4.7 Article

P-n junctions based on CuO-decorated ZnO nanowires for ethanol sensing application

期刊

APPLIED SURFACE SCIENCE
卷 538, 期 -, 页码 -

出版社

ELSEVIER
DOI: 10.1016/j.apsusc.2020.148140

关键词

P-n junction; CuO-ZnO composite; Nanowire; Ethanol; Gas sensing

资金

  1. National Natural Science Foundation of China [51674067, 51422402]
  2. Fundamental Research Funds for the Central Universities [N180102032, N180106002, N180408018]
  3. Liaoning Revitalization Talents Program [XLYC1807160]
  4. Open Foundation of State Environmental Protection Key Laboratory of Mineral Metallurgical Resources Utilization and Pollution Control [HB201902]
  5. China Scholarship Council (CSC)

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CuO-ZnO p-n junctions were constructed by precipitating CuO nanoparticles on the surface of ZnO nanowires, resulting in an enhancement of gas sensing performance, specifically in ethanol sensing. The distinct sensing behaviors of the sensors were discussed in relation to several factors and considerations.
CuO-ZnO p-n junctions were constructed by precipitating CuO nanoparticles on the surface of ZnO nanowires followed by an annealing process. The molar ratio of Cu to Zn in the final composites was controlled by regulating Cu content in the precursor solution. XRD, SEM, TEM, EDS, and XPS were used for the structural characterization of the prepared samples. The results confirmed that the monoclinic CuO nanoparticles were closely and uniformly attached on the surface of the hexagonal ZnO nanowires to form the p-n junctions. Notably, the one-dimensional structure of the host ZnO nanowires was well-maintained during the p-n junction construction process. Five sensors based on CuO-ZnO p-n junction nanowires with different Cu/Zn ratios as well as the pure ZnO nanowires were fabricated and their gas sensing performance was systematically compared. The formation of CuO-ZnO p-n junction effectively enhanced the ethanol sensing properties of the host pure ZnO nanowires. And 5%CuO-ZnO exhibited the highest ethanol response at the operating temperature of 300 degrees C, which was about 4 times higher than that of the pure ZnO. Several factors and considerations were then discussed for the explanation of the distinct sensing behaviors of these sensors.

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