Article
Engineering, Chemical
Kaixuan Wang, Xin Qin, Peike Cao, Shuo Chen, Hongtao Yu, Xie Quan
Summary: An integrated electrocatalytic process combining electrochemical anodic oxidation (AO) with cathodic electro-Fenton (EF) was proposed to boost refractory pollutant removal over a broad pH range. The process showed high efficiency and stability in actual wastewater treatment, meeting the discharge standard for sewage treatment plants in China.
SEPARATION AND PURIFICATION TECHNOLOGY
(2024)
Article
Environmental Sciences
Jaimy Scaria, P. V. Nidheesh
Summary: This study compares the pre-oxidation of pharmaceutical wastewater using hydroxyl radical and sulfate radical based advanced oxidation processes. The heterogeneous Fenton process shows the highest efficiency in TOC removal, while persulfate activation requires an additional treatment step to reduce COD and inorganics.
ENVIRONMENTAL RESEARCH
(2023)
Article
Chemistry, Analytical
Fangfang Xuan, Zihao Yan, Zhirong Sun
Summary: The study focused on a novel heterogeneous catalyst (Fe-Ce-LDH/13X) for the removal of organic pollutants, particularly diuron, in the heterogeneous electro-Fenton process. Doping with Ce improved the performance of the catalyst and led to the successful degradation of diuron. The process not only effectively degraded organic pollutants but also reduced toxicity.
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2022)
Article
Engineering, Chemical
Zhaobo Wang, Dajun Ren, Shanshan Shang, Shuqin Zhang, Xiaoqing Zhang, Wangsheng Chen
Summary: In this study, a novel metal-carbon nanocomposite was synthesized and used as a catalyst carrier for removing 2,4-DCP. The synthesized catalyst materials showed a rich pore structure and high specific surface area, and exhibited excellent performance in terms of applicability to a wide pH range and reusability.
ADVANCED POWDER TECHNOLOGY
(2022)
Article
Engineering, Environmental
Minghui Xiang, Maofang Huang, Hui Li, Wenbing Wang, Yuan Huang, Zhen Lu, Chen Wang, Ruofan Si, Wei Cao
Summary: In this study, novel nanoscale zero-valent iron/cobalt@mesoporous hydrated silica core-shell particles were synthesized for the rapid degradation of Tetrabromobisphenol A. By optimizing the catalyst ratio and reaction conditions, the particles exhibited excellent reactivity and mineralization activity for TBBPA removal.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Engineering, Environmental
Zhichao Yang, Chao Shan, Joseph J. Pignatello, Bingcai Pan
Summary: Mn(II) was found to accelerate the Fenton reaction by participating directly and catalytically in the Fe(III)/Fe(II) redox cycle in the presence of picolinic acid (PICA) as an assisting agent. Mn(II) accelerated Fe(III) reduction, superoxide radical formation, and hydroxyl radical formation, but the proposed Mn(II/III)-H2O2 redox cycle was shown to be insignificant. Instead, Mn(II) initially complexes with a ferric hydroperoxo species, followed by intramolecular electron transfer to give Fe(II) and MnO2+. This scheme can be applied to other Fenton-type systems. These findings will be valuable for the design of practical and sustainable Fenton-based advanced oxidation processes (AOPs) using Mn(II) in combination with chelating agents.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2022)
Article
Engineering, Environmental
Kira Bresler, Dror Shamir, Zorik Shamish, Dan Meyerstein, Ariela Burg
Summary: This study investigates the catalytic oxidation of ethanol and dimethyl sulfoxide (DMSO) by LaFeO3 in Fenton-like reactions. The results demonstrate the formation of two short-lived oxidizing intermediates, which are identified as [((LaFeIIIO3)n)n((LaFeIIIO2(OH)m-2)(LaFeIV(O)O2)2] and [(LaFeIVO3)2(LaFeIIIO3)n-2]2+ based on product analysis. Notably, DMSO is oxidized much faster by [((LaFeIIIO3)n)n((LaFeIIIO2(OH)m-2)(LaFeIV(O)O2)2] than ethanol, while [(LaFeIVO3)2(LaFeIIIO3)n-2]2+ only oxidizes ethanol. The findings contribute to a better understanding of the mechanisms of perovskite catalyzed Fenton-like reactions and can facilitate the development of efficient AOPs.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Article
Environmental Sciences
Aref Shokri, Bahram Nasernejad, Mahdi Sanavi Fard
Summary: The efficiency of heterogeneous electro-Fenton technology in degrading recalcitrant organic pollutants in wastewater is highly evident. This green technology has gained significant attention from wastewater treatment research communities due to its outstanding performance, eco-friendliness, and wide operability. The article discusses the mechanism of the electro-Fenton process, the properties of efficient catalysts, and the challenges hindering its commercialization. It proposes future research directions and concludes that addressing those gaps will make the commercialization of electro-Fenton technology a realistic goal.
