Article
Engineering, Environmental
Xiaoyi Tang, Siyi Wang, Zhihui Zhang, Zijie Li, Lin Wang, Liyong Yuan, Bairong Wang, Jian Sun, Lirong Zheng, Hongqing Wang, Weiqun Shi
Summary: In this study, a composite hydrogel/aerogel was prepared by inducing the self-assembly of chitosan and graphene oxide and growing potassium copper hexacyanoferrate(II) nanoparticles onto the surface. The composite hydrogel showed high sorption capacity and ultrafast kinetics for Cs+ removal. The system also demonstrated potential for the cleanup of Cs+ from contaminated groundwater using a fixed-bed column.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Engineering, Environmental
Joanna Kurczewska
Summary: In this study, chitosan beads with incorporated montmorillonite were prepared and characterized. The results showed that the chitosan beads with montmorillonite had better adsorption capacity for methyl green removal. Several parameters were investigated to optimize the process.
JOURNAL OF WATER PROCESS ENGINEERING
(2022)
Article
Biochemistry & Molecular Biology
Neset Erek Sen, Zeynep Mine Senol
Summary: Chitosan-diatomite composite beads (Ch-D) were synthesized and exhibited improved adsorption capacity for Allura red AC (AR) food dye through hydrogen bonding and electrostatic interactions. The Ch-D composite showed a removal rate of 98% at 25 degrees Celsius, natural pH value, and an initial AR dye concentration of 200 mg L-1. The maximum adsorption capacity was found to be 34.7 mg g-1. The interactions between functional groups on the Ch-D composite and AR dye involved pi-pi interactions, hydrogen bonds, and electrostatic interactions.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Materials Science, Multidisciplinary
Zhen Zhang, Noureddine Abidi, Lucian Lucia
Summary: The presence of toxic dyes in water threatens environmental safety, making efficient removal of dyes from wastewater highly desired. This study successfully fabricated efficient biosorbents through a simple gelation process of sodium alginate and carboxymethyl chitosan in an acidic aqueous solution. The resulting hydrogel beads showed excellent water absorption properties, pH-responsive swelling characteristics, and high methylene blue (MB) adsorption capacity, comparable to existing lignocellulosic and alginate-based hydrogels. The adsorption mechanism was explained by strong electrostatic forces. This research provides a promising and sustainable approach to dye decontamination.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2023)
Article
Engineering, Environmental
Abubakar Chadi Sadiq, Ayo Olasupo, Nurul Yani Rahim, Wan Saime Wan Ngah, Faiz Bukhari Mohd Suah
Summary: This study investigated the adsorption properties of malachite green dye on two types of chitosan deep eutectic solvent adsorbents. The optimal pH and adsorption capacity under different factors were determined, while various characterization techniques were used to reveal the surface properties, crystallinity, pore sizes, and magnetic characteristics of the adsorbents. The results showed good fitting with the Langmuir model and the best description of kinetic behavior by the pseudo-second-order kinetic model for both adsorbents.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Engineering, Chemical
Jia Xin Yap, C. P. Leo, Derek Juinn Chieh Chan, Nazlina Haiza Mohd Yasin, Mohd Shaiful Sajab
Summary: Water pollution requires sustainable materials for green treatment solutions. This study successfully extracted nanocellulose from microalgae through alkaline treatment, bleaching, and hydrolysis without TEMPO-mediated oxidation. The effects of acid concentration on nanocellulose properties were studied and the maximum yield was achieved using sulphuric acid with a concentration of 60%(v/v). The extracted microalgae nanocellulose was incorporated into carboxymethyl cellulose/sodium alginate beads, significantly increasing methylene blue adsorption capacity and achieving a high dye removal percentage.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)
Article
Polymer Science
Hafida Ferfera-Harrar, Tayeb Benhalima, Amina Sadi
Summary: Hydrogel nanocomposites comprised of chitosan-grafted-hydrolyzed polyacrylamide as matrix and montmorillonite clay as nanofiller were successfully synthesized as efficient adsorbents for removing Basic Red 46 dye. The nanohybrid hydrogels showed superior water-absorbing ability, thermal stability, pH-sensitivity, and high adsorption efficiency for the dye due to electrostatic interactions and hydrogen bonding. Effective regeneration and multiple cycles of dye release indicate their promising potential in treating water contaminated with cationic dyes.
