Indirect Access to Carbene Adducts of Bismuth- and Antimony-Substituted Phosphaketene and Their Unusual Thermal Transformation to Dipnictines and [(NHC)2OCP][OCP]

Crystalline BP-Doped Phenanthryne via Photolysis of The Elusive Boraphosphaketene

(2020) Wenlong Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carbodicarbene Bismaalkene Cations: Unravelling the Complexities of Carbene versus Carbone in Heavy Pnictogen Chemistry

(2020) Jacob Walley et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Beryllium Halide Complexes Incorporating Neutral or Anionic Ligands: Potential Precursors for Beryllium Chemistry

(2019) Albert Paparo et al.   Chemistry-An Asian Journal

Bi(I)-Catalyzed Transfer-Hydrogenation with Ammonia-Borane

(2019) Feng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Syntheses, Structures, and Bonding Analyses of Carbene-Stabilized Stibinidenes

(2019) Julia Krüger et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

An antimony(V) dication as a Z-type ligand: Turning on styrene activation at gold

(2019) Ying-Hao Lo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Redox-Confused Bismuth(I/III) Triamide with a T-Shaped Planar Ground State

(2019) Marcus B. Kindervater et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

B(C 6 F 5 ) 3 ‐Enabled Synthesis of a Cyclic cis ‐Arsaphosphene

(2019) Meera Mehta et al.   CHEMISTRY-A EUROPEAN JOURNAL

Bismuth Pyridine Dipyrrolide Complexes: a Transient Bi(II) Species Which Ring Opens Cyclic Ethers

(2019) Zoë R. Turner   INORGANIC CHEMISTRY

The chemistry of the 2-phosphaethynolate anion

(2018) Hansjörg Grützmacher et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Isolable Phosphaethynolatoborane and Its Reactivity

(2018) Daniel W. N. Wilson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Limitations of Steric Bulk: Towards Phospha-germynes and Phospha-stannynes

(2018) Alexander Hinz et al.   CHEMISTRY-A EUROPEAN JOURNAL

An isolable magnesium diphosphaethynolate complex

(2018) Robert J. Gilliard et al.   DALTON TRANSACTIONS

2-Phospha- and 2-Arsaethynolates - Versatile Building Blocks in Modern Synthetic Chemistry

(2018) Lothar Weber   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Synthesis and reactivity of rare-earth metal phosphaethynolates

(2018) Sebastian Bestgen et al.   DALTON TRANSACTIONS

Highly Reactive Cyclic(alkyl)(amino) Carbene- and N-Heterocyclic Carbene-Bismuth(III) Complexes: Synthesis, Structure, and Computations

(2018) Guocang Wang et al.   INORGANIC CHEMISTRY

N-nacnac Stabilized Tetrelenes: Formation of an N,P-Heterocyclic Germylene via C-C Bond Insertion

(2018) Dinh Cao Huan Do et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

London Dispersion Interactions in Pnictogen Cations [ECl 2 ] + and [E=E] 2+ (E=P, As, Sb) Supported by Anionic N ‐Heterocyclic Carbenes

(2018) Luong Phong Ho et al.   CHEMISTRY-A EUROPEAN JOURNAL

P,P-Dimethylformylphosphine: The Phosphorus Analogue of N,N-Dimethylformamide

(2018) Kevin M. Szkop et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Quantum Chemical Calculations on CHOP Derivatives—Spanning the Chemical Space of Phosphinidenes, Phosphaketenes, Oxaphosphirenes, and COP− Isomers

(2018) Alicia Rey et al.   MOLECULES

Selective Derivatization of a Hexaphosphane from Functionalization of White Phosphorus

(2017) Felix Hennersdorf et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Spectroscopic Characterization, Computational Investigation, and Comparisons of ECX– (E = As, P, and N; X = S and O) Anions

(2017) Gao-Lei Hou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Formation of a Uranium-Bound η1-Cyaphide (CP–) Ligand via Activation and C–O Bond Cleavage of Phosphaethynolate (OCP–)

(2017) Christopher J. Hoerger et al.   ORGANOMETALLICS

N-Heterocyclic Carbenes as Promotors for the Rearrangement of Phosphaketenes to Phosphaheteroallenes: A Case Study for OCP to OPC Constitutional Isomerism

(2016) Zhongshu Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Stable Heterocyclic Amino(phosphanylidene-σ4 -phosphorane) Germylene

(2016) Natalia Del Rio et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From a Phosphaketenyl-Functionalized Germylene to 1,3-Digerma-2,4-diphosphacyclobutadiene

(2016) Shenglai Yao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Simple access to ionic liquids and organic salts containing the phosphaethynolate (PCO−) and Zintl (Sb113−) anions

