Article
Physics, Applied
Yoshihiro Shimazu, Shotaro Ono, Takaaki Miyazawa, Kazuya Yamada
Summary: The study shows that the carrier density of Al-contacted MoS2 flakes is 10 times higher than that of Au-contacted MoS2 flakes, indicating a doping effect induced by Al contact. Additionally, the Al-contacted flakes exhibit ohmic contact and metallic conductivity down to 5 K, which is distinct from the properties of Au-contacted MoS2 flakes.
JAPANESE JOURNAL OF APPLIED PHYSICS
(2021)
Review
Physics, Applied
Yan Wang, Manish Chhowalla
Summary: A key challenge in fabricating devices out of 2D materials is making good electrical contact, especially for TMDs. Lack of high-quality, low-contact-resistance P-type and N-type contacts on TMDs has limited progress towards next-generation low-power devices. This Expert Recommendation provides strategies for making clean van der Waals contacts on monolayered TMD semiconductors and discusses prospects for achieving quantum conductance.
NATURE REVIEWS PHYSICS
(2022)
Article
Materials Science, Ceramics
Bin Li, Qiankun Ju, Wenting Hong, Qian Cai, Jinxin Lin, Wei Liu
Summary: The study successfully synthesized a novel molybdenum disulfide using chemical vapor deposition, with the synthesis reaction being carried out in an inert gas environment. The use of a high concentration of molybdenum precursor helped control the morphology of molybdenum disulfide, leading to the innovative method for synthesizing bilayer molybdenum disulfide.
CERAMICS INTERNATIONAL
(2021)
Article
Chemistry, Multidisciplinary
Xiumei Zhang, Luyao Huangfu, Zhengjian Gu, Shaoqing Xiao, Jiadong Zhou, Haiyan Nan, Xiaofeng Gu, Kostya (Ken) Ostrikov
Summary: In this study, large-area vertical MoS2/WS2 heterostructures were synthesized using single-step confined-space chemical vapor epitaxy. By switching the H-2 flow on and off, two different kinds of heterostructures can be obtained, both with high quality. Photodetectors based on isolated MoS2/WS2 heterostructures exhibit excellent performance.
Article
Chemistry, Multidisciplinary
Han Li, Yating Ma, Zhongjie Xu, Xiang'ai Cheng, Tian Jiang
Summary: This study observed anomalous interlayer coupling and giant PL enhancement in artificially twisted bilayers of MoS2, laying the groundwork for future advancements and applications beyond TMDCs monolayers.
Article
Chemistry, Multidisciplinary
Preeti K. Poddar, Yu Zhong, Andrew J. Mannix, Fauzia Mujid, Jaehyung Yu, Ce Liang, Jong-Hoon Kang, Myungjae Lee, Saien Xie, Jiwoong Park
Summary: Photolithography and electron-beam lithography are commonly used methods for making nanoscale devices, but they disturb the electrical properties of 2D materials. We propose a resist-free lithography method using laser patterning and resist-free electrode transfer, which avoids unintentional modification to the 2D materials. This method enables the fabrication of large arrays of field-effect transistors and reveals the impact of solvents on the electrical conductivity of MoS2.
Article
Chemistry, Multidisciplinary
Cheolmin Park, Seung Hun Han, Hyeok Jun Jin, Woonggi Hong, Sung-Yool Choi
Summary: In order to solve the image deterioration caused by the pixel miniaturization in high-resolution CMOS image sensor technology, a photodiode with an enhanced mechanism based on a distinctive device structure is needed. This study introduced a photodiode consisting of gold nanoparticles/monolayer graphene/n-type trilayer MoS2/p-type Si bulk, which achieved ultrafast rising/falling times due to the narrow depletion width resulting from the 2D/3D heterojunction. To compensate for the expected low absorbance, plasmonic gold nanoparticles on monolayer graphene were introduced, resulting in broadband enhanced EQE.
Article
Nanoscience & Nanotechnology
Woonggi Hong, Cheolmin Park, Gi Woong Shim, Sang Yoon Yang, Sung-Yool Choi
Summary: In this study, MoS2 thin films were successfully synthesized using the MOCVD method, with controlled number of layers, growth rate, and electrical properties. The growth map guided the growth of MoS2, enabling control over growth rate, domain density, and domain size. Electrical performance of the MOCVD-grown MoS2 with five layers exhibited promising on/off current ratio and field effect mobility.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Multidisciplinary
Jing Guo, Ruixuan Peng, Xiaolong Zhang, Zeqin Xin, Enze Wang, Yonghuang Wu, Chenyu Li, Shoushan Fan, Run Shi, Kai Liu
Summary: Scaling up the CVD growth of monolayer TMDCs is in high demand for practical applications. In this work, uniform monolayer MoS2 on a large scale is achieved by delicate control of gas flows of precursors using a well-designed p-CNT film. The as-grown monolayer MoS2 shows good uniformity and advances their applications in high-performance electronic devices.
