4.7 Article

Multicomponent Co9S8@MoS2 nanohybrids as a novel trifunctional electrocatalyst for efficient methanol electrooxidation and overall water splitting

期刊

JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 586, 期 -, 页码 538-550

出版社

ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2020.10.119

关键词

Polyoxometalate; Co9S8; MoS2; Methanol oxidation reaction; Overall water splitting

资金

  1. National Natural Science Foundation of China [21601161]
  2. Program for Science & Technology Innovation Talents in Universities of Henan Province [19HASTIT050]
  3. Innovative Technology Team of Henan Province [CXTD2014042]
  4. Key Research Project of University of Henan Province [19zx004]

向作者/读者索取更多资源

In this study, Co9S8@MoS2 nanohybrids were designed and synthesized as trifunctional electrocatalysts for hydrogen evolution, oxygen evolution, and methanol oxidation reactions. The nanostructure and chemical components of the nanohybrids can be modulated by changing the mole ratios of precursors. The nanohybrid exhibited superior catalytic efficiency and low overpotential for overall water splitting at a current density of 10 mA cm(-2).
In view of the importance of multifunctional catalysts that can drive different electrocatalytic reactions in the same electrolyte solution, we designed and prepared a series of multicomponent nanohybrids composed of Co9S8 and MoS2 derived from cobalt-doped polyoxometalate (Co-ROMs) by one-pot calcination method. The obtained Co9S8@MoS2 nanohybrids were composed of Co9S8, MoS2, Co-Mo-S phases and assembled nanosheets, and therefore were explored as trifunctional electrocatalysts for hydrogen evolution reaction, oxygen evolution reaction, and methanol oxidation reaction (MOR) in an alkaline medium. The nanostructure and chemical components of the series of Co9S8@MoS2 nanohybrids can be modulated by changing the mole ratios of H8Mo12O41P to Co(NO3)(2) precursor. Compared with the sole component and other reported Co9S8@MoS2 nanohybrids, the Co9S8@MoS2 nanohybrid prepared from the 1:1 ratio of PMo12 and Co(NO3)(2) exhibited superior MOR catalysis efficiency (121.4 mA cm(-2)) and an extremely low overpotential (1.49 V) for overall water splitting at a current density of 10 mA cm(-2) owning to the effective synergism among Co9S8, MoS2, and Co-Mo-S phase. Overall, this study provides a feasible approach to developing efficient and stable trifunctional bimetal electrocatalysts for clean-energy applications. (C) 2020 Elsevier Inc. All rights reserved.

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