期刊
JOURNAL OF ELECTROCHEMICAL ENERGY CONVERSION AND STORAGE
卷 18, 期 4, 页码 -出版社
ASME
DOI: 10.1115/1.4049926
关键词
fuel cells; electrocatalysis; novel materials
资金
- Doctoral Research Fund of Xi'an Polytechnic University [107020509]
- Fundamental Research (Free Academic Exploration) Project of Science, Technology and Innovation Commission of Shenzhen Municipality [JCYJ20170306161133420]
- National Natural Science Foundation of China [51772248]
- Science and Technology Innovation as a Whole Plan Projects of Shaanxi Province [2016KTZDGY10-01]
A stable three-dimensional glucose/oxygen enzymatic biofuel cell was successfully fabricated using the polymer encapsulation-based immobilization method, with enhanced stability and efficiency. Gold nanoparticles and multi-wall carbon nanotubes were employed to improve direct electron transfer and conductivity of the bio-electrodes, while carbon felt was utilized as the substrate.
A stable three-dimensional glucose/oxygen enzymatic biofuel cell is fabricated based on the method of polymer encapsulation-based immobilization. And three-dimensional carbon felt is used as the substrate of the bio-electrode for increasing enzymatic loading density. Gold nanoparticles and multi-wall carbon nanotubes are employed to promote direct electron transfer and enhance conductivity and electron conduction rate of bio-electrodes. Glucose dehydrogenase and bilirubin oxidase are immobilized with tetrabutylammonium bromide (TBAB) modified Nafion, which enhances the stability of the bio-electrodes by the immobilization method. A membrane-free glucose/oxygen biofuel cell is assembled with a high open-circuit voltage of 0.85 V and a maximum power density of 21.9 +/- 0.1 mu W/cm(2) in 0.1 M pH 7.0 phosphate buffer solution with 100 mM glucose and air saturation. And the biofuel cell shows high stability to the condition. After 60 days of periodic storage experiments, the performance of the enzymatic biofuel cell still maintained 90.3% of its electrochemical performance.
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