Article
Multidisciplinary Sciences
Mohamed M. Abou Alsoaud, Mahmoud A. Taher, Abdelrahman M. Hamed, Mohamed S. Elnouby, Ahmed M. Omer
Summary: In this study, Kaolin (K) impregnated aminated chitosan (AM-CTS) composite beads were fabricated and used for the adsorption of anionic Congo red (CR) dye. The results showed that the K@AM-CTS composite beads had a larger specific surface area and improved thermal stability compared to pure AM-CTS. The adsorption equilibrium of CR dye was achieved rapidly and the removal efficiency increased with increasing kaolin content. The adsorption process followed the pseudo-first order kinetic model and the Freundlich isotherm model, and was determined to be physical adsorption with spontaneous and endothermic nature. The developed K@AM-CTS composites beads demonstrated good reusability.
SCIENTIFIC REPORTS
(2022)
Article
Engineering, Environmental
Mohammadtaghi Vakili, Fatemeh Gholami, Haider M. Zwain, Wei Wang, Amin Mojiri, Martin Tomas, Giovanni Cagnetta, Reza Gholizadeh, Wafa Dastyar, Zahra Gholami
Summary: This study achieved effective adsorption of GenX by using chitosan (CS) modified adsorbent. The prepared CS-DEO-APTES adsorbent showed high adsorption capacity and excellent stability. Kinetic and isothermal data revealed chemisorptive interactions between GenX and CS-DEO-APTES with a uniform distribution of adsorption sites. GenX-saturated beads were successfully regenerated multiple times. Density functional theory calculations indicated that electrostatic interactions primarily influenced the adsorption of GenX. These results highlight the effectiveness of the CS-DEO-APTES adsorbent for removing GenX from aqueous solutions.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Article
Engineering, Chemical
Saad Zafar, Vignesh Nayak, Soumyasri Nikhilesh Mahapatra, Bimlesh Lochab
Summary: Environmentally friendly sorbents based on sustainable feedstocks have been developed for easy removal of various pollutants from water. These sorbents show good mechanical and hydrolytic stability, and can effectively remove crude oil and mercury ions. The waste-derived sorbents hold great promise for water purification.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)
Article
Chemistry, Physical
Joanna Kluczka, Gabriela Dudek, Wojciech Pudlo, Alicja Kazek-Kesik, Roman Turczyn
Summary: Hybrid biosorbent hydrogel beads based on chitosan and manganese were used to effectively remove boron from aqueous media, achieving a maximum sorption capacity of 190 mg/g. The method shows promise in improving water quality and reducing pollution in aquatic environments.
Article
Environmental Sciences
Prarabdh Jain, Kedar Sahoo, Lenin Mahiya, Harsh Ojha, Harshita Trivedi, Avanish Singh, Manoj Kumar
Summary: A low cost polyvinyl alcohol-glutaraldehyde cross-linked hydrogel beads were successfully used for color removal from model industrial effluent containing Congo Red dye, achieving a high adsorption capacity and showing good reusability. Adsorption analysis revealed a multi-layer adsorption and pseudo second order kinetics, with fixed bed experiments best explained by the Thomas mathematical model. The studies demonstrated that external and internal mass diffusion were no longer rate limiting factors in the experiments.
JOURNAL OF ENVIRONMENTAL MANAGEMENT
(2021)
Article
Biology
Johanna Galan, Jorge Trilleras, Paula A. Zapata, Victoria A. Arana, Carlos David Grande-Tovar
Summary: The discharge of dyes into water affects aquatic organisms and human health, while chitosan is effective in removing anionic dyes. This study optimized CS beads crosslinked with GA to adsorb RB4 dye, with RSM used to evaluate and optimize the process parameters. The adsorption mechanism was mainly controlled by chemisorption interactions, showing applicability in removing contaminants with similar structures.
