Selective hydrogenation of cinnamaldehyde with NixFe1-xAl2O4+δ composite oxides supported Pt catalysts: C=O versus C=C selectivity switch by varying the Ni/Fe molar ratios

Due to coexistence of two conjugated unsaturated functional groups in cinnamaldehyde (CAL), exploring efficient catalysts with desirable selectivity to highly value-added products is still challengeable for the selective hydrogenation of CAL. Herein, NixFe1-xAl2O4+delta spinel composite metal oxides (SCMOs) supported Pt catalysts were developed and proved to be active and selective for the selective hydrogenation of CAL. Moreover, the selectivity switch can be realized just by changing the Ni/(Fe + Ni) molar ratios in NixFe1-xAl2O4+delta SCMOs. As a result, the excellent cinnamyl alcohol (COL) selectivity (-92.2%) and hydrocinnamaldehyde (HCAL) selectivity (-80.7%) were achieved on Pt/FeAl2O4+delta and Pt/NiAl2O4+delta, respectively. Based on the kinetic investigation of further hydrogenation of semi-hydrogenated product, the reason for the selectivity switch with Pt/NixFe1-xAl2O4+delta was revealed. In combination with detailed characterization, the excellent COL selectivity on Pt/FeAl2O4+delta can be attributed to more Pt(1 1 1) facets and FeOx species which can facilitate the preferential activation of C=O bonds; while the high HCAL selectivity on Pt/NiAl2O4+delta is owing to the fact that there are more low coordinated active sites and two neighbouring Pt sites. (C) 2020 Elsevier Inc. All rights reserved.

Automated summary

The study developed NixFe1-xAl2O4+delta spinel composite metal oxides (SCMOs) supported Pt catalysts, which showed activity and selectivity for the selective hydrogenation of CAL. The selectivity switch can be achieved by changing the Ni/(Fe + Ni) molar ratios in NixFe1-xAl2O4+delta SCMOs.