4.8 Article

Flexible MoSe2/MXene films for Li/Na-ion hybrid capacitors

期刊

JOURNAL OF POWER SOURCES
卷 488, 期 -, 页码 -

出版社

ELSEVIER
DOI: 10.1016/j.jpowsour.2021.229452

关键词

MoSe2 nanoparticles; MXene; Sodium-ion capacitors; Lithium-ion capacitors

资金

  1. Natural Science Foundation of Tianjin City [15JCYBJC53200]
  2. Natural Science Foundation of Hebei Province of China [E2018202123]
  3. Jian-Hua Research Foundation of Hebei University of Technology [HB1921]
  4. Key Research and Development Program of Hebei Province, China [17391001D]
  5. One Belt, One Road Technology Innovation Cooperation Project of Tianjin [18PTZWHZ00220]
  6. Ministry of Science and Higher Education of the Russian Federation as part of World-class Research Center program [075-15-2020-934]

向作者/读者索取更多资源

A flexible and free-standing MoSe2/MXene film with sandwich structure was developed as an anode for SICs and LICs, showing improved electrochemical activity and reaction kinetics. The optimized film exhibited enhanced Li/Na storage performances, with high energy/power densities and long lifespans, demonstrating the potential for future flexible energy storage devices.
MoSe2 presents a prospect in sodium-ion capacitors (SICs) and lithium-ion capacitors (LICs), which are considered as promising new energy systems because they possess the merits of both batteries and supercapacitors. In this work, we develop a flexible and free-standing MoSe2/MXene film with sandwich structure as an anode for SICs and LICs. The highly conductive MXene sheets can boost the electrochemical activity of MoSe2 nanoparticles. Meanwhile, the MoSe2 nanoparticles can also enlarge the interlayer spacing of MXene film, facilitating the permeation of electrolyte and eventually leading to fast reaction kinetics of MoSe2. The sandwich structure can effectively limit the loss of intermediate products generated during the insertion/extraction reactions of MoSe2, giving rise to a durable cycle performance. The MoSe2/MXene film with an optimized mass ratio exhibits much improved Li/Na storage performances as compared with the pristine MoSe2, particular the long term cyclic stability. SICs and LICs could deliver high energy/power densities (Max 110.1 Wh kg(-1)/4764.7 W kg(-1) and 84.9 Wh kg(-1)/3288.3 W kg(-1), respectively), as well as long lifespans, demonstrating the prospective of such MXene/MoSe2 film electrode towards alkali metal ion capacitors. Assembled flexible SICs/LICs prototypes further prove the potential application for the future flexible energy storage devices.

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