Article
Environmental Sciences
Hassan Karimi-Maleh, Sara Ranjbari, Bahareh Tanhaei, Ali Ayati, Yasin Orooji, Marzieh Alizadeh, Fatemeh Karimi, Sadegh Salmanpour, Jalal Rouhi, Mika Sillanpaa, Fatih Sen
Summary: The study revealed that BmImBr impregnated chitosan beads showed efficient removal of methylene blue, reaching 86% removal efficiency in just 25 minutes. Increasing the amount of BmImBr improved the adsorption performance of the prepared beads.
ENVIRONMENTAL RESEARCH
(2021)
Article
Biochemistry & Molecular Biology
Yangyang Zhao, Yang Song, Rui Li, Fengfan Lu, Yibin Yang, Qiongjian Huang, Dongli Deng, Mingzhu Wu, Ying Li
Summary: In order to overcome the weak affinity and difficult separation of biochar, chitosan-biochar hydrogel beads (CBHBs) were developed as a solution for removing reactive brilliant blue (RBB KN-R) from wastewater. The adsorption behavior and mechanism of RBB KN-R onto CBHBs were extensively studied. The adsorption capacity showed pH-dependence and the highest adsorption capacity was observed at pH 2. The adsorption process followed the pseudo-second-order kinetic model and the intraparticle diffusion model. Film diffusion and intraparticle diffusion both contributed to the adsorption process. The maximum adsorption capacity was found to be 140.74 mg/g at 298.15 K, and higher temperatures favored the adsorption process. A complex mechanism involving p-p interactions, electrostatic attraction, hydrophobic interaction, and hydrogen bonding was found to contribute to the overall adsorption process. The presence of coexisting substances and elevated ionic strength hindered the adsorption capacity. After three cycles of adsorption-desorption, the CBHBs maintained an adsorption capacity above 95% for RBB KN-R. These results suggest that CBHBs are a durable and cost-effective adsorbent for efficient removal of dyes from wastewater.
Article
Chemistry, Analytical
Priscila Fernanda Pereira Barbosa, Valmor Roberto Mastelaro, Eduardo Guimaraes Vieira, Devaney Ribeiro do Carmo
Summary: A synthesis method for the functionalization of beta-cyclodextrin (beta-Cd) with polyamide dendrimer PAMAM G.0 and the formation of a mixed-valence complex (beta-Cd-PAMAM-Ag/Fe) with silver and potassium hexacyanoferrate (III) was proposed. The material was characterized using SEM, FTIR, XRD, EDS, and EPR. The electrochemical behavior of the hybrid complex was investigated, and optimal analytical responses were obtained by evaluating various parameters. The beta-Cd-PAMAM-Ag/Fe material showed successful application in the electrocatalytic oxidation of dopamine using CV and SWV.
Article
Engineering, Environmental
Tauany de Figueiredo Neves, Natalia Gabriele Camparotto, Everton Augusto Rodrigues, Valmor Roberto Mastelaro, Renato Falcao Dantas, Patricia Prediger
Summary: This study synthesized new hydrolyzed poliacrylonitrile (hPAN) membranes incorporated with graphene oxide (GO), and investigated the changes in membrane properties. The results demonstrate that the GO modified membranes have good ability to remove emerging contaminants, with high water flux and removal capacity.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Food Science & Technology
Larissa G. R. Duarte, Natalia C. A. Ferreira, Ana Clara T. R. Fiocco, Carolina S. F. Picone
Summary: The aim of this study was to enhance the antimicrobial activity of lactoferrin and chitosan by producing nanoparticles through ionic cross-linking with TPP. The nanoparticles were synthesized in varying proportions and characterized for size, zeta potential, morphology, chemical interactions, structure, and antibacterial properties. The nanoparticles with higher zeta potential values and lower hydrodynamic diameters showed strong bacteriostatic action against S. aureus and delayed the ripening and degradation of strawberries when applied as coatings. These findings highlight the potential of these nanoparticles as natural food preservatives.
