Harnessing Radical Chemistry via Electrochemical Transition Metal Catalysis

Site-Selective C–H Functionalization via Synergistic Use of Electrochemistry and Transition Metal Catalysis

(2020) Ke-Jin Jiao et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalyzing Electrosynthesis: A Homogeneous Electrocatalytic Approach to Reaction Discovery

(2020) Juno C. Siu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Asymmetric Electrochemical Transformation

(2020) Xihao Chang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Chain-Walking Cross-Electrophile Coupling of Alkyl and Aryl Halides and Olefin Hydroarylation Enabled by Electrochemical Reduction

(2020) Gadde Sathish Kumar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dual electrocatalysis enables enantioselective hydrocyanation of conjugated alkenes

(2020) Lu Song et al.   Nature Chemistry

Microfluidic electrochemistry for single-electron transfer redox-neutral reactions

(2020) Yiming Mo et al.   SCIENCE

Single Electron Activation of Aryl Carboxylic Acids

(2020) Xiao-Qiang Hu et al.   iScience

Electrochemically Promoted Nickel-Catalyzed Carbon–Sulfur Bond Formation

(2019) Yang Wang et al.   ACS Catalysis

Mn-Mediated Electrochemical Trifluoromethylation/C(sp2)–H Functionalization Cascade for the Synthesis of Azaheterocycles

(2019) Zhenxing Zhang et al.   ORGANIC LETTERS

One-Pot Electrochemical Nickel-Catalyzed Decarboxylative Sp2–Sp3 Cross-Coupling

(2019) Takaoki Koyanagi et al.   ORGANIC LETTERS

Electrochemically Driven, Ni-Catalyzed Aryl Amination: Scope, Mechanism, and Applications

(2019) Yu Kawamata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Thiolation of Aryl Halides and Heteroaryl Halides through Electrochemistry

(2019) Dong Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lewis-Acid-Catalyzed Asymmetric Electrochemical Alkylation

(2019) Qinglin Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Formal Aza-Wacker Cyclization by Tandem Electrochemical Oxidation and Copper Catalysis

(2019) Xiangli Yi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Persistent Radical Effect in Organic Synthesis

(2019) Dirk Leifert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Electrochemical Catalysis

(2019) Qifeng Lin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Three-Component Chlorophosphinoylation of Alkenes via Anodically Coupled Electrolysis

(2019) Lingxiang Lu et al.   SYNLETT

Proton-Coupled Electron Transfer Enables Tandem Radical Relay for Asymmetric Copper-Catalyzed Phosphinoylcyanation of Styrenes

(2019) Guoyu Zhang et al.   ORGANIC LETTERS

Enantioselective Electroreductive Coupling of Alkenyl and Benzyl Halides via Nickel Catalysis

(2019) Travis J. DeLano et al.   ACS Catalysis

New Bisoxazoline Ligands Enable Enantioselective Electrocatalytic Cyanofunctionalization of Vinylarenes

(2019) Niankai Fu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Electrochemical Phosphorylation of Aryl Bromides

(2019) Ya Bai et al.   ORGANIC LETTERS

Chemistry with Electrochemically Generated N-Centered Radicals

(2019) Peng Xiong et al.   ACCOUNTS OF CHEMICAL RESEARCH

Manganese-Catalyzed Electrochemical Deconstructive Chlorination of Cycloalkanols via Alkoxy Radicals

(2019) Benjamin D. W. Allen et al.   ORGANIC LETTERS

Metalla-electrocatalyzed C–H Activation by Earth-Abundant 3d Metals and Beyond

(2019) Lutz Ackermann   ACCOUNTS OF CHEMICAL RESEARCH

Nickel-Catalyzed Electrochemical Reductive Relay Cross-Coupling of Alkyl Halides to Aryl Halides

(2019) Ke-Jin Jiao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Chlorotrifluoromethylated Pyrrolidines by Electrocatalytic Radical Ene-Yne Cyclization

(2018) Ke-Yin Ye et al.   CHEMISTRY-A EUROPEAN JOURNAL

Divergent Synthesis of Pyrone Diterpenes via Radical Cross Coupling

(2018) Rohan R. Merchant et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Anodically Coupled Electrolysis for the Heterodifunctionalization of Alkenes

(2018) Ke-Yin Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni-Catalyzed Electrochemical Decarboxylative C–C Couplings in Batch and Continuous Flow

(2018) Hui Li et al.   ORGANIC LETTERS

An Electrocatalytic Approach to the Radical Difunctionalization of Alkenes

(2018) Gregory S. Sauer et al.   ACS Catalysis

Electrocatalytic C–H Activation

(2018) Nicolas Sauermann et al.   ACS Catalysis

Recent Advances in C–H Functionalization Using Electrochemical Transition Metal Catalysis

