期刊
POLYHEDRON
卷 193, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.poly.2020.114897
关键词
Metal-Organic Frameworks (MOFs); Solvothermal/Hydrothermal Synthesis; Microwave Synthesis; Sonochemical Synthesis; Electrochemical Synthesis; Mechanochemical Synthesis
Metal-organic frameworks (MOFs) are porous materials constructed by inorganic metallic centers and organic ligands, widely used in gas purification and catalysis. Recent years have seen a shift towards green chemistry principles in synthesizing MOFs, driving continuous development in material fabrication.
Metal-organic frameworks (MOFs) the porous materials have been primarily created by using the inorganic metallic centers and the different organic ligands linked via coordination bonds to construct the one, two, or three-dimensional networks depending upon the spatial arrangement of both inorganic and organic constituents. The construction of a plethora of well-defined porous MOFs, covering a wide range of topologies and an even broader range of pore sizes and surface area, superior design flexibility, and tunable functionality, has fueled the exploration of wide-open unprecedented scope in several fields such as gas purification, storage, catalysis, sensor materials, drug delivery, and wastewater treatment. Here, we review the outline journey of synthesis of MOFs, from the year 1995 to 2019, highlighting the transition in synthetic approaches based on the principles of green chemistry from conventional solvothermal to the greener protocols. Moreover, the expansion of several sustainable synthetic routes and the deeper symphony of post-synthetic approaches may lead to the fabrication of robust MOFs with new structural morphologies and enthralling features, that would be convenient for countless real-world applications. These challenges and orientations may result in a continual expansion of interest and further growth in MOF chemistry. (C) 2020 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据