4.7 Article

Engineered biochars from organic wastes for the adsorption of diclofenac, naproxen and triclosan from water systems

期刊

JOURNAL OF CLEANER PRODUCTION
卷 288, 期 -, 页码 -

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.jclepro.2020.125686

关键词

Triclosan; Diclofenac; Naproxen; Engineered biochar; Sorption

向作者/读者索取更多资源

Biochar production is an eco-efficient technology that can convert toxic wastes into highly efficient materials for pharmaceuticals removal from water. Converting sewage sludge into engineered biochar can help minimize waste volume and obtain novel highly efficient sorbents.
The increased volume of produced toxic sewage sludge requires suitable management and utilization. Biochar production is an eco-efficient technology that uses toxic wastes towards highly efficient materials in pharmaceuticals removal from water. The management of sewage sludge towards engineered biochar can solve several problems: waste volume minimalization and obtaining of the novel highly efficient sorbents. The objective of this work was an evaluation of the affinity of sewage sludge-derived biochars towards selected pharmaceuticals in water systems. In order to achieve high specific surface area and high carbon content of biochar different carrier gas conditions, preparation temperatures and different raw materials were tested. The maximum adsorption capacity was following: diclofenac - 92.7 mg/g; triclosan - 113 mg/g and naproxen - 127 mg/g. The best fitting of the experimental results revealed mainly pseudo-second order model. The adsorption of diclofenac can occur via pi-stacking interactions with the biochar surface mainly via Dubinin-Radushkevich model. Both interactions between the phenyl groups of triclosan molecules and phenol groups on biochar via hydrogen bonding, and non-covalent pi-pi stacking of aromatic groups of triclosan and biochar were responsible for monolayer surface coverage. The adsorption of naproxen was ascribed to Langmuir, Temkin and Dubinin-Radushkevich models and strong pi-pi electro-donor-acceptor interactions. (C) 2020 Elsevier Ltd. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Environmental Sciences

The antioxidant defense responses of Hordeum vulgare L. to polycyclic aromatic hydrocarbons and their derivatives in biochar-amended soil

Agnieszka Krzyszczak, Michal Dybowski, Izabela Josko, Magdalena Kusiak, Malgorzata Sikora, Bozena Czech

Summary: The impact of biochar on barley growth was assessed, and it was found that despite the low concentration of PAHs and their derivatives, oxidative stress was still induced in the plants.

ENVIRONMENTAL POLLUTION (2022)

Article Chemistry, Analytical

Microwave synthesis of biochar for environmental applications

Kamyar Shirvanimoghaddam, Bozena Czech, Sara Abdikheibari, Graham Brodie, Magdalena Konczak, Agnieszka Krzyszczak, Amani Al-Othman, Minoo Naebe

Summary: This paper discusses the principles and applications of microwave assisted pyrolysis, as well as the adsorption properties and other applications of biochar. The paper concludes that further research and optimization are needed for the development of microwave assisted pyrolysis biochar, but it has the potential to be a cost-effective, environmentally friendly, and tunable material for various applications.

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS (2022)

Article Green & Sustainable Science & Technology

Application of the engineered sewage sludge-derived biochar to minimize water eutrophication by removal of ammonium and phosphate ions from water

Magdalena Konczak, Milosz Huber

Summary: This study investigated the adsorption and desorption of phosphate and ammonium ions on engineered biochars derived from sewage sludge and willow. The results showed that different production conditions affected the adsorption and desorption properties of the biochars. Re-using these biochars in wastewater treatment can regulate the mobility and release rate of nutrients.

JOURNAL OF CLEANER PRODUCTION (2022)

Article Green & Sustainable Science & Technology

Facemask Global Challenges: The Case of Effective Synthesis, Utilization, and Environmental Sustainability

Kamyar Shirvanimoghaddam, Bozena Czech, Ram Yadav, Cemile Gokce, Laura Fusco, Lucia Gemma Delogu, Acelya Yilmazer, Graham Brodie, Amani Al-Othman, Adil K. Al-Tamimi, Jarret Grout, Minoo Naebe

Summary: Coronavirus disease (COVID-19) is a rapidly spreading pandemic that poses a severe threat to global public health. Human-to-human transmission of the virus is well established, primarily through aerosols and droplets. This review highlights the environmental challenges and risks associated with the surge in facemask production during the pandemic. It also discusses the potential of nanomaterial-based antiviral and self-cleaning facemasks as a sustainable solution.