FOOD AND BIOPROCESS TECHNOLOGY
(2023)
Article
Environmental Sciences
Paula Mayara Morais da Silva, Gilberto Dias de Alkimin, Natalia Gabriele de Camparotto, Patricia Prediger, Bruno Nunes
Summary: The widespread use of carbon-based materials in various applications leads to their release into aquatic systems, where they co-occur with other environmental contaminants, such as pharmaceutical drugs. This co-occurrence can have negative effects on aquatic organisms, but few studies have investigated the simultaneous toxicity of nanomaterials and organic contaminants on aquatic plants. Therefore, this study aimed to assess the toxic effects of co-exposure to a pharmaceutical drug called propranolol (PRO) and nanomaterials based on cellulose nanocrystals and graphene oxide in the aquatic macrophyte Lemna minor. The results showed that the presence of nanomaterials enhanced the toxicity of PRO, resulting in detrimental effects on the freshwater plant L. minor.
ENVIRONMENTAL POLLUTION
(2023)
Article
Environmental Sciences
Ruth Nobrega Queiroz, Meuris Gurgel Carlos da Silva, Valmor Roberto Mastelaro, Patricia Prediger, Melissa Gurgel Adeodato Vieira
Summary: A green magnetic composite was synthesized and used for the adsorption of naphthalene from effluents. The composite showed good adsorption performance and could be effectively regenerated for reuse.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Article
Food Science & Technology
Jaqueline Milagres de Almeida, Bruna Lourenco Crippa, Victoria Vilaca Martins Alencar de Souza, Vanessa Pereira Perez Alonso, Edison da Motta Santos Junior, Carolina Siqueira Franco Picone, Ana Silvia Prata, Nathalia Cristina Cirone Silva
Summary: The antimicrobial properties of essential oils from spice and medicinal plants have shown potential as alternative preservatives in food, inhibiting the growth of bacteria that cause Foodborne Diseases. Cinnamon essential oil performed the best in inhibiting the growth of all tested bacteria, while a combination of oregano and thyme showed synergistic effects. Encapsulation of essential oils in microcapsules enhanced their inhibitory power.
Article
Chemistry, Physical
Laura O. Libero, Lara K. Ribeiro, Luis I. Granone, Maria S. Churio, Josiane C. Souza, Valmor R. Mastelaro, Juan Andres, Elson Longo, Lucia H. Mascaro, Marcelo Assis
Summary: This study reports on the immobilization of Fe-2(MoO4)(3) in chitosan films and its effect on the oxidation reaction of sulfide derivatives. The catalyst showed good yields and excellent selectivity, even tolerating oxidatively sensitive functional groups. The key success of the selective oxidation was attributed to the presence of hydroxyl radical, center dot OH, and the Fe3+/Fe2+ Fenton-like process. Additionally, the synergistic effect between Fe-2(MoO4)(3) and chitosan was demonstrated in the selective oxidation of sulfides to sulfones. This work provides a design strategy for efficient catalysts that can be applied to other semiconductors and oxidation processes.
Article
Environmental Sciences
Natalia Gabriele Camparotto, Tauany de Figueiredo Neves, Valmor Roberto Mastelaro, Patricia Prediger
Summary: In this study, highly hydrophobic chitosan beads were prepared as adsorbents for removing organic contaminants from water. The chitosan beads exhibited high porosity, large pore space, and excellent hydrophobicity. The beads showed efficient adsorption capacities for sildenafil citrate, basic blue 26 dye, and cetylpyridinium chloride, and were also effective in fixed-bed experiments.
ENVIRONMENTAL RESEARCH
(2023)
Article
Chemistry, Inorganic & Nuclear
H. Moreno, G. L. Domingues, M. Assis, P. P. Ortega, V. R. . Mastelaro, M. A. . Ramirez, A. . Z. Simoes
Summary: This study investigates the morphology and photocatalytic properties of CeO2 nanocrystals synthesized using microwave-assisted solvothermal method with acetone and ethanol as solvents. The results show that CeO2 synthesized in acetone has more emission peaks in the blue region, possibly due to higher Ce3+ concentration, while CeO2 synthesized in ethanol exhibits a strong orange-red emission, suggesting the presence of oxygen vacancies. CeO2 synthesized in acetone demonstrates superior photocatalytic response compared to that synthesized in ethanol, possibly due to increased disorder in the CeO2 structure, leading to enhanced light absorption.