(2016) Maximilian Jost et al.   CHEMICAL COMMUNICATIONS

N-Heterocyclic carbene phosphaketene adducts as precursors to carbene–phosphinidene adducts and a rearranged π-system

(2016) Zhongshu Li et al.   CHEMICAL COMMUNICATIONS

From the parent phosphinidene–carbene adduct NHCPH to cationic P4-rings and P2-cycloaddition products

(2016) Andreas Beil et al.   DALTON TRANSACTIONS

Transition-Metal-like Behavior of Main Group Elements: Ligand Exchange at a Phosphinidene

(2016) Max M. Hansmann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isolation of a Heavier Cyclobutadiene Analogue: 2,4-Digerma-1,3-diphosphacyclobutadiene

(2016) Yile Wu et al.   ORGANOMETALLICS

Isolation of Au-, Co-η1PCO and Cu-η2PCO complexes, conversion of an Ir–η1PCO complex into a dimetalladiphosphene, and an interaction-free PCO anion

(2016) Liu Liu et al.   Chemical Science

N-heterocyclic carbene induced reductive coupling of phosphorus tribromide. Isolation of a bromine bridged P–P bond and its subsequent reactivity

(2016) Jordan B. Waters et al.   Chemical Science

A stable phosphanyl phosphaketene and its reactivity

(2015) Zhongshu Li et al.   DALTON TRANSACTIONS

Synthesis of Selected Cationic Pnictanes [LnPnX3–n]n+ (L = Imidazolium-2-yl; Pn = P, As; n = 1–3) and Replacement Reactions with Pseudohalogens

(2015) F. D. Henne et al.   INORGANIC CHEMISTRY

Uranium and thorium complexes of the phosphaethynolate ion

(2015) Clément Camp et al.   Chemical Science

Metal-Free Stabilization of Monomeric Antimony(I): A Carbene-Supported Stibinidene

(2014) Christopher L. Dorsey et al.   CHEMISTRY-A EUROPEAN JOURNAL

Is the phosphaethynolate anion, (OCP)−, an ambident nucleophile? A spectroscopic and computational study

(2014) Dominikus Heift et al.   DALTON TRANSACTIONS

Low-Coordinate Bismuth Cations

(2014) Ryan J. Schwamm et al.   INORGANIC CHEMISTRY

Oxidative Addition across Sb–H and Sb–Sb Bonds by an Osmium Carbonyl Cluster: Trapping the Intermediate

(2014) Ying-Zhou Li et al.   ORGANOMETALLICS

The 2-Phosphaethynolate Anion: A Convenient Synthesis and [2+2] Cycloaddition Chemistry

(2013) Andrew R. Jupp et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Single-site bismuth alkoxide catalysts for the ring-opening polymerization of lactide

(2013) Vagulejan Balasanthiran et al.   DALTON TRANSACTIONS

The first bismuth–NHC complexes

(2013) Antonino Aprile et al.   DALTON TRANSACTIONS

Coulomb repulsion versus cycloaddition: formation of anionic four-membered rings from sodium phosphaethynolate, Na(OCP)

(2013) Dominikus Heift et al.   DALTON TRANSACTIONS

Coordination of CO to low-valent phosphorus centres and other related P–C bonding situations. A theoretical case study

(2013) Gerd von Frantzius et al.   Chemical Science

Synthesis and Characterization of Terminal [Re(XCO)(CO)2(triphos)] (X=N, P): Isocyanate versus Phosphaethynolate Complexes

(2012) Simone Alidori et al.   CHEMISTRY-A EUROPEAN JOURNAL

Incorporating different secondary building units of {Bi2}, {Bi8} and {Bi10} to construct diversity of luminescent bismuth–organic frameworks

(2012) Xiao-Ping Zhang et al.   DALTON TRANSACTIONS

Phosphination of Carbon Monoxide: A Simple Synthesis of Sodium Phosphaethynolate (NaOCP)

(2011) Florian Frank Puschmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carbene Stabilization of Highly Reactive Main-Group Molecules

(2011) Yuzhong Wang et al.   INORGANIC CHEMISTRY

Bismuthenium-pnictonium dications [R′BiPnR3]2+ (Pn = As, Sb) containing carbenoid bismuth centers and rare Bi–Sb bonds

(2010) Eamonn Conrad et al.   CHEMICAL COMMUNICATIONS

Isolation of crystalline carbene-stabilized P2-radical cations and P2-dications

(2010) Olivier Back et al.   Nature Chemistry

Carbene-Stabilized Diphosphorus

(2008) Yuzhong Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY