Article
Chemistry, Multidisciplinary
Zhenyu Zhang, Anran Li, Haining Na, Fei Liu, Jin Zhu
Summary: In this study, amino-enriched g-C3N4 was used as a solid base to prepare micro-fibrillated cellulose (MCF) through the synergistic action with acid under microwave irradiation. The obtained MCF showed excellent adsorption ability and efficient photocatalytic degradation.
Article
Environmental Sciences
Giselle Gonzalez, Nanci Ehman, Yanina S. Aguerre, Sergio Henriquez-Gallegos, Ana P. Namikata da Fonte, Graciela I. B. Muniz, Miguel Pereira, Mayara E. Carneiro, Maria E. Vallejos, Fernando E. Felissia, M. Cristina Area
Summary: This study analyzed the physical and morphological properties of MFC obtained from different sources, showing that unbleached pine sawdust pulp is a low-cost and environmentally friendly raw material for MFC production, which can be produced with less energy and on a small scale.
WASTE AND BIOMASS VALORIZATION
(2022)
Article
Materials Science, Paper & Wood
Nanci Ehman, Agustina Ponce de Leon, Fernando E. Felissia, M. Cristina Area
Summary: This research focuses on producing bio-degradable MFC films from pine sawdust pulp, combined with food-grade polyols to enhance hydrophobicity and barrier properties. The mechanical properties, crystallinity, transparency, and biodegradation ability of the films were evaluated, indicating their potential application as liquid containers.
Article
Materials Science, Multidisciplinary
Zoheb Karim, Susanna Monti
Summary: Most polymeric membranes used in water decentralization today are synthesized through complicated and expensive processes, and are not environmentally friendly. Research shows that active hybrid membranes made of eco-friendly high-grade microfibrillated cellulose (MFC) have superior performance in separating metal ions from industrial effluents, and their separation efficiency can be adjusted by selecting the appropriate functional groups. This study has developed a chemo-enzymatic functionalization strategy to modify MFC fibers, adjusting the membrane properties and demonstrating promising potential for sustainable high-performance filtration devices.
ACS APPLIED POLYMER MATERIALS
(2021)
Article
Green & Sustainable Science & Technology
L. Bartolucci, S. Cordiner, A. Di Carlo, A. Gallifuoco, P. Mele, V. Mulone
Summary: Spent coffee grounds are a valuable biogenic waste that can be used as a source of biofuels and valuable chemicals through pyrolysis and solvent extraction processes. The study found that heavy organic bio-oil derived from coffee grounds can be used as a carbon-rich biofuel, while solvent extraction can extract xantines and p-benzoquinone, which are important chemicals for various industries. The results highlight the promising potential of solvent extraction in improving the economic viability of coffee grounds pyrolysis-based biorefineries.
Article
Biochemistry & Molecular Biology
Mouhanad Babi, Ayodele Fatona, Xiang Li, Christine Cerson, Victoria M. Jarvis, Tiffany Abitbol, Jose M. Moran-Mirabal
Summary: A versatile and efficient method based on click chemistry has been developed to fluorescently label nanocelluloses while preserving their native morphology and crystalline structure. This method allows for high degrees of labeling using minimal amounts of dye, making it cost-effective and suitable for various applications.
Article
Engineering, Environmental
Huimin Zhang, Jilong Wang, Guangbiao Xu, Yanfang Xu, Fumei Wang, Hua Shen
Summary: Cellulose aerogels with kapok/microfibrillated cellulose (MFC) exhibit ultralow density, ultrahigh porosity, and hydrophobicity, enabling advanced oil sorption and high absorption ability. These aerogels are cost-effective, sustainable, and possess excellent reusability, making them a suitable alternative for cleaning oil spills.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Materials Science, Paper & Wood
Amir Varamesh, Ragesh Prathapan, Ali Telmadarreie, Jia Li, Keith Gourlay, Gurminder Minhas, Qingye Lu, Steven L. Bryant, Jinguang Hu
Summary: Nanocellulose, particularly cellulose filaments (CFs), has shown great potential in formulating stable Pickering emulsions over a wide range of salt concentrations and pH levels. CFs can adsorb strongly to oil and water interfaces, providing stable surfactant-free emulsions with larger droplet sizes and comparable or better stability than conventional nanocelluloses. The higher viscosity of the continuous phase in the presence of CFs contributes to their effectiveness in emulsion stabilization.
Article
Materials Science, Paper & Wood
Adriano Reis Prazeres Mascarenhas, Mario Vanoli Scatolino, Matheus Cordazzo Dias, Maria Alice Martins, Rafael Rodolfo de Melo, Renato Augusto Pereira Damasio, Maressa Carvalho Mendonca, Gustavo Henrique Denzin Tonoli
Summary: This study investigates the pre-treatment of bleached Eucalyptus and Pinus fibers with sodium silicate and its effects on the quality index of cellulose micro/nanofibrils (MFC/CNF). The results show that sodium silicate pre-treatment improves the particle size and turbidity of Pinus fibers, but reduces the transparency of the films. In addition, sodium silicate increases the tensile strength of MFC/CNF and generates films with suitable packaging properties.
NORDIC PULP & PAPER RESEARCH JOURNAL
(2022)
Article
Biochemistry & Molecular Biology
Zhilu Rao, Yitong Dong, Jie Liu, Xuejing Zheng, Ying Pei, Keyong Tang
Summary: A strong and stable gelatin-based composite hydrogel was fabricated by incorporating amino-functionalized microfibrillated cellulose (AMFC) into the gelatin matrix. The addition of AMFC significantly improved the mechanical properties and structural stability of the gelatin hydrogel. The composite hydrogel exhibited excellent compressive strength and biocompatibility, making it promising for biomedical applications.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2022)
Article
Polymer Science
Ethan E. O'Banion, S. Shams Es-haghi
Summary: The rheological behavior of cellulose nanofibril (CNF) suspensions with different fines contents and solid concentrations was investigated. The samples showed a gel-like behavior with the highest dynamic moduli observed in samples with 50% fines. CNF suspensions with higher concentrations exhibited higher viscosity and dynamic moduli. A critical shear rate of 10 s-1 was found, above which viscosity measurements converged and below which they diverged. Yield stress decreased and then reached a plateau as fines levels increased. The lowest structure recovery was observed in samples with 50% fines content. A rheopectic-thixotropic transition was observed in samples with high fines content at low solid concentrations.
Article
Forestry
Muller de Souza Luana, Renato Queiroz Assis, Cristian Mauricio Barreto Pinilla, Rafaela Stange, Helena Cristina Vieira, Adriano Brandelli, Tania Maria Haas Costa, Alessandro de Oliveira Rios, Polliana D'Angelo Rios
Summary: This study aimed to obtain cellulose nanocrystals (CNC) through acid hydrolysis and evaluate their application potential in paper as a structural reinforcing agent. Papers incorporated with 12% and 18% CNC showed superior mechanical properties in tensile testing, improving paper quality. Optical properties remained unchanged after the addition of CNC.
WOOD SCIENCE AND TECHNOLOGY
(2021)
Article
Green & Sustainable Science & Technology
Nikos Giannakis, Miguel Carmona-Cabello, Aikaterini Makri, David Leiva-Candia, Katiana Filippi, Chrysanthi Argeiti, Chrysanthi Pateraki, M. P. Dorado, Apostolis Koutinas, Eleni Stylianou
Summary: A consolidated biorefinery was developed using spent coffee grounds and orange peel residues to produce microbial oil and value-added co-products. The biorefinery utilized extracted coffee oil and antioxidant-rich extracts from spent coffee grounds, as well as free sugars and pectin-rich extracts from orange peel residues. Microbial oil production was successfully achieved in a 30 L bioreactor scale using a combination of hydrolysates from both waste sources, resulting in high lipid accumulation and productivity. The properties of the microbial oil as biodiesel were found to generally meet European standards.
Article
Polymer Science
Flavia P. Morais, Joana M. R. Curto
Summary: This study focuses on designing and engineering sustainable biomaterials using natural fibers to replace non-renewable sources, with cellulose fibers and microfibrillated cellulose (MFC) being key components. The addition of eucalyptus essential oil (CMC/EO) into a 3D carboxymethylcellulose matrix provides controlled release functionalities. MFC improves strength while CMC/EO enhances absorption and strength properties.
Article
Biochemistry & Molecular Biology
Mastafa H. Al-Musawi, Ali Khoshkalampour, Hanan Adnan Shaker Al-Naymi, Zainab Farooq Shafeeq, Sepideh Pourvatan Doust, Marjan Ghorbani
Summary: This study evaluated the effects of nano-gels containing ginger essential oil on ethyl cellulose/casein nano-fibers. The results showed that adding these nano-gels improved the morphology, mechanical properties, and thermal stability of the fibers. The nano-gels also exhibited antioxidant properties and inhibited bacterial growth. Furthermore, the fibers showed no toxicity to normal cells and had good blood compatibility, indicating their potential use in food packaging materials.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Chemistry, Physical
Parul Johar, C. Robert McElroy, Elizabeth L. Rylott, Avtar S. Matharu, James H. Clark
Summary: In this study, a biologically bound non-noble metal catalyst was prepared using a simple and efficient method. The catalyst showed high efficiency and selectivity in catalytic hydrogenation, while effectively suppressing the over-hydrogenation reaction pathway. It has the advantages of simplicity, long-term stability, and easy handling, making it an economically and environmentally attractive alternative to traditional catalysts.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2022)
Article
Biology
Pooja Rani, Bilal Ahmed, Jagpreet Singh, Jasmeen Kaur, Mohit Rawat, Navjot Kaur, Avtar Singh Matharu, Muneera AlKahtani, Eman A. H. Alhomaidi, Jintae Lee
Summary: This study reports the green synthesis of silver nanostructures using waste Brassica oleracea leaves and evaluates their efficacy in 4-nitrophenol reduction, glucose sensing, and antimicrobial activity.
SAUDI JOURNAL OF BIOLOGICAL SCIENCES
(2022)
Review
Chemistry, Multidisciplinary
Simerjeet Parmar, Harwinder Kaur, Jagpreet Singh, Avtar Singh Matharu, Seeram Ramakrishna, Mikhael Bechelany
Summary: This review evaluates recent advances in biological approaches for synthesis of silver nanoparticles and explores their antimicrobial potential and mechanisms of action. Moreover, it briefly discusses the potential toxic effects of silver nanoparticles on animals, the environment, and human health.
Article
Chemistry, Multidisciplinary
Aashima Sharma, Surinder K. Mehta, Avtar S. Matharu
Summary: Phosphorus is becoming critical as its global supply and demand reach unsustainable levels. This study reports the synthesis, characterization, and application of a novel biomass-derived mesoporous carbonaceous material decorated with CeO2 as an efficient catalyst for dephosphorylation reactions.
Article
Chemistry, Multidisciplinary
Rajdeep Kaur, Jagpreet Singh, Deepika Kathuria, Avtar Singh Matharu
Summary: A facile method for synthesizing carbon quantum dots and silver nanoparticle carbon quantum dots nanocomposites from syzygium cumini leaves for the sensing of Hg2+ ions is reported. The synthesized CQDs were characterized and exhibited selective colorimetric sensing properties, avoiding the use of expensive and toxic materials.
SUSTAINABLE CHEMISTRY AND PHARMACY
(2022)
Article
Chemistry, Multidisciplinary
Lauren I. Austen, Thomas I. J. Dugmore, Avtar S. Matharu, Glenn A. Hurst
Summary: This experiment introduces students to the valorization of byproducts by producing a biodiesel analogue from spent coffee grounds. By analyzing spectroscopic characteristics and green metrics, students apply green concepts and sustainable development goals to real-world problems, demonstrating the value of waste and the importance of reducing fossil fuel consumption.
JOURNAL OF CHEMICAL EDUCATION
(2023)
Article
Engineering, Chemical
Yang Gao, Hannah K. Briers, Avtar S. Matharu, Jiajun Fan
Summary: The exploration of cucumber waste as a biorefinery feedstock is reported. The essential oils in cucumber waste were successfully extracted using vacuum microwave hydro-distillation (VMHD), with higher quality and yield compared to traditional hydro-distillation (HD). The resulting residues were rich in cellulose and showed no significant changes after VMHD and HD treatment, providing an efficient, inexpensive, and environmentally friendly platform for cellulose material production.
Article
Materials Science, Multidisciplinary
Uji Pratomo, Rifky Adhia Pratama, Allyn Pramudya Sulaeman, Irkham, Grandprix T. M. Kadja, Munawar Khalil, Indah Primadona
Summary: The functionalized zinc oxide nanotube coated with MXene layer was successfully prepared using a simple dipping method. The existence of the prepared material was confirmed through various characterization techniques. The modification of ZnO NT with MXene resulted in a decrease in bandgap value and an increase in photoelectrochemical performance. The current density of ZnO NT/MXene was about 0.2 mA/cm2 (1.4 V vs Ag/AgCl), which is twice as high as that of ZnO NT. Additionally, the oxygen evolution of the modified ZnO NT was 1.5 times higher than the pristine one, indicating effective hole junction/charge transfer in ZnO NT/MXene.
Article
Green & Sustainable Science & Technology
E. Frecha, J. Remon, A. P. Sulaeman, A. S. Matharu, I. Suelves, J. L. Pinilla
Summary: The zero-waste biorefinery concept focuses on cellulose defibrillation from almond hulls using hydrotreatment technologies. Hemicellulose is converted into sugar alcohols and/or polyols, while bioactive compounds and chemically stabilized energy carriers are extracted from the hydrolysate stream for fuel additive and/or fuel intermediate production.
JOURNAL OF CLEANER PRODUCTION
(2023)
Article
Chemistry, Multidisciplinary
Allyn Pramudya Sulaeman, Rifky Adhia Pratama, Uji Pratomo, Irkham, Avtar S. Matharu, Indah Primadona
Summary: By sensitizing ZnO nanopencils with sulfur and nitrogen co-doped graphene quantum dots (S,N-GQDs), the photo absorption range of ZnO nanopencils can be expanded to the visible light spectrum, and the light harvesting efficiency can be significantly improved. The results indicate that ZnO NPc/S,N-GQDs shows remarkable improvement in photoelectrochemical activity under visible light irradiation.
Article
Engineering, Environmental
E. Frecha, D. Torres, J. Remon, R. Gammons, A. S. Matharu, I. Suelves, J. L. Pinilla
Summary: Carbon nanostructures provide a unique platform for the synthesis of novel catalysts for biomass conversion. In this study, a series of graphene oxide (GO)-based materials were prepared and their catalytic behavior was compared. It was found that the reactivity of the GO-catalyst was related to their degree of oxidation/exfoliation, and the use of microwave radiation enabled similar kinetic profiles with considerably less amount of catalyst.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Review
Chemistry, Physical
Yingdong Zhou, Javier Remon, Zhicheng Jiang, Avtar S. Matharu, Changwei Hu
Summary: The chemical transformation of natural oils provides alternatives to limited fossil fuels and produces compounds with added value for the chemical industries. This review summarizes recent progress in catalytic deoxygenation of natural oils to renewable liquid fuels and valuable fatty alcohols. It also discusses strategies to control product selectivity and proposes future research goals. Rating: 8/10
GREEN ENERGY & ENVIRONMENT
(2023)
Article
Chemistry, Multidisciplinary
Suranjana Bose, Rebecca D. Kirk, Harry Maslen, Martha A. Pardo Islas, Benedict Smith, Thomas I. J. Dugmore, Avtar S. Matharu
Summary: In this study, degreased coffee grounds were used as precursors to produce highly mesoporous activated carbons for efficient removal of manganese ions. The commonly used activating agent, ZnCl2, was replaced by benign and sustainable CaCl2 and K2CO3. The adsorption process followed pseudo-second order kinetics and was spontaneous.
Article
Engineering, Environmental
Shun-Shun Chen, Xu-Xiu Chen, Tian-Yu Yang, Li Chen, Zheng Guo, Xing-Jiu Huang
Summary: A temperature-modulated sensing strategy was proposed to identify and determine BTEX compounds. Highly effective identification of BTEX was achieved using linear discrimination and convolutional neural network analyses. Additionally, quantitative analysis of concentration was accomplished by establishing the relationship between concentration and response.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Myungkyung Noh, Jeong Yeon Sim, Jisung Kim, Jee Hwan Ahn, Hye-Young Min, Jong-Uk Lee, Jong-Sook Park, Ji Yun Jeong, Jae Young Lee, Shin Yup Lee, Hyo-Jong Lee, Choon-Sik Park, Ho-Young Lee
Summary: This study reveals that chronic exposure to PM induces chronic inflammation and development of COPD by dysregulating NAD+ metabolism and subsequent SIRT1 deficiency in pulmonary macrophages. Activation of SIRT1 by resveratrol effectively mitigates PM-induced inflammation and COPD development. Targeting metabolic and epigenetic reprogramming in macrophages induced by PM is a promising strategy for COPD treatment.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Yu Liu, Linlin Qin, Yiming Qin, Tong Yang, Haoran Lu, Yulong Liu, Qiqi Zhang, Wenyan Liang
Summary: Co/NC/PAC electrode was prepared by compounding ZIF-67 with powder-activated carbon for the electrocatalytic treatment of nitrogen-containing heterocyclic compounds. The degradation efficiency of the four compounds reached 90.2-93.7% under optimal conditions, and the degradation order was pyridazine < pyrimidine < pyrazine < pyridine.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Julien Couturier, Pierre Tamba Oulare, Blanche Collin, Claire Lallemand, Isabelle Kieffer, Julien Longerey, Perrine Chaurand, Jerome Rose, Daniel Borschneck, Bernard Angeletti, Steven Criquet, Renaud Podor, Hamed Pourkhorsandi, Guilhem Arrachart, Clement Levard
Summary: This study analyzes the properties of bauxite residue samples and explores the influence of bauxite ore origin, storage conditions, and storage time. The results show that the speciation of yttrium is related to the origin of bauxite ore, while no significant variation was observed with storage conditions or aging of the residues.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Sakthinarenderan Saikumar, Ravi Mani, Mirunalini Ganesan, Inbakandan Dhinakarasamy, Thavamani Palanisami, Dharani Gopal
Summary: Microplastic contamination in marine ecosystems poses a growing concern due to its trophic transfer and negative effects on marine organisms. This study investigates the transfer and impacts of polystyrene microplastics in an estuarine food chain. The results show that microplastics can be transferred through the food chain, although the transfer rates are low. The exposed organisms exhibit stress responses, suggesting the potential risk of microplastics reaching humans through the food chain.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Review
Engineering, Environmental
Yan-Jiao Li, Ying Yuan, Wen-Bing Tan, Bei-Dou Xi, Hui Wang, Kun-Long Hui, Jia-Bao Chen, Yi-Fan Zhang, Lian-Feng Wang, Ren-Fei Li
Summary: This review investigated and analyzed the distribution, composition, and abundance of heavy metals and antibiotic resistance genes (ARGs) in landfill. The results showed that heavy metals have lasting effects on ARGs, and complexes of heavy metals and organic matter are common in landfill. This study provides a new basis to better understand the horizontal gene transfer (HGT) of ARGs in landfill.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Jessy Joseph, Ari Vaisanen, Ajay B. Patil, Manu Lahtinen
Summary: Efficient and environmentally friendly porous hybrid adsorbent beads have been developed for the removal of arsenic from drinking water. The structural tuning of the adsorbents has been shown to have a significant impact on their adsorption performance, with high crystallinity leading to increased adsorption capacity and selectivity towards As5+.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Yangyang Liu, Minhua Xiao, Kaiqin Huang, Juntao Cui, Hongli Liu, Yingxin Yu, Shengtao Ma, Xihong Liu, Meiqing Lin