WATER AIR AND SOIL POLLUTION
(2023)
Article
Engineering, Environmental
Yufan Chen, Christopher J. Miller, Jieli Xie, T. David Waite
Summary: In this study, it was found that the oxidation products of methyl phenyl sulfoxide (PMSO) enhance the formation of methyl phenyl sulfone (PMSO2) by complexing with Fe(III) species. This finding suggests caution in using PMSO to investigate the role of ferryl ion ([(FeO)-O-IV](2+)) in iron-based advanced oxidation processes (AOPs). Additionally, other target compounds were found to modify the reactivity of iron species through complexation and/or redox reactions. Overall, this study highlights the confounding effects of aromatic probe compounds on the reactivity of iron species in AOPs.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2023)
Article
Chemistry, Applied
Nassira Ferroudj, Patricia Beaunier, Anne Davidson, Sebastien Abramson
Summary: The study explored the relationship between the activity and structure of γ-Fe2O3/SiO2 nanocomposite microspheres as heterogeneous catalysts, revealing that doped Fe3+ and ordered mesoporosity significantly enhance the activity of the materials, demonstrating excellent oxidation and mineralization effects on simulated water pollutants.
MICROPOROUS AND MESOPOROUS MATERIALS
(2021)
Review
Chemistry, Physical
Puthiya Veetil Nidheesh, Clement Trellu, Hugo Olvera Vargas, Emmanuel Mousset, Soliu Oladejo Ganiyu, Mehmet A. Oturan
Summary: Combination of electro-Fenton process with other advanced oxidation processes is effective for water and wastewater treatment. These combined processes can enhance the mineralization efficiency and reduce operational cost and toxicity of treated wastewater. However, they also present challenges such as increased side reactions and energy requirements.
CURRENT OPINION IN ELECTROCHEMISTRY
(2023)
Article
Environmental Sciences
Hernan D. Rojas-Mantilla, Saidy C. Ayala-Duran, Raquel F. Pupo Nogueira
Summary: This study characterized Nontronite, a clay mineral with high content of structural iron, before and after iron incorporation and 600 degrees C heat treatment. It was found to be a mesoporous material with high absorption and a band gap energy indicative of superficial hematite. Heat treatment promoted structure rearrangement, converting other iron phases to hematite and creating irregular surface sites, enhancing catalytic activity in the degradation of antibiotics with hydroxylation as the main degradation route.
Article
Environmental Sciences
Ruirui Sun, Rong Huang, Jiapeng Yang, Chongqing Wang
Summary: A novel process of waste treatment using magnetic copper smelter slag as a heterogeneous catalyst is proposed, which can effectively degrade tetracycline. The catalyst has a broad operation pH range and is not significantly affected by water quality, showing potential application prospects.
Article
Chemistry, Physical
Nasr Bensalah, Emna Neily, Ahmed Bedoui, Mohammad I. Ahmad
Summary: The Fenton system, a simple and efficient advanced oxidation technology, is used for the treatment of organic micropollutants in water and soil. This study aimed to replace the homogeneous catalyst with a heterogeneous natural iron-based catalyst, which showed high catalytic activity in decomposing H2O2 into hydroxyl radicals. The natural iron-based catalyst can function at any pH level without the need for pH control, and can be reused after heat treatment.
