期刊
JOURNAL OF FLUORINE CHEMISTRY
卷 240, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2020.109653
关键词
Fluorosulfonylation; Arenediazonium salts; Sulfur dioxide insert; Fluorination; Transition-metal-free; Radical
资金
- National Natural Science Foundation of China [21421002, 21991211]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
A transition-metal-free Sandmeyer-type fluorosulfonylation reaction has been achieved by the three-component reaction of arenediazonium tetrafluoroborates, Na2S2O5, and N-fluorobenzenesulfonimide (NFSI). The reaction proceeds through a radical tandem process, affording various arenesulfonyl fluorides in moderate to high yields. This protocol not only provides a complement to the previous fluorosulfonylation reactions, but also extends the applications of Sandmeyer reaction.
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