4.7 Article

Synthesis of anhydrite from red gypsum and acidic wastewater treatment

期刊

JOURNAL OF CLEANER PRODUCTION
卷 278, 期 -, 页码 -

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.jclepro.2020.124026

关键词

Red gypsum; Anhydrous calcium sulfate; Step precipitation; Cycle number; Preparation mechanism

资金

  1. National Key R&D Program of China [2018YFC1802902]
  2. doctoral foundation of Southwest University of Science and Technology [17ZX7117]
  3. Longshan academic talent research and Innovation Team Project of SWUST [18lzx401]

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A one-step process for leaching red gypsum to produce anhydrite was proposed, achieving a high leaching rate and quality product through optimized control conditions. The method of using the leaching solution in a circular manner and recovering valuable components were also emphasized.
One-step process of red gypsum leaching to produce anhydrite was proposed. The effects of sulfuric acid concentration, reaction temperature and reaction time on both the leaching rate of red gypsum, the phase and micro-morphology of the product were systematically investigated. The acid leaching solution was tried to use circularly. And the valuable components in the leaching solution were recovered by step precipitation. Anhydrous calcium sulfate powder with anhydrite crystal phase and smooth and serrate morphology was successfully produced. The leaching rate of red gypsum was 39.82% under optimized conditions. The optimum cycle number for the reuse of acid leaching solution was 5. Sulfate ions and iron ions in the leaching solution were recovered by adjusting the pH value. A preparation mechanism of anhydrite from red gypsum was also proposed by theoretical analysis. All of these indicated that the whole procedure setup showed potential application for red gypsum utilization. (C) 2020 Elsevier Ltd. All rights reserved.

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