Article
Chemistry, Multidisciplinary
Jing Li, Shuang Wang, Qi Jiang, Haoji Qian, Shike Hu, He Kang, Chen Chen, Xiaoyi Zhan, Aobo Yu, Sunwen Zhao, Yanhui Zhang, Zhiying Chen, Yanping Sui, Shan Qiao, Guanghui Yu, Songang Peng, Zhi Jin, Xinyu Liu
Summary: This study successfully achieved the epitaxial growth of single crystal MoS2 (SC-MoS2) monolayer on an Au (111) film, allowing for the unidirectional alignment of MoS2 domains with seamless stitching into a single crystal monolayer without GBs formation. This breakthrough in growth mode provides a new direction for the practical applications of TMDCs in microelectronics.
Article
Physics, Multidisciplinary
Li Lu, Zhang Yang-Kun, Shi Dong-Xia, Zhang Guang-Yu
Summary: The research summarized the preparation of monolayer MoS2 films and the characteristics of devices with excellent optical and electrical properties. It is of guiding significance for the basic and application research of MoS2, and is also universal and instructive for other 2D transition metal dichalcogenides.
ACTA PHYSICA SINICA
(2022)
Article
Chemistry, Physical
Seoungwoong Park, Jaekwang Song, Tae Kyung Kim, Kwang-Hun Choi, Seok-Ki Hyeong, Minchul Ahn, Hwa Rang Kim, Sukang Bae, Seoung-Ki Lee, Byung Hee Hong
Summary: This study demonstrates an omnidirectionally stretchable MoS2 platform with laser-induced strained structures. The platform has great potential for applications in wearable technology, including logic devices and sensors.
Article
Chemistry, Physical
Ruijie Zhang, Yajing Sun, Fei Jiao, Lin Li, Dechao Geng, Wenping Hu
Summary: As a new paradigm of material science, two-dimensional (2D) heterostructured composites have attracted extensive interests because of combining the collective advantages and collaborative characteristics of individual building blocks. Molybdenum disulfide (MoS2) has demonstrated great promise as a low-cost substitute to platinum-based catalysts for electrochemical hydrogen production. However, the broad adoption of MoS2 is hindered by its limited number of active sites and low inherent electrical conductivity. One of the promising methods to further activate MoS2 is coupling engineering. Here, we demonstrate for the first time the synthesis of 2D MXene-MoS2 nanocomposites through chemical vapor deposition (CVD) approach, thus leading to precise design in structure type and orientation. The computational results show that nanocomposites have metallic properties. Owing to their unique 2D/2D structure, MXene-MoS2 nanocomposites exhibit more active catalytic sites, resulting in higher electrochemical performance, as inherited from parent excellent characteristics, and a much lower overpotential of similar to 69 mV at a current density of 10 mA center dot cm(-2) is achieved. This work paves the way to employ CVD method by coupling engineering to construct 2D nanocomposites for energy storage applications.
Article
Electrochemistry
Zuzanna Zarach, Mariusz Szkoda, Konrad Trzcinski, Marcin Lapinski, Grzegorz Trykowski, Andrzej P. Nowak
Summary: This paper presents several approaches to synthesize molybdenum-based electrode materials for supercapacitors, including anodization, hydrothermal process, and annealing. The study focuses on the Pt-surface modification through repetitive cycling in sulfuric acid, which effectively improves the electrochemical performance of the electrode material. With increasing number of cycles, the capacitance value increases significantly, and the pseudocapacitance contribution in energy storage processes also increases. The formation of mixed molybdenum oxides with oxygen vacancies is identified as the cause of the observed changes. Pt-surface modification of MoS2 provides a novel approach for high-performance electrode materials in supercapacitors.
ELECTROCHIMICA ACTA
(2022)
Article
Chemistry, Physical
Shengxue Zhou, Lina Liu, Shuang Cui, Xiaofan Ping, Dake Hu, Liying Jiao
Summary: A new method using chemical vapor deposition (CVD) with K2WS4 as growth precursor was developed for the growth of large and high-quality WS(2) monolayers, achieving a fast growth rate and high electrical performance. The obtained WS(2) flakes were 2D single crystals with low defect density, demonstrating the potential for producing high quality 2D semiconductors for future nanoelectronics.