SUSTAINABILITY (2022)

Article Environmental Sciences

Chemical properties of soil determine the persistence and bioavailability of polycyclic aromatic hydrocarbons in sewage sludge- or sewage sludge/biomass-derived biochar-amended soils*

Magdalena Konczak, Paulina Godlewska, Malgorzata Wisniewska, Patryk Oleszczuk

Summary: This study examines the effects of biochar derived from sewage sludge (BCSSL) or sewage sludge/biomass (BCSSLW) on the persistence and bioavailability of polycyclic aromatic hydrocarbons (PAHs) in soils with different properties. The results show that the content of organic solvent extractable PAHs decreases when biochar is applied to the soils, depending on pH and feedstock. Similarly, the content of freely dissolved PAHs also decreases. The bioavailability and persistence of PAHs in the biochar-amended soils are closely related to the chemical properties of the soils, as indicated by the significant relationships between PAH content and pH, cation exchange capacity, available nutrients, and dissolved organic carbon.

ENVIRONMENTAL POLLUTION (2023)

Article Chemistry, Physical

The Visible-Light-Driven Activity of Biochar-Doped TiO2 Photocatalysts in β-Blockers Removal from Water

Agata Kowalczyk, Bozena Zgardzinska, Karol Osipiuk, Katarzyna Jedruchniewicz, Katarzyna Tyszczuk-Rotko, Magdalena Gozdziuk, Haitao Wang, Bozena Czech

Summary: Water is essential for life on Earth, but the increasing global population has led to higher water consumption and increased production of wastewater. Current wastewater treatment techniques are not efficient enough to remove pharmaceuticals, highlighting the need for innovative approaches. This study investigates the photocatalytic oxidation of beta-blockers using modified TiO2 photocatalysts. The results show that solely relying on pollutant concentration reduction is insufficient for determining treatment method safety and additional ecotoxicity testing is necessary.

MATERIALS (2023)

Article Plant Sciences

Nitrogen Fertilization and Solvents as Factors Modifying the Antioxidant and Anticancer Potential of Arnica montana L. Flower Head Extracts

Danuta Sugier, Piotr Sugier, Joanna Jakubowicz-Gil, Urszula Gawlik-Dziki, Adrian Zajac, Beata Krol, Stanislaw Chmiel, Magdalena Konczak, Mateusz Piet, Roman Paduch

Summary: This study focuses on the flower heads of Arnica montana, an endemic and endangered medicinal plant in Europe. It reveals that nitrogen fertilization significantly affects the chemical composition, antioxidant activity, and anticancer activity of arnica extracts. Low doses of nitrogen fertilizer enhance LOX inhibition ability, while high doses decrease the content of secondary metabolites. Moreover, this study is the first report on the anticancer activity of A. montana water extracts, emphasizing the importance of water as a solvent in research.

PLANTS-BASEL (2023)

Article Environmental Sciences

Radially aligned hierarchical N-doped porous carbon beads derived from oil-sand asphaltene for long-life water filtration and wastewater treatment

Bijan Nasri-Nasrabadi, Bozena Czech, Ram Yadav, Kamyar Shirvanimoghaddam, Agnieszka Krzyszczak, Vishnu Unnikrishnan, Minoo Naebe

Summary: This study presents the application of waste-derived adsorbent for removing organic pollutants from water and wastewater. The adsorbent, made from asphaltene, consists of highly porous carbon beads with radially aligned macrochannels, which enhances solute diffusion and liquid accommodation capacity. N-doping further improves the hydrophilicity of the adsorbent and its absorption performance for organic solvents. The N-doped carbon beads effectively remove lopinavir (LNV) and ritonavir (RNV) from water and wastewater, with RNV exhibiting higher removal efficiency. The presence of co-pollutants in treated wastewater enhances the removal of LNV and RNV, and the toxicity of the solutions is reduced after the adsorption process.

SCIENCE OF THE TOTAL ENVIRONMENT (2023)

Article Engineering, Chemical

Enhanced degradation of tetracycline via Visible-light-assisted peroxymonosulfate activation over oxygen vacancy rich Fe2O3-CoFe2O4 heterostructures

Haiyan Zou, Yingying Liu, Linjie Ni, Shuangjiang Luo, Dmitry Moskovskikh, Patryk Oleszczuk, Bozena Czech, Jinfeng Lu, Tielong Li, Haitao Wang

Summary: In this study, oxygen vacancy (OV) rich Fe2O3-CoFe2O4 heterostructures were synthesized and tested for visible-light assisted peroxymonosulfate (PMS) activation. The Fe2O3-CoFe2O4/PMS/Vis system exhibited efficient degradation of tetracycline (TC) with a removal rate of 98.1% within 20 minutes under visible light. The presence of visible light not only enhanced TC degradation, but also increased the reusability and stability of Fe2O3-CoFe2O4 due to the replenishment of oxygen vacancies.

SEPARATION AND PURIFICATION TECHNOLOGY (2023)

Article Environmental Sciences

Estrogens and xenoestrogen residues in manure-based fertilizers and their potential ecological risks

Emmanuel Stephen Odinga, Xuwen Chen, Evance Omondi Mbao, Michael Gatheru Waigi, Fredrick Owino Gudda, Xian Zhou, Wanting Ling, Bozena Czech, Patryk Oleszczuk, Dyaaaldin Abdalmegeed, Yanzheng Gao

Summary: This study investigated the contamination levels and potential ecotoxicological risks of hormone substances and xenoestrogens in livestock manure-based fertilizers collected from 71 animal farms in China. The results showed varying frequencies and concentrations of these substances across different study locations. Compared with farm level manure, manure-based fertilizers had significantly reduced quantities of micropollutants. However, 38% of the fertilizers had risk quotients that exceeded 0.1, indicating medium to high risks to terrestrial organisms. Nonetheless, manure-based fertilizers had lower estrogenic risks compared to manure. This study emphasizes the importance of proper treatment of livestock manure and designing optimal fertilization strategies to mitigate the risks posed by hormone substances and xenoestrogens to agroecosystems.

JOURNAL OF ENVIRONMENTAL MANAGEMENT (2023)

Article Biochemistry & Molecular Biology

Plant-Waste-Derived Sorbents for Nitazoxanide Adsorption

Artur Sokolowski, Katarzyna Jedruchniewicz, Rafal Kobylecki, Robert Zarzycki, Krzysztof Rozylo, Haitao Wang, Bozena Czech

Summary: The increased application of drugs during the COVID-19 pandemic has led to higher drug concentrations in wastewater. Conventional wastewater treatment plants lack effective removal methods for these pollutants. Adsorption, particularly using plant waste-derived pelletized biochar, was found to effectively remove nitazoxanide, an antiparasitic drug used to treat SARS-CoV-2. The highest adsorption capacity was observed with biochar obtained from biogas production.

MOLECULES (2023)

Article Environmental Sciences

Microorganisms and their metabolites affect the content of polycyclic aromatic hydrocarbons and their derivatives in pyrolyzed material

Agnieszka Krzyszczak, Michal P. Dybowski, Bozena Czech

Summary: This study examined the effect of biological agents on the physicochemical characteristics and content of PAHs and their derivatives in biochar. The results showed that enzymatic aging decreased the content of PAHs and their derivatives, while biological aging reduced their bioavailability.

