4.7 Article

Study on the Photocatalysis Mechanism of the Z-Scheme Cobalt Oxide Nanocubes/Carbon Nitride Nanosheets Heterojunction Photocatalyst with High Photocatalytic Performances

期刊

JOURNAL OF HAZARDOUS MATERIALS
卷 402, 期 -, 页码 -

出版社

ELSEVIER
DOI: 10.1016/j.jhazmat.2020.123839

关键词

carbon nitride; Z-scheme; photocatalysts; charge migration and separation

资金

  1. National Natural Science Foundation of China [51808250, 41603097, 51872109, 51676082, 41931292]
  2. Natural Science Foundation of Jiangsu Province of China [BK20181070]
  3. China Postdoctoral Science Foundation [2017M610336]
  4. Science and Technology Research Programs of Guangdong Province [2019A1515011015]
  5. Science and Technology Program of Guangzhou [201904010353]
  6. Fundamental Research Funds for the Central Universities [19lgpy157]
  7. Hong Kong Scholars Program

向作者/读者索取更多资源

The study developed an efficient Z-scheme Co3O4/g-C3N4 heterojunction photocatalyst with highly efficient interfacial charge migration and separation, exhibiting high photocatalytic activity for visible-light-driven reduction of Cr(VI) and oxidation of TC, especially the Co3O4/g-C3N4-0.04 sample.
An efficient Z-scheme Co3O4/g-C3N4 heterojunction photocatalyst was developed via in-situ forming Co3O4 nanocubes on the g-C3N4 nanosheet in the hydrothermal process. The obtained photocatalyst exhibited high photocatalytic activity for the visible-light-driven catalytic reduction of Cr(VI) and catalytic oxidation of tetra-cycline (TC). Among the as-synthesized catalysts, Co3O4/g-C3N4-0.04 (the mass ratio of g-C3N4 to Co3O4 is 0.04) sample exhibits the most efficient catalytic activities. The photocatalytic reduction and photocatalytic oxidation efficiencies of Co3O4/g-C3N4-0.04 can obtain 81.3 and 92.6 %, respectively. Moreover, the TC is mineralized in the course of photocatalytic degradation, 72.2% of TOC is removed from the reaction system. In addition, the apparent quantum efficiency for the removal of Cr(VI) was also obtained and the the Co3O4/g-C3N4-0.04 could achieve the highest apparent quantum efficiency among the samples. The enhancing photocatalytic activities originated from the efficient interfacial charge migration and separation obtained in Co3O4/g-C3N4-0.04, which is preliminarily confirmed by the photoluminescence spectra, time-resolved photoluminescence spectra and the photoelectrochemical characterizations. Finally, we speculate that the Co3O4/g-C3N4 heterostructures follow a more reasonable Z-scheme charge transfer in this study, which is confirmed by analyzing the results of electron paramagnetic resonance, radical scavenging experiments, and theoretical calculations.

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