Article
Chemistry, Physical
Kyeongmin Moon, Hack-Keun Lee, Youchang Park, Sanha Jang, Hyeonhan Lim, Ji Chan Park, Kang Hyun Park
Summary: A facile method for synthesizing highly dispersed molybdenum disulfide nanoparticles on Ketjenblack carbon support has been developed, showing good onset potential, high durability, and excellent methanol tolerance for oxygen reduction reactions.
Article
Nanoscience & Nanotechnology
Amit Chaturvedi, Patit Paban Kundu
Summary: High-performance cobalt nanoparticles supported on a zeolite-graphene oxide matrix have been synthesized and exhibit outstanding oxygen reduction reaction (ORR) performance and electrocatalytic properties. When applied as the cathode electrocatalyst in a single-chambered microbial fuel cell, the coated catalyst generates significantly higher power density compared to a Pt/C catalyst.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Multidisciplinary Sciences
Tao Meng, Pingping Sun, Feng Yang, Jie Zhu, Baoguang Mao, Lirong Zheng, Minhua Cao
Summary: This study investigates the use of bulk defects (FPDs) to improve the surface properties of metallic cobalt catalysts for the oxygen reduction reaction (ORR). The introduction of FPDs creates a unique type of surface catalytic site with concave geometry and compressive strain, which weakens oxygen binding. The catalyst exhibits excellent activity and stability in metal-air batteries and fuel cells, making it a promising alternative to precious metal catalysts.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
(2022)
Article
Chemistry, Physical
Song-Jeng Huang, Aristotle T. Ubando, Yan-Ting Lin, Chuan-Yun Wang, Alvin B. Culaba, Chin-Tsan Wang
Summary: This study evaluates the performance of three oxygen reduction catalysts in microbial fuel cells, with results showing that the B12/CNT catalyst exhibits the highest performance. This research could facilitate the application of wastewater for energy conversion.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Multidisciplinary
Ki Ro Yoon, Chang-Kyu Hwang, Seung-hoon Kim, Ji-Won Jung, Ji Eon Chae, Jun Kim, Kyung Ah Lee, Ahyoun Lim, Su-Ho Cho, Jitendra Pal Singh, Jong Min Kim, Kihyun Shin, Byung Moo Moon, Hyun S. Park, Hyoung-Juhn Kim, Keun Hwa Chae, Hyung Chul Ham, Il-Doo Kim, Jin Young Kim
Summary: Optimized design of bifunctional oxygen electrocatalysts is crucial for achieving high-performance energy conversion systems. The novel CoOx@CoNy/NCNF hybrid catalyst exhibits excellent oxygen reduction and oxygen evolution reaction activity, catalyzing redox reactions effectively and enhancing the stability of Zn-air batteries.
Article
Chemistry, Multidisciplinary
Sung Yul Lim, Santiago Martin, Guohua Gao, Yibo Dou, Soren Bredmose Simonsen, Jens Oluf Jensen, Qingfeng Li, Kion Norrman, Shao Jing, Wenjing Zhang
Summary: The expedited conversion of O-2 to H2O with minimal amounts of Pt is crucial for the wide applicability of PEM fuel cells. Developing a process for catalyst management is essential to avoid unnecessary catalyst loss while enhancing Pt utilization, catalytic activity, and durability. The fabrication of self-standing nanofiber electrodes using electrospinning simplifies the operation of cell devices and reduces Pt loss, showing excellent performance due to the synergistic interaction between Pt-Co and Co-N-x nanoparticles.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Nanoscience & Nanotechnology
Ruisong Li, Peng Rao, Junming Luo, Wei Huang, Chunman Jia, Jing Li, Peilin Deng, Yijun Shen, Xinlong Tian
Summary: This study developed a nitrogen-doped carbon catalyst (CON-900) using cellulose as a carbon precursor. CON-900 exhibited high activity, stability, and poisoning resistance for the oxygen reduction reaction. The microbial fuel cell (MFC) fabricated with CON-900 as a cathode catalyst demonstrated a comparable maximum power density to that of a Pt/C cathode.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Materials Science, Ceramics
Huiying Qi, Peng Qiu, Tonghuan Zhang, Di Liu, Mojie Cheng, Baofeng Tu
Summary: This study proposes cost-effective cathode materials with high catalysis activity for use in intermediate-temperature solid oxide fuel cells. Cobalt-free composites were synthesized using a smart self-assembled method, primarily utilizing doped-BaZrO3 and doped-BaFeO3 cubic perovskites. Both composite cathodes exhibit nano- and micro-particles with extensive heterointerfaces and excellent cathode| electrolyte interfaces, which can assist the surface catalysis and oxygen species transport. A cell with a BSrFZ composite cathode achieved a higher maximum power density compared to that with a BSmFZ composite cathode, benefiting from its enriched oxygen vacancies and high surface and heterointerface activities.
CERAMICS INTERNATIONAL
(2022)
Article
Engineering, Environmental
Weifeng Liu, Zihao Zhou, Zhe Li, Yan Yang, Jiao Zhao, Yimin Zhu, Wenjing Miao
Summary: The study introduces a cost-effective non-precious metal catalyst CoP@N-C for oxygen reduction reaction in microbial fuel cells, demonstrating enhanced catalytic activity and power density, compared to traditional activated carbon control.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Chemistry, Physical
Feifei Dong, Zilin Ma, Qirui Ye, Bingkai Zhang, Lu Li, Guangming Yang, Meng Ni, Zhan Lin
Summary: This study reports a highly active and robust cobalt-free perovskite oxygen electrode, prepared by a facile co-doping strategy, for intermediate-to-low temperature SOFCs. The cathode exhibits exceptional catalytic performance and stability, suggesting an effective strategy for the development of perovskite-type cathodes for SOFCs and related applications.