Article
Chemistry, Multidisciplinary
Feier Fang, Yi Wan, Henan Li, Shaofan Fang, Fu Huang, Bo Zhou, Ke Jiang, Vincent Tung, Lain-Jong Li, Yumeng Shi
Summary: This study integrates two-dimensional perovskites with transition metal dichalcogenide monolayers to enhance photosensitivity and photoresponse. The vertically stacked heterostructure photodetector shows high detectivity and fast response time.
Article
Chemistry, Multidisciplinary
Chang-Ju Liu, Yi Wan, Lain-Jong Li, Chih-Pin Lin, Tuo-Hung Hou, Zi-Yuan Huang, Vita Pi-Ho Hu
Summary: Research indicates that monolayer 2DM FET with superior electrostatics is beneficial in reducing read-write conflicts in SRAM cells at scaled technology nodes, while monolayer 2DM SRAM shows lower cell read access time and write time compared to bilayer and trilayer 2DM SRAM cells at fixed leakage power.
ADVANCED MATERIALS
(2022)
Review
Chemistry, Multidisciplinary
Yi Wan, Jui-Han Fu, Chih-Piao Chuu, Vincent Tung, Yumeng Shi, Lain-Jong Li
Summary: This review provides a systematic summary of the critical factors for synthesizing single-orientation 2D layers, with a focus on the role of atomic edge-guided epitaxial growth in the wafer-scale growth of single-crystal 2D layers.
CHEMICAL SOCIETY REVIEWS
(2022)
Article
Materials Science, Multidisciplinary
Pin Tian, Libin Tang, Jinzhong Xiang, Shu Ping Lau, Shouzhang Yuan, Dengquan Yang, Lain-Jong Li, Kar Seng Teng
Summary: The study developed an easy method for liquid-phase catalytic growth of graphene, that can transform graphene quantum dots into graphene films at room temperature. This method has advantages of environmental-friendliness, high yields, low cost, and a wide choice of substrates. The bandgap of the graphene films can be tuned by post-annealing.
JOURNAL OF MATERIALS CHEMISTRY C
(2022)
Article
Chemistry, Multidisciplinary
Bo Liu, Ying-Feng Chang, Juzhe Li, Xu Liu, Le An Wang, Dharmendra Verma, Hanyuan Liang, Hui Zhu, Yudi Zhao, Lain-Jong Li, Tuo-Hung Hou, Chao-Sung Lai
Summary: The fast development of the Internet of Things (IoT) brings security challenges, and a true random number generator (TRNG) based on stochastic physical phenomena, such as the Bi2O2Se-based TRNG, shows potential in ensuring data security. Compared to traditional memristors, the Bi2O2Se layer has unique properties for more reliable analogue/digital random number generation.
Article
Chemistry, Multidisciplinary
Hao-Yu Chen, Hung-Chang Hsu, Chuan-Chun Huang, Ming-Yang Li, Lain-Jong Li, Ya-Ping Chiu
Summary: This study utilizes light-modulated scanning tunneling microscopy and quasiparticle interference technique to reveal the unexplored momentum-forbidden electronic quantum states in transition metal dichalcogenide monolayers. The results highlight the large spin-splitting energy and the band renormalization dependent on photoexcited carrier density, emphasizing the importance of excited-state distribution in band renormalization.
Article
Chemistry, Multidisciplinary
Merfat M. Alsabban, Mathan Kumar Eswaran, Karthik Peramaiah, Wandi Wahyudi, Xiulin Yang, Vinoth Ramalingam, Mohamed N. Hedhili, Xiaohe Miao, Udo Schwingenschlogl, Lain-Jong Li, Vincent Tung, Kuo-Wei Huang
Summary: This paper reports a electrocatalyst with activity and durability in an alkaline medium, and reveals its high efficiency reaction mechanism through theoretical studies.
Article
Chemistry, Multidisciplinary
Caleb Z. Zerger, Linsey K. Rodenbach, Yi-Ting Chen, Benjamin Safvati, Morgan Z. Brubaker, Steven Tran, Tse-An Chen, Ming-Yang Li, Lain-Jong Li, David Goldhaber-Gordon, Hari C. Manoharan
Summary: This research demonstrates that the Cu(111) surface state under wafer-scale hBN is homogeneous in energy and spectral weight over nanometer length scales and across atomic terraces. However, a new spectral feature that is not observed on bare Cu(111) varies with atomic registry and shares the spatial periodicity of the hBN/Cu(111) moire.
