuro[3,2‐d]pyrimidines via [4 + 2] annulation reaction of 1,3,5‐triazinanes and aurone‐derived α,β‐unsaturated imines

(2020) Bin cheng et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric Catalytic Reactions of Donor‐Acceptor Cyclopropanes

(2020) Yong Xia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition Metal-Catalyzed Selective Carbon–Carbon Bond Cleavage of Vinylcyclopropanes in Cycloaddition Reactions

(2020) Jianhua Wang et al.   CHEMICAL REVIEWS

Regio- and Diastereoselective Spirocyclopropanation of Benzofuran-Derived Azadienes through 1,4-Addition-Induced Dearomatization Reaction under Mild Conditions

(2020) Qing-Yun Fang et al.   ORGANIC LETTERS

Access to Optically Active 7-Membered Rings by a 2-Step Synthetic Sequence: Cu-Catalyzed Stereoselective Cyclopropanation of Branched 1,3-Dienes/Rh-Catalyzed Stereoconvergent [5 + 2] Cycloaddition

(2020) Michele Garbo et al.   ACS Catalysis

Catalytic Enantioselective Construction of Spiro Quaternary Carbon Stereocenters

(2019) Peng-Wei Xu et al.   ACS Catalysis

Palladium-Catalyzed Highly Enantioselective Cycloaddition of Vinyl Cyclopropanes with Imines

(2019) Xiao-Bing Huang et al.   ORGANIC LETTERS

Pd-Catalyzed Dearomatization of Anthranils with Vinylcyclopropanes by [4+3] Cyclization Reaction

(2019) Qiang Cheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electron-Deficient Alkynes as Dipolarophile in Pd-Catalyzed Enantioselective (3 + 2) Cycloaddition Reaction with Vinyl Cyclopropanes

(2019) Wen-Ping Ding et al.   ORGANIC LETTERS

Construction of All-Carbon Quaternary Stereocenters via Sequential Photoactivation/Isothiourea Catalysis

(2019) Tao Fan et al.   ORGANIC LETTERS

Highly Regio-, Diastereo-, and Enantioselective Synthesis of Tetrahydroazepines and Benzo[b ]oxepines through Palladium-Catalyzed [4+3] Cycloaddition Reactions

(2019) Barry M. Trost et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Alkynylation/Cyclization/Isomerization Cascade for Synthesis of 1,2-Dihydrobenzofuro[3,2-b]pyridines and Benzofuro[3,2-b]pyridines

(2019) Huan-Ping Xie et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Asymmetric [4+3] Cyclization of Trimethylenemethane: Regio-, Diastereo-, and Enantioselective Construction of Benzofuro[3,2-b ]azepine Skeletons

(2019) Yang-Zi Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd-Catalyzed Enantioselective [6+4] Cycloaddition of Vinyl Oxetanes with Azadienes to Access Ten-Membered Heterocycles

(2018) Ya-Nong Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Dearomative [3 + 2] Cycloaddition of Electron-Deficient Indoles with All-Carbon 1,3-Dipoles

(2018) Meng Sun et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective N-Heterocyclic Carbene-Catalyzed Synthesis of Spirocyclic Oxindole-benzofuroazepinones

(2018) Zhong-Hua Gao et al.   JOURNAL OF ORGANIC CHEMISTRY

Divergent Domino Reactions of Sulfur Ylides: Access to Functionalized Six- and Seven-Membered Nitrogen–Heterocycles

(2018) Junlong Chen et al.   ORGANIC LETTERS

Design and Synthesis of Spirocycles

(2017) Sambasivarao Kotha et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

A novel polycyclic meroterpenoid with aldose reductase inhibitory activity from medicinal mushroom Ganoderma leucocontextum

(2017) Jinjin Zhang et al.   JOURNAL OF ANTIBIOTICS

Phosphine-Catalyzed Sequential [4 + 3] Domino Annulation/Allylic Alkylation Reaction of MBH Carbonates: Efficient Construction of Seven-Membered Heterocycles

(2017) Junlong Chen et al.   ORGANIC LETTERS

Catalyst-controlled regioselectivity in phosphine catalysis: the synthesis of spirocyclic benzofuranones via regiodivergent [3 + 2] annulations of aurones and an allenoate

(2017) Huanzhen Ni et al.   Chemical Science

A Catalyst-Enabled Diastereodivergent Aza-Diels-Alder Reaction: Complementarity ofN-Heterocyclic Carbenes and Chiral Amines

(2016) Zi-Qiang Rong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Spiro Meroterpenoids from Ganoderma applanatum

(2016) Qi Luo et al.   JOURNAL OF NATURAL PRODUCTS

NHC-Catalyzed Enantioselective Dearomatizing Hydroacylation of Benzofurans and Benzothiophenes for the Synthesis of Spirocycles

(2016) Daniel Janssen-Müller et al.   ACS Catalysis

Rhodium-Catalyzed [5 + 2 + 1] Cycloaddition of Ene–Vinylcyclopropanes and CO: Reaction Design, Development, Application in Natural Product Synthesis, and Inspiration for Developing New Reactions for Synthesis of Eight-Membered Carbocycles

(2015) Yi Wang et al.   ACCOUNTS OF CHEMICAL RESEARCH

A New Golden Age for Donor-Acceptor Cyclopropanes

(2014) Tobias F. Schneider et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The use of spirocyclic scaffolds in drug discovery

(2014) Yajun Zheng et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

The Chemistry of Griseofulvin

(2014) Asger B. Petersen et al.   CHEMICAL REVIEWS

Enantioselective Copper(I/II)-Catalyzed Conjugate Addition of Nitro Esters to β,γ-Unsaturated α-Ketoesters

(2014) Sheng Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Pharbinilic Acid, an Allogibberic Acid from Morning Glory (Pharbitis nil)

(2013) Ki Hyun Kim et al.   JOURNAL OF NATURAL PRODUCTS

A ring-distortion strategy to construct stereochemically complex and structurally diverse compounds from natural products

(2013) Robert W. Huigens III et al.   Nature Chemistry

Asymmetric Catalysis for the Synthesis of Spirocyclic Compounds

(2013) Annaliese K. Franz et al.   ACS Catalysis

New and unusual scaffolds in medicinal chemistry

(2011) Charles M. Marson   CHEMICAL SOCIETY REVIEWS

Enantioselective methodologies for the synthesis of spiro compounds

(2011) Ramon Rios   CHEMICAL SOCIETY REVIEWS

Synthesis and Structural Revision of (±)-Laurentristich-4-ol

(2007) Pinhong Chen et al.   JOURNAL OF ORGANIC CHEMISTRY