Article
Engineering, Environmental
Yan Gao, Miao Yan, Liangting Chen, Jianshe Zhao
Summary: This study successfully improved the diesel desulfurization efficiency using magnetic supported catalysts. The selected catalyst showed high catalytic activity in the oxidation of organic sulfides with H2O2 as oxidant. The catalyst can be magnetically recycled and reused for ten consecutive cycles without significant decrease in activity. GC-MS and EPR results confirmed the oxidation of sulfides to sulfones in the presence of center dot OH radical.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Materials Science, Multidisciplinary
Meiling Huang, Chao Wang, Shiquan Liu
JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION
(2019)
Article
Materials Science, Ceramics
Feng Chen, Weijuan Zhang, Shiquan Liu
CERAMICS INTERNATIONAL
(2020)
Article
Materials Science, Ceramics
Nan Jiang, Yi Du, Peihong Ji, Shiquan Liu, Bo He, Junnan Qu, Jiajia Wang, Xinyue Sun, Yang Liu, Haoyu Li
CERAMICS INTERNATIONAL
(2020)
Article
Physics, Condensed Matter
Weijuan Zhang, Pengbo Li, Xiaoxiao Duan, Shiquan Liu, Zhi Wang
PHYSICA B-CONDENSED MATTER
(2020)
Article
Engineering, Environmental
Feng Chen, Wenhong Tao, Dickon H. L. Ng, Luteng Zhang, Shiquan Liu
WATER SCIENCE AND TECHNOLOGY
(2020)
Article
Engineering, Environmental
Ruilin Wang, Shiquan Liu, Shivani Bhardwaj Mishra, Hui Zhao
Summary: The electrostatic attraction between negatively charged silica species and the micelles composed of the protonated amines, as well as the hydrogen bonding between neutral silica species and the micelles composed of the non-protonated amines, contribute to a coexisting assembly mechanism. This mechanism can explain the differences in morphology and properties of uncalcined amine gels.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Biochemistry & Molecular Biology
Aleksandra Jankowska, Agata Chlopek, Andrzej Kowalczyk, Malgorzata Rutkowska, Marek Michalik, Shiquan Liu, Lucjan Chmielarz
Article
Polymer Science
Xiansong Li, Shiquan Liu
Summary: Iron oxide-silica hybrid xerogels with high surface areas and highly dispersed Fe species were synthesized using recycled liquid, showing excellent adsorption and Fenton-like catalytic activity. These hybrid xerogels exhibited outstanding stability and recyclability in degrading Rhodamine B in aqueous solution.
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
(2021)
Article
Chemistry, Applied
Aleksandra Jankowska, Agata Chlopek, Andrzej Kowalczyk, Malgorzata Rutkowska, Wlodzimierz Mozgawa, Marek Michalik, Shiquan Liu, Lucjan Chmielarz
Summary: Deposition of copper by TIE method results in samples containing highly dispersed copper species and CuO nanorods, while deposition of highly dispersed copper species inside pores can be achieved through the TIE-NH3 procedure. Samples obtained by TIE-NH3 method are found to be promising catalysts for low-temperature NH3-SCR process.
MICROPOROUS AND MESOPOROUS MATERIALS
(2021)
Article
Chemistry, Physical
Sixun Niu, Xiaobin Dong, Weifen Zhang, Xiansong Li, Shiquan Liu
Summary: SiO2-CuxO composite films with high Cu/Si molar ratios were successfully prepared via a facile two-step process of dip coating and annealing, showing potential applications in antibacterial and dye degradation. The microstructure and crystalline phase of the composite films could be finely controlled by adjusting the amount of PVP, the concentration of copper solution, and the calcination temperature. The film prepared with 1 mol/L copper acetate solution and calcined at 500 degrees C exhibited the best antibacterial activity, adsorption, and photocatalytic performance toward methylene blue in solutions, indicating convenient use in antibacterial field and organic wastewater treatment.
SURFACES AND INTERFACES
(2021)
Article
Materials Science, Ceramics
Yuebo Hu, Xianying Shao, Linling Tan, Yang Shen, Shiquan Liu, Yuanzheng Yue
Summary: The upconversion luminescence of Er3+-doped oxyfluoro-germanate glasses and glass ceramics is studied using the Judd-Ofelt theory. The J-O intensity parameters were determined from experimental absorption spectra via the line strength equation of electric-dipole transitions, and the results were calibrated using fluorescence lifetime measurements. The study also analyzed the structure characteristics, bonding properties, crystallization mechanism, and microstructure of the materials.
JOURNAL OF NON-CRYSTALLINE SOLIDS
(2021)
Article
Materials Science, Ceramics
Jiejie Zhao, Shiquan Liu
Summary: In this study, frits with a molar ratio of MgO:TiO2:P2O5 = 20:32:24 were prepared by melt water-quenching method, with the addition of various amounts of CuO. The frits were then heat- and acid-treated to form porous anatase consisting of nanosheets. The presence of CuO increased the crystallization of anatase and even led to the crystallization of CuO nano-rods, greatly accelerating the selective dissolution of the crystallized samples during acid-leaching process.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2023)
Article
Chemistry, Multidisciplinary
Nayab Arif, Ye-Zhan Lin, Kai Wang, Yi-Chuan Dou, Yu Zhang, Kui Li, Shiquan Liu, Fu-Tian Liu
Summary: Bimetallic zeolite-imidazole frameworks were utilized as a photocatalytic hydrogen production catalyst, while a 2D-2D surface heterostructure of g-C3N4-MoS2 was introduced to facilitate the charge carrier separation efficiency in ZnM-ZIFs. The optimal g-C3N4-MoS2-ZnNi-ZIF exhibited significantly higher photocatalytic hydrogen evolution activity compared to other structures, highlighting the potential of porous MOF-based heterostructures for hydrogen production.