Article
Chemistry, Physical
Cong Wang, Chao Xu, Xuyun Guo, Ning Zhang, Jianmin Yan, Jiewei Chen, Wei Yu, Jing-Kai Qin, Ye Zhu, Lain-Jong Li, Yang Chai
Summary: In this study, a Cu foil-assisted alloy-buffer-controlled growth method was designed to epitaxially grow aligned single-crystalline 2D tellurium (Te) on an insulating mica substrate. The in-situ formation of Cu-Te alloy played a key role in alleviating the spatial and temporal non-uniformity of precursor, resulting in the controllable growth of high-quality and highly aligned 2D Te.
Article
Materials Science, Multidisciplinary
Hsiang-Ting Lin, Chiao-Yun Chang, Cheng-Li Yu, Andrew Boyi Lee, Shih-Yu Gu, Li-Syuan Lu, Yu-Wei Zhang, Shih-Yen Lin, Wen-Hao Chang, Shu-Wei Chang, Min-Hsiung Shih
Summary: This study investigates dual-color continuous-wave microcavity lasers by integrating WSe2 monolayer and CdSe quantum dots into a single microdisk cavity. The results show that adding CdSe quantum dots can reduce the laser threshold of WSe2 monolayer and expand the wavelength range of TMDC-based compact lasers.
ADVANCED OPTICAL MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Meng-Kai Lin, Guan-Hao Chen, Ciao-Lin Ho, Wei-Chen Chueh, Joseph Andrew Hlevyack, Chia-Nung Kuo, Tsu-Yi Fu, Juhn-Jong Lin, Chin Shan Lue, Wen-Hao Chang, Noriaki Takagi, Ryuichi Arafune, Tai-Chang Chiang, Chun-Liang Lin
Summary: Monolayer transition metal dichalcogenides show tunability in electronic properties, with bandgap modulation possible through control of tunneling current. Monolayer PtTe2 exhibits a reversible semiconductor-to-metal transition at moderate tunneling current, attributed to its surface electronic structure coupling with the tunneling tip.
Article
Chemistry, Multidisciplinary
Jun-Ru Chang, Po-Hsun Ho, Chun-Hsiang Chen, Chun-Hao Chiang, Cheng-Hung Hou, Min-Chuan Shih, Hung-Chang Hsu, Wen-Hao Chang, Jing-Jong Shyue, Ya-Ping Chiu, Chun-Wei Chen
Summary: The researchers developed a reliable method for contact doping in 2D electronics, which effectively reduces contact resistance. Through a two-step doping process, strong and hysteresis-free doping was achieved, suitable for the commonly used transition-metal dichalcogenides. The method resulted in a record-high sheet conductance and carrier concentration in monolayer MoS2 devices.
Article
Geochemistry & Geophysics
Hengrong Zhang, Lizhi Xiao, Min Wang, Xinmin Ge, Xiangyang Hu, Wei Tan
Summary: This study investigates the influential factors on gas breakthrough pressure in marine shale gas reservoirs, such as pore size distribution, mineral composition, and organic geochemical properties. The results show that gas breakthrough capability in shale is influenced by factors such as mineral types, pore radius, and specific surface areas. Additionally, organic geochemical properties also have an impact on gas breakthrough capability. The breakthrough pressure can serve as a significant parameter for evaluating shale gas reservoir quality.
Article
Nanoscience & Nanotechnology
Jui-Han Fu, Jiacheng Min, Che-Kang Chang, Chien-Chih Tseng, Qingxiao Wang, Hayato Sugisaki, Chenyang Li, Yu-Ming Chang, Ibrahim Alnami, Wei-Ren Syong, Ci Lin, Feier Fang, Lv Zhao, Tzu-Hsuan Lo, Chao-Sung Lai, Wei-Sheng Chiu, Zih-Siang Jian, Wen-Hao Chang, Yu-Jung Lu, Kaimin Shih, Lain-Jong Li, Yi Wan, Yumeng Shi, Vincent Tung
Summary: The large-scale batch growth of single-crystal 2D semiconducting transition metal dichalcogenides (TMDs) is crucial for pushing the limits of semiconductor technology. This study demonstrates that the interaction between TMD grains and the exposed oxygen-aluminium atomic plane in sapphire plays a more dominant role than step-edge docking in controlling the single-crystal epitaxy of these materials. Reconstructing the surfaces of the sapphire substrate to a single type of atomic plane enables the epitaxial growth of TMDs without the aid of step edges.
NATURE NANOTECHNOLOGY
(2023)
Article
Energy & Fuels
Si-Hui Luo, Li-Zhi Xiao, Yan Jin, Guang-Zhi Liao, Bin-Sen Xu, Jun Zhou, Can Liang
Summary: In this paper, a data processing framework based on dictionary learning is proposed to improve the quality of low field NMR echo data. The results show that dictionary learning can significantly improve the quality of NMR echo data with high noise level and effectively improve the accuracy and reliability of inversion results.