期刊
MICROPOROUS AND MESOPOROUS MATERIALS
卷 309, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.micromeso.2020.110572
关键词
Aluminophosphate; Water adsorption; Working capacity; Adsorption chiller
类别
资金
- Technology Development Program to Solve Climate Changes through National Research Foundation of Korea (NRF) - Ministry of Science and ICT [2018M1A2A2026254]
- Korea Institute of Energy Research [B8-2431]
- National Research Foundation of Korea [2018M1A2A2026254] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
We synthesized an aluminophosphate (AlPO4)-based adsorbent that shows great cooling performance when used in a water adsorption chiller as an adsorbent. This adsorbent is crystalline microporous (CHA-type structure) material, which is composed of aluminum, phosphine, and oxygen atoms. It shows high water adsorption capacity (0.3 g(H2O) g(ads)(-1)) at 308 K under 12 Torr of water vapor pressure (typical adsorption conditions of the adsorption chiller), and almost zero adsorption capacity at 348 K under 42 Torr (typical desorption conditions). This adsorbent shows much larger working capacity between the adsorption and desorption steps than silico-aluminophosphate (SAPO(4)) adsorbent which has same physico-chemical properties as the AlPO4, except for the absence of silicon species in framework. The commercial water adsorbent, FAM-Z02 is known to have the same structure as this SAPO(4). We confirmed that AlPO4 can be easily synthesized in a large scale with a high hydrothermal stability, and easily pelletized to 0.6-1 mm sphere-shaped particles. The present AlPO4 adsorbent was tested in lab-made water adsorption chiller with 5 kW scale, and it shows 523 W kg(-1) of specific cooling power (SCP). This experimental value was in good agreement with SCP (513 W kg(-1)) derived from simulation. The SCP of the AlPO4 adsorbent is 28% larger than that of the SAPO(4) adsorbent calculated from simulation.
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