4.7 Article

Luminescence properties of composite material Sr2MgSi2O7:Eu2+,Dy3+/light conversion agent with multilayer structure

期刊

JOURNAL OF RARE EARTHS
卷 40, 期 1, 页码 34-40

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ELSEVIER
DOI: 10.1016/j.jre.2020.11.016

关键词

Sr2MgSi2O7:Eu2+,Dy3+; Light conversion agent; Stability; Multilayer structure; Composite material; Rare earths

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A composite red luminescent material Sr2MgSi2O7:Eu2+,Dy3+/light conversion agent (SMED/LCA) was prepared, with SiO2, Al2O3, or MgF2 coated on its surface to maintain stability and luminescent properties.
In order to improve the red luminescent properties, Sr2MgSi2O7:Eu2+,Dy3+ was selected as a blue persistent luminescent donor phosphor, while light conversion agent was utilized to tune the persistent luminescent spectra from blue to red. Composite red luminescent material Sr2MgSi2O7:Eu2+,Dy3+/light conversion agent (SMED/LCA) was fabricated with light conversion agent and Sr2MgSi2O7:Eu2+,Dy3+ at a certain mass ratio. SiO2 (Al2O3 or MgF2) were coated on the surface of SMED/LCA through heterogeneous deposition method. The structural and optical characteristics of the resulting samples were launched in terms of X-ray diffraction and emission spectrum as well as afterglow brightness. The results demonstrate that the emission spectrum exhibits two emission bands, and the peaks are located at around 470 and 615 nm. SiO2, Al2O3 and MgF2 are coated on the surface of SMED/LCA like a protective shell to maintain its stability and luminescent properties, the afterglow initial brightness is still up to 0.37 cd/m(2) and the afterglow color purity calculated from CIE color coordinates is basically unchanged. (C) 2020 Chinese Society of Rare Earths. Published by Elsevier B.V. All rights reserved.

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