Article
Chemistry, Multidisciplinary
Nayab Arif, Zhao-Xu Wang, Yan-Tao Wang, Yi-Chuan Dou, Kui Li, Shi-Quan Liu, Fu-Tian Liu
Summary: A ternary Z-scheme g-C3N4/rGO/FeOOH heterostructure photocatalyst was designed and fabricated, showing excellent photocatalytic hydrogen production performance. By rational design of the component of the heterostructure, this work could expand the usage of the earth-abundant element and provide a new viewpoint for the development of high-performance photocatalysts.
Article
Chemistry, Physical
Rajalaxmi Sahoo, C. Reshma, D. S. Shankar Rao, C. V. Yelamaggad, S. Krishna Prasad
Summary: This study investigates the influence of the flexible spacer parity of a guest photoactive liquid crystalline dimer on the photonic bandgap features of the cholesteric and twist grain boundary smectic C phases of the host molecule. The results show that the parity of the photoactive dimer affects the width of the photonic bandgap and the blue-shift of the cholesteric phase. Additionally, the parity of the dimer also affects the layer spacing and two-dimensional periodicity of the liquid crystalline phases.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Sara Rozas, Alberto Gutierrez, Mert Atilhan, Alfredo Bol, Santiago Aparicio
Summary: This study presents a multiscale theoretical investigation on the use of bifunctional hydrophobic Deep Eutectic Solvent for carbon capture using tetrapropylammonium chloride, acetic acid, and ethanolamine. The characterization includes nanoscale analysis of CO2 absorption mechanisms and changes in liquid phase properties during gas capture.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Tabouli Eric Da-yang, Alhadji Malloum, Jean Jules Fifen, Mama Nsangou, Jeanet Conradie
Summary: In this study, the potential energy of different glycine tautomers and their interaction with Cu2+ cations was investigated. The results showed that the solvation medium and the presence of Cu2+ cations influenced the stability of glycine tautomers.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Xiaoliang Gou, Nan Ye, Qingqing Han, Junjie Cui, Long Yi Jin
Summary: In this study, amphiphilic rod-coil molecules with rigid DSA parts and flexible oligoether chains were designed and their assembly capacities were investigated. The morphology of the molecular aggregates was influenced by the pH of the solution and UV light, and the aggregates showed adsorption capacity for nitroaromatic compounds.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Shuang Liu, Liyan Shan, Cong Qi, Wenhui Zhang, Guannan Li, Bei Wang, Wei Wei
Summary: Optimizing the design of styrene-butadiene-styrene copolymer (SBS) is crucial for producing cost-effective SBS modifiers and improving road quality. This study examined the influence of SBS content and molecular structure on viscosity and compatibility. The results showed that the viscosity contribution of SBS is determined by its molecular structure and phase morphology.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Artem A. Petrov, Ekaterina A. Titova, Aydar A. Akhmadiyarov, Ilnaz T. Rakipov, Boris N. Solomonov
Summary: This work focuses on the thermochemistry of solvation of azeotropes. The enthalpies of dissolution of azeotropes in different mediums were determined, and the impact of the structure of the azeotropes on their properties in solution was discussed. A correlation between enthalpies of solvation and molar refraction was used to determine the vaporization enthalpies of azeotropes for the first time. The results were found to be consistent with literature data, obtained using direct and calculated methods. These findings contribute to the analysis of the structure-property relationships of azeotropes.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
L. V. Kamaeva, E. N. Tsiok, N. M. Chtchelkatchev
Summary: Understanding the correlations between liquids and solids allows us to predict the thermodynamic parameter range favorable for the formation of intriguing solid phases by studying liquids. In this study, we experimentally and theoretically investigated an Al-Cu-Co system within different composition ranges, and identified high-temperature solid phases. Our findings demonstrated the correlation between the boundaries of different solid phases and undercooling and viscosity in the concentration area.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
R. Aneesh Kumar, S. Jamelah Al-Otaibi, Y. Sheena Mary, Y. Shyma Mary, Nivedita Acharjee, Renjith Thomas, Renjith Raveendran Pillai, T. L. Leena