SCIENCE OF THE TOTAL ENVIRONMENT (2023)

Article Engineering, Environmental

Rational construction of micron-sized zero-valent iron/graphene composite for enhanced Cr(VI) removal from aqueous solution

Haitao Wang, Yue Wang, Zhenglong Liu, Shuangjiang Luo, Valentin Romanovski, Xianqiang Huang, Bozena Czech, Hongwen Sun, Tielong Li

Summary: This study reports the rational construction of mZVI/graphene composite (mZVI/G) through a simple and environmental-friendly mechanochemical method, achieving efficient removal of Cr(VI) in wastewater treatment.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2022)

Article Engineering, Environmental

Elucidating the crystal structure-dependent Cd2+-uptake property of benzimidazolium ionic liquid immobilized into macroporous polystyrene

Shahlo S. Daminova, Zukhra C. Kadirova, Khasan T. Sharipov, Quvondiq S. Sanaqulov, Dilnoza S. Rakhmonova, Masahiro Miyauchi, Yuichi Sugai, Bozena Czech, Mirabbos Hojamberdiev

Summary: In this study, the crystal structures of two ionic liquids and a cadmium complex are characterized, and their sorption capacity for Cd2+ from aqueous solution is evaluated. The successful immobilization of organic ligands into a commercial polymeric sorbent is confirmed. The novel composite material shows promising adsorption ability for Cd2+ removal.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2022)

Article Green & Sustainable Science & Technology

Relative evaluation of probabilistic methods for spatio-temporal wind forecasting

Lars odegaard Bentsen, Narada Dilp Warakagoda, Roy Stenbro, Paal Engelstad

Summary: This study investigates uncertainty modeling in wind power forecasting using different parametric and non-parametric methods. Johnson's SU distribution is found to outperform Gaussian distributions in predicting wind power. This research contributes to the literature by introducing Johnson's SU distribution as a candidate for probabilistic wind forecasting.

JOURNAL OF CLEANER PRODUCTION (2024)

Article Green & Sustainable Science & Technology

Comparison of ethane recovery processes for lean gas based on a coupled model

Xing Liu, Qiuchen Wang, Yunhao Wen, Long Li, Xinfang Zhang, Yi Wang

Summary: This study analyzes the characteristics of process parameters in three lean gas ethane recovery processes and establishes a prediction and multiobjective optimization model for ethane recovery and system energy consumption. A new method for comparing ethane recovery processes for lean gas is proposed, and the addition of extra coolers improves the ethane recovery. The support vector regression model based on grey wolf optimization demonstrates the highest prediction accuracy, and the multiobjective multiverse optimization algorithm shows the best optimization performance and diversity in the solutions.

JOURNAL OF CLEANER PRODUCTION (2024)

Article Green & Sustainable Science & Technology

A novel deep-learning framework for short-term prediction of cooling load in public buildings

Cairong Song, Haidong Yang, Xian-Bing Meng, Pan Yang, Jianyang Cai, Hao Bao, Kangkang Xu

Summary: The paper proposes a novel deep learning-based prediction framework, aTCN-LSTM, for accurate cooling load predictions. The framework utilizes a gate-controlled multi-head temporal convolutional network and a sparse probabilistic self-attention mechanism with a bidirectional long short-term memory network to capture both temporal and long-term dependencies in the cooling load sequences. Experimental results demonstrate the effectiveness and superiority of the proposed method, which can serve as an effective guide for HVAC chiller scheduling and demand management initiatives.

JOURNAL OF CLEANER PRODUCTION (2024)

Article Green & Sustainable Science & Technology

The impact of social interaction and information acquisition on the adoption of soil and water conservation technology by farmers: Evidence from the Loess Plateau, China

Zhe Chen, Xiaojing Li, Xianli Xia, Jizhou Zhang

Summary: This study uses survey data from the Loess Plateau in China to evaluate the impact of social interaction on the adoption of soil and water conservation (SWC) technology by farmers. The study finds that social interaction increases the likelihood of farmers adopting SWC, and internet use moderates this effect. The positive impact of social interaction on SWC adoption is more pronounced for farmers in larger villages and those who join cooperative societies.

JOURNAL OF CLEANER PRODUCTION (2024)

Article Green & Sustainable Science & Technology

Study on synergistic heat transfer enhancement and adaptive control behavior of baffle under sudden change of inlet velocity in a micro combustor

Chenghua Zhang, Yunfei Yan, Kaiming Shen, Zongguo Xue, Jingxiang You, Yonghong Wu, Ziqiang He

Summary: This paper reports a novel method that significantly improves combustion performance, including heat transfer enhancement under steady-state conditions and adaptive stable flame regulation under velocity sudden increase.

JOURNAL OF CLEANER PRODUCTION (2024)