INORGANIC CHEMISTRY
(2023)
Article
Food Science & Technology
Ana Carolina R. Goncalves, Larissa G. R. Duarte, Ana Clara T. R. Fiocco, William M. P. Alencar, Raiza Iacuzio, Nathalia C. C. Silva, Carolina S. F. Picone
Summary: Chitosan nanoparticles were prepared using two different methods: ionic cross-linking with sodium tripolyphosphate (TPP) and chemical cross-linking with genipin (GN). The nanoparticles exhibited positive zeta potentials (+46.24 mV for CS-TPP and +62.86 mV for CS-GN) and sizes ranging from 83.70 to 835.91 nm, with the ionic cross-linked nanoparticles being smaller. In vitro antibacterial tests showed effective inhibition, particularly for CS-TPP. In situ studies on O/W emulsions demonstrated that the nanoparticles improved the microbiological and oxidative stability of the emulsions. These findings highlight the relationship between particle size reduction and enhanced functional properties of biopolymers, and expand the potential applications of chitosan as a natural preservative for emulsified systems.
INTERNATIONAL JOURNAL OF FOOD SCIENCE AND TECHNOLOGY
(2023)
Article
Chemistry, Physical
Francielle Candian Firmino Marcos, Maria Jose Fonseca Costa, Gabriel L. Catuzo, Daniel Angeli de Moraes, Marcos de Oliveira Jr, Valmor Roberto Mastelaro, Jose Mansur Assaf, Reinaldo Giudici, Elisabete Morreira Assaf
Summary: xCu/MOF catalysts were synthesized by impregnation of copper precursor on UiO-66 support and characterized using various techniques. The 20Cu/MOF catalyst, with the highest copper loading, exhibited the best methanol formation rate and CO2 conversion due to the strong metal-support interaction and the highest amount of missing linker defects in the MOF structure.
JOURNAL OF CATALYSIS
(2023)
Article
Nanoscience & Nanotechnology
Raul L. Ferreira, Walter Muniz Jr, Louise E. A. Souza, Hector M. C. Navarro, Lucas R. de Mello, Valmor R. Mastelaro, Tasso O. Sales, Cintya D. A. E. S. Barbosa, Adriana S. Ribeiro, Emerson R. da Silva, Melissa F. Landell, Italo N. de Oliveira
Summary: This study investigates the physicochemical and antimicrobial properties of carbon dots derived from the methyl red azo dye. The results show that these carbon dots exhibit low cytotoxicity and tunable photoluminescence, and can generate reactive oxygen species (ROS) with a high singlet oxygen quantum efficiency. They also demonstrate strong antimicrobial activity against healthcare-relevant pathogens.
ACS APPLIED BIO MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Guilherme K. Maron, Mateus G. Masteghin, Veridiana Gehrke, Lucas S. Rodrigues, Jose H. Alano, Jessica H. H. Rossato, Valmor Roberto Mastelaro, Jairton Dupont, Marcia Tsuyama Escote, S. Ravi P. Silva, Neftali Lenin Villarreal Carreno
Summary: This study demonstrates an enhanced fabrication technique using CO2 infrared lasers to pattern micro-supercapacitor electrodes. The direct-written laser-induced graphene (LIG) micro-supercapacitors with NiCo2S4 nanoparticles exhibited outstanding properties, including high specific capacitance and energy density, as well as excellent capacitance retention and flexibility. These findings suggest the potential use of LIG/NiCo2S4 MSC in the next generation of flexible and miniaturized portable devices.
MATERIALS RESEARCH BULLETIN
(2023)
Article
Chemistry, Multidisciplinary
P. Jennita Jacqueline, G. Velvizhi
Summary: This study examines the potential of yellow banana peel, pineapple peel, and papaya peel as substrates for producing reducing sugar. Different pretreatment techniques were used to enhance the delignification process and enzymatic hydrolysis, resulting in increased yield of reducing sugars.
SUSTAINABLE CHEMISTRY AND PHARMACY
(2024)
Article
Chemistry, Multidisciplinary
Priya Sundararajan, Shanmuga Priya Ramasamy
Summary: This review provides insights into the production of carotenoids using microorganisms, summarizing the biosynthetic pathways involved in microbial synthesis and highlighting the production, extraction, and purification strategies. It aims to expedite the commercialization of microbial carotenoids.