Summary: In this study, the interactions between doped and pristine coronenes and adenine nucleobases were investigated using Density Functional Theory. The optimal configurations, adsorption energies, charge transfer, and electrical properties of each complex were calculated. It was found that doped coronene had stronger adsorption strength and charge transfer compared to pristine coronene. The stability of the complexes was attributed to non-covalent interactions in the interactive region. The change in electrical conductivity of coronenes after adsorption suggested their sensitivity towards DNA bases. The predicted energy gap and prolonged recovery time for adenine-coronene configurations indicated the potential application of pristine/doped coronene in DNA detection.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Gang Zhou, Yongwei Liu, Biao Sun, Zengxin Liu, Cuicui Xu, Rulin Liu, Qi Zhang, Yongmei Wang
Summary: The CFD-DEM method was used to simulate the dust deposition pattern in the bronchus of anchor digging drivers, revealing the highest dust concentration in the vortex region of the working face. The study also found a positive correlation between dust particle diameter and bronchial deposition rate, and a negative correlation with alveolar deposition rate.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Yan Zhang, Yafei Luo, Lingkai Tang, Mingyan E, Jianping Hu
Summary: This study investigates the effects of different transition metal decorations on B12N12 nanocages on the adsorption properties of nitrosourea drugs using computational methods. The results reveal the presence of weak non-covalent interactions between metals and nanocages, and the interaction between drugs and nanocages plays a significant role in drug adsorption. Compared to free drugs, the adsorption of drugs on nanocages can facilitate electron transfer, reduce energy gaps and chemical hardness, indicating activity at the target site.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
C. I. Alcolado, J. Poblete, L. Garcia-Rio, E. Jimenez, F. J. Poblete
Summary: In this study, the selective oxidation of aromatic aldehydes was investigated using Ru(VI) as a catalyst and hexacyanoferrate (III) as a cooxidant in an alkaline medium. The reaction mechanism involves complex reaction orders for the oxidant and the aromatic aldehyde, while the reaction order for Ru(VI) is one. The proposed mechanism includes two catalytic cycles and the formation and decomposition of complexes. Quantitative structure-activity relationship analysis showed that deactivating groups in the para-position enhance the process.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Inez A. Barbieri, Marcos L. S. Oliveira, Franciele S. Bruckmann, Theodoro R. Salles, Leonardo Zancanaro, Luis F. O. Silva, Guilherme L. Dotto, Eder C. Lima, Mu. Naushad, Cristiano R. Bohn Rhoden
Summary: This study evaluated the adsorption of zolpidem on magnetic graphene oxide and synthesized magnetic graphene oxide adsorbents for zolpidem removal. The best magnetic nanoadsorbent was found to have a removal percentage of 87.07% at specific pH and temperature conditions. The results suggest that the removal of zolpidem is related to the surface chemistry of the adsorbent rather than the surface area of graphene oxide. The adsorbent showed excellent adsorption efficiency and magnetic behavior, making it a promising material for removing zolpidem from aqueous solutions.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Hongyan Huang, Chunquan Li, Siyuan Huang, Yuling Shang
Summary: This study examines the sensitivity of the thermal conductivity of water-based alumina nanofluids to changes in concentration, sphericity, and temperature. The results show that volume fraction and temperature have a significant impact on the thermal conductivity, while sphericity also needs to be considered. A support vector machine regression model was created to analyze the sensitivity of the thermal conductivity to different parameters. The findings indicate that temperature, sphericity, and volume fraction are the most sensitive variables.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Correction
Chemistry, Physical
V. M. Pergamenshchik, T. Bryk, A. Trokhymchuk
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Valentyn Rudenko, Anatolii Tolochko, Svitlana Bugaychuk, Dmytro Zhulai, Gertruda Klimusheva, Galina Yaremchuk, Tatyana Mirnaya, Yuriy Garbovskiy
Summary: This paper reports on the synthesis, structural characterization, spectral and nonlinear-optical properties of glass nanocomposites made of glass forming ionic liquid crystals and nanoparticles. The study reveals that by exciting the nanocomposites within their absorption band, a control over effective optical nonlinearities can be achieved, allowing the modification of the magnitude and sign of the effective nonlinear absorption coefficient. The proposed strategy using metal-alkanoates based glass-forming ionic liquid crystals and nanoparticles shows great potential for the development of nanophotonics and plasmonics technologies.
JOURNAL OF MOLECULAR LIQUIDS
(2024)