Summary: This study measured the levels of phthalate metabolites in breast milk collected from mothers in southern China. The results showed that phthalates are still prevalent in the region, and breastfeeding contributes to phthalate intake in infants. However, the levels detected do not pose significant health risks to infants based on dietary exposure. The increasing exposure to certain phthalates calls for further research into their sources and potential risks.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Zhiqiang Wu, Jianxing Sun, Liting Xu, Hongbo Zhou, Haina Cheng, Zhu Chen, Yuguang Wang, Jichao Yang
Summary: Ocean depth affects microbial diversity, composition, and co-occurrence patterns of microplastic microbial communities. Deterministic processes dominate the assembly of mesopelagic plastisphere microbial communities, while stochastic processes shape the assembly of bathypelagic microbial communities. The relationships between microorganisms in the mesopelagic layer are more complex and stable, with Proteobacteria and Actinobacteriota playing important roles.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Tingting Xiao, Renjie Chen, Chen Cai, Shijie Yuan, Xiaohu Dai, Bin Dong, Zuxin Xu
Summary: Based on the efficiency of catalytic ozonation techniques in enhancing sludge dewaterability, this study investigated its effectiveness in simultaneous reduction of antibiotics and antibiotic resistance genes. The results showed that catalytic ozonation conditioning changed the distribution of antibiotics and achieved high degradation rates. It also significantly reduced the abundance of ARGs, inhibited horizontal gene transfer, and decreased the signal transduction of typical ARGs host bacteria.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Yang Deng, Xiaohong Guan
Summary: This article discusses two different development approaches for ferrate(VI) technology in water treatment, arguing that process integration is a promising method that can drive technological innovation and revolution in water treatment, achieving higher treatment efficiency, reduced costs and energy consumption, and a smaller physical footprint.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Zhe Zhang, Lu Zhang, Zhihao Huang, Yuxin Xu, Qingqing Zhao, Hongju Wang, Meiqing Shi, Xiangnan Li, Kai Jiang, Dapeng Wu
Summary: In this study, a floating catalytic foam was designed and prepared to enhance the mass transfer in immobilized photocatalysts for wastewater treatment. The floating catalytic foam could float on the water surface and establish a temperature gradient, effectively promoting the diffusion and adsorption of target molecules during the photocatalytic process.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Muhammad Nafees, Adiba Khan Sehrish, Sarah Owdah Alomrani, Linlin Qiu, Aasim Saeed, Shoaib Ahmad, Shafaqat Ali, Hongyan Guo
Summary: The accumulation of cadmium and antibiotics in edible plants and fertile soil is a worldwide problem. This study investigated the potential of zinc oxide nanoparticles to alleviate the toxicity of both cadmium and antibiotics and promote spinach growth.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Lurui Wan, Kai Wang, Yuan Chen, Zhiyong Xu, Wenbo Zhao
Summary: In this study, a low viscosity and high thermal stability SO2 absorbent with dual interacting sites was successfully synthesized. The absorbent showed the highest absorption enthalpy change and entropy change values among reported SO2 absorbents, and exhibited lower viscosity and comparable thermal stability to ILs.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Zhengwei Zhou, Guojie Ye, Yang Zong, Zhenyu Zhao, Deli Wu
Summary: This study utilized Mo powder and STPP to enhance the performance of the sodium percarbonate system in pollutant degradation. The presence of Mo and STPP resulted in a higher degradation rate of the model pollutant SMX, with low oxidant consumption. The system generated multiple active species through a series of chain reactions at different pH values, exhibiting excellent performance towards electron-rich pollutants. Furthermore, Mo demonstrated excellent stability and reusability.
JOURNAL OF HAZARDOUS MATERIALS
(2024)