(2018) Cong Ma et al.   ACS Catalysis

Copper-Catalyzed Radical Relay for Asymmetric Radical Transformations

(2018) Fei Wang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Radical Retrosynthesis

(2018) Joel M. Smith et al.   ACCOUNTS OF CHEMICAL RESEARCH

N -(Acyloxy)phthalimides as Redox-Active Esters in Cross-Coupling Reactions

(2018) Sandip Murarka   ADVANCED SYNTHESIS & CATALYSIS

Radicals in natural product synthesis

(2018) Kevin J. Romero et al.   CHEMICAL SOCIETY REVIEWS

Recent Advances in Alkyl Carbon-Carbon Bond Formation by Nickel/Photoredox Cross-Coupling

(2018) Gary Molander et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Forging C(sp3)–C(sp3) Bonds with Carbon-Centered Radicals in the Synthesis of Complex Molecules

(2018) Spencer P. Pitre et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mn-Catalyzed Electrochemical Chloroalkylation of Alkenes

(2018) Niankai Fu et al.   ACS Catalysis

Remote Migratory Cross-Electrophile Coupling and Olefin Hydroarylation Reactions Enabled by in Situ Generation of NiH

(2017) Fenglin Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal- and Reagent-Free Intramolecular Oxidative Amination of Tri- and Tetrasubstituted Alkenes

(2017) Peng Xiong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrocatalytic Radical Dichlorination of Alkenes with Nucleophilic Chlorine Sources

(2017) Niankai Fu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrochemical Nickel Catalysis for Sp2-Sp3 Cross-Electrophile Coupling Reactions of Unactivated Alkyl Halides

(2017) Robert J. Perkins et al.   ORGANIC LETTERS

Metal-catalyzed electrochemical diazidation of alkenes

(2017) Niankai Fu et al.   SCIENCE

Ligand-Controlled Nickel-Catalyzed Reductive Relay Cross-Coupling of Alkyl Bromides and Aryl Bromides

(2017) Long Peng et al.   ACS Catalysis

Engaging Radicals in Transition Metal-Catalyzed Cross-Coupling with Alkyl Electrophiles: Recent Advances

(2017) Atsushi Kaga et al.   ACS Catalysis

Transition-Metal Catalysis of Nucleophilic Substitution Reactions: A Radical Alternative to SN1 and SN2 Processes

(2017) Gregory C. Fu   ACS Central Science

The merger of transition metal and photocatalysis

(2017) Jack Twilton et al.   Nature Reviews Chemistry

Mn-, Fe-, and Co-Catalyzed Radical Hydrofunctionalizations of Olefins

(2016) Steven W. M. Crossley et al.   CHEMICAL REVIEWS

Asymmetric copper-catalyzed C-N cross-couplings induced by visible light

(2016) Q. M. Kainz et al.   SCIENCE

Photoredox Catalysis Unlocks Single-Electron Elementary Steps in Transition Metal Catalyzed Cross-Coupling

(2016) Mark D. Levin et al.   ACS Central Science

Manganese Catalyzed C–H Halogenation

(2015) Wei Liu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Manganese-Catalyzed Late-Stage Aliphatic C–H Azidation

(2015) Xiongyi Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Renaissance of Electrosynthetic Methods for the Construction of Complex Molecules

(2014) Siegfried R. Waldvogel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redox catalysis in organic electrosynthesis: basic principles and recent developments

(2014) Robert Francke et al.   CHEMICAL SOCIETY REVIEWS

Recent advances in homogeneous nickel catalysis

(2014) Sarah Z. Tasker et al.   NATURE

Vicinal Difunctionalization of Alkenes: Chlorotrifluoromethylation with CF3SO2Cl by Photoredox Catalysis

(2014) Se Hwan Oh et al.   ORGANIC LETTERS

Single-electron transmetalation in organoboron cross-coupling by photoredox/nickel dual catalysis

(2014) J. C. Tellis et al.   SCIENCE

Merging photoredox with nickel catalysis: Coupling of  -carboxyl sp3-carbons with aryl halides

(2014) Z. Zuo et al.   SCIENCE

Catalytic Asymmetric Reductive Acyl Cross-Coupling: Synthesis of Enantioenriched Acyclic α,α-Disubstituted Ketones

(2013) Alan H. Cherney et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Merging Visible-Light Photocatalysis and Transition-Metal Catalysis in the Copper-Catalyzed Trifluoromethylation of Boronic Acids with CF3I

(2012) Yingda Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photoinduced Ullmann C-N Coupling: Demonstrating the Viability of a Radical Pathway

(2012) S. E. Creutz et al.   SCIENCE

Room-Temperature C–H Arylation: Merger of Pd-Catalyzed C–H Functionalization and Visible-Light Photocatalysis

(2011) Dipannita Kalyani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Contribution of Electrochemistry to Organometallic Catalysis

(2008) Anny Jutand   CHEMICAL REVIEWS