SUSTAINABLE CHEMISTRY AND PHARMACY
(2024)
Article
Chemistry, Multidisciplinary
T. K. S. Fayaz, Hemanth Kumar Chanduluru, Reem H. Obaydo, Palash Sanphui
Summary: This study employed Green Analytical Chemistry (GAC) and RP-HPLC technique to investigate the stability of Ripretinib under different stress conditions and developed a highly sensitive and accurate RP-HPLC method. The method's environmentally friendly performance was validated and aligned with several sustainable development goals, further enhancing its credibility and significance in advancing a greener and more sustainable future.
SUSTAINABLE CHEMISTRY AND PHARMACY
(2024)
Article
Chemistry, Multidisciplinary
Nikolaos Tzortzakis, Antonios Chrysargyris
Summary: The cultivation of olive trees and grapevines in the Mediterranean area has expanded, but the processes that follow harvesting have negative effects on the environment and human health. This study explored the potential use of olive-mill and grape-mill residues in soil, finding that they can provide minerals and organic matter to the mixtures. However, further research is needed to develop the appropriate fertilization scheme.
SUSTAINABLE CHEMISTRY AND PHARMACY
(2024)
Article
Chemistry, Multidisciplinary
Renzo Carlucci, Juan A. Arancibia, Guillermo R. Labadie
Summary: Phytosterols, naturally occurring plant sterols, have been found in various plant-based foods and have potential beneficial effects on human health, particularly in reducing the risk of cardiovascular disease. In this study, an efficient method for preparing phytosterols from a by-product of biodiesel production was developed and optimized using an environmentally friendly alternative to traditional mineral acids. The optimized method showed improved yield and offered a greener approach in terms of E factor, energy consumption, and safety. This has important implications for the food and nutraceutical industries, which are increasingly focused on using renewable and eco-friendly sources.
SUSTAINABLE CHEMISTRY AND PHARMACY
(2024)
Article
Chemistry, Multidisciplinary
Qiuyun Zhang, Yaping Wu, Xingyue Hong, Zhenying Li, Yanting Lei, Rongfei Yu, Taoli Deng, Yutao Zhang, Peihua Ma
Summary: Different ligand functionalized bimetallic organic framework composites with phosphotungstic acid (HPW) were prepared and used as catalysts for the esterification of methanol with oleic acid. The HPW/(Zr/Ce)UiO-66-NO2 catalyst showed the most promising catalytic features, including the highest number of strong Bronsted and Lewis acid sites, wider pores, higher surface area, and synergistic catalytic effects with the (Zr/Ce)UiO-66-NO2 framework. The catalytic activity of the HPW/(Zr/Ce)UiO-66-NO2 catalyst was higher than other catalysts, and it also exhibited good reusability over multiple cycles.
SUSTAINABLE CHEMISTRY AND PHARMACY
(2024)
Article
Chemistry, Multidisciplinary
Filippo Marchetti, Irene Gugel, Stefania Costa, Erika Baldini, Gaia Bellonzi, Silvia Vertuani, Stefano Manfredini
Summary: The study aimed to identify an alternative process for isolating two new steroids obtained by biotransformation, using cloud point extraction for the first time. Cloud point extraction was chosen as a green downstream method due to its low cost, short extraction time, and non-toxic extraction agents.
SUSTAINABLE CHEMISTRY AND PHARMACY
(2024)
Review
Chemistry, Multidisciplinary
Sidhartha Sondh, Darshit S. Upadhyay, Sanjay Patel, Rajesh N. Patel
Summary: This study proposes the key elements for designing a solid waste management system based on the circular economy. It emphasizes the importance of reducing, reusing, recycling, and recovering in the circular economy framework. The study also discusses the role of policies, legislation, and case studies in solid waste management systems. Additionally, it explores various aspects of the circular economy and presents insights into achieving sustainability through a circular economy-based waste management system.
SUSTAINABLE CHEMISTRY AND PHARMACY
(2024)