Article
Chemistry, Physical
Quan Yang, Taoli Sun, Yanzhi Ding, Xiaoyong Lu, Dong Tian, Bin Lin
Summary: This study investigates the effects of K and F doping on the performance of conventional cobalt-free cathode SSF. The results show that both K and F doping significantly enhance the electrochemical performance of SSF, but co-doping leads to decreased performance.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Physical
Yuande Shi, Jiannan Cai, Xiaofeng Zhang, Zhongshui Li, Shen Lin
Summary: In this study, Co-Ni (trace)/NCNTs with superior dual-functional electrocatalytic performance for ORR and OER were successfully synthesized using a one-pot vapor deposition method. The catalyst showed excellent stability during durability testing and provides a feasible strategy for designing efficient nonnoble metal-catalysts for renewable energy conversion devices.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Chemistry, Physical
Yun Chen, Sergio A. Paredes-Navia, Cesar-Octavio Romo-De-La-Cruz, Liang Liang, Andre Fernandes, Alec Hinerman, Jacky Prucz, Mark Williams, Xueyan Song
Summary: The study demonstrates that applying a unary electrocatalyst of Pt or CoOx to the LSCF/SDC composite electrode can mitigate the cation surface segregation and improve conductivity and the oxygen reduction reaction. ALD coating reduces cell ohmic resistance and enhances cathode conductivity and durability.
JOURNAL OF POWER SOURCES
(2021)
Article
Chemistry, Applied
Feifei Dong, Zhenghui Gao, Bingkai Zhang, Lu Li, Ziqi Kong, Zilin Ma, Meng Ni, Zhan Lin
Summary: A novel cobalt-free perovskite oxide, Ba0.75Sr0.25Fe0.875Ga0.125O3-delta (BSFG), has been developed as an efficient oxygen reduction electrode for solid oxide fuel cells (SOFCs), demonstrating exceptional electrochemical performance at 600 degrees C. The stable crystalline structure and favorable thermal expansion behavior contribute to the short-term performance stability of the cathode.
JOURNAL OF ENERGY CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Yanmin Hu, Mengzhao Zhu, Xuan Luo, Geng Wu, Tingting Chao, Yunteng Qu, Fangyao Zhou, Rongbo Sun, Xiao Han, Hai Li, Bin Jiang, Yuen Wu, Xun Hong
Summary: Efficient and highly stable catalysts for the oxygen reduction reaction are essential for long-term operation of proton exchange membrane fuel cells. The coplanar Pt-carbon nanomeshes synthesized in this study exhibit excellent activity and stability in fuel cell tests, with peak power density of 1.21 W cm(-2) and current density of 0.360 A cm(-2) at 0.80 V in the H-2/O-2 cell. Density-functional theory analysis suggests that the increased vacancy formation energy of Pt atoms in coplanar Pt/C NMs helps restrain Pt dissolution and aggregation.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Multidisciplinary
Sagar B. Ingavale, Indrajit M. Patil, Haridas B. Parse, Niranjan Ramgir, Bhalchandra Kakade, Anita Swami
NEW JOURNAL OF CHEMISTRY
(2018)
Article
Chemistry, Physical
Haridas B. Parse, Indrajit Patil, Sagar Ingavale, Clement Manohar, V. A. L. Roy, Bhalchandra Kakade
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2019)
Article
Chemistry, Physical
Sagar B. Ingavale, Indrajit Patil, Haridas Parse, Divya Catherin Sesu, Phiralang Marbaniang, Niranjan Ramgir, Bhalchandra Kakade, Anita Swami
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2019)
Article
Chemistry, Physical
Phiralang Marbaniang, Sagar Ingavale, Divya Catherin, Niranjan Ramgir, Anita Swami, Bhalchandra Kakade
JOURNAL OF CATALYSIS
(2019)
Article
Chemistry, Physical
K. Prabakaran, Sagar B. Ingavale, Bhalchandra Kakade
JOURNAL OF ALLOYS AND COMPOUNDS
(2020)
Article
Chemistry, Multidisciplinary
Divya Catherin Sesu, Phiralang Marbaniang, Sagar Ingavale, Arva Clement Manohar, Bhalchandra Kakade
Article
Chemistry, Multidisciplinary
Anita Swami, Indrajit Patil, Moorthi Lokanathan, Sagar Ingavale, Bhalchandra Kakade
Article
Chemistry, Applied
Sagar Ingavale, Phiralang Marbaniang, Bhalchandra Kakade, Anita Swami
Summary: The nitrogen-doped starbon/zinc oxide composite (NS/ZnO) synthesized in this study exhibits enhanced electrocatalytic activity towards oxygen reduction reaction (ORR) and has the potential to be used in energy conversion and storage devices.
Article
Chemistry, Physical
Phiralang Marbaniang, Sagar Ingavale, Prabakaran Karuppanan, Anita Swami, Bhalchandra Kakade
Summary: In this study, nitrogen-doped multiwalled carbon nanotubes (N-CNTs) were prepared using melamine foam as a template to address the challenges of platinum-based catalysts for oxygen reduction reaction in low temperature fuel cells. The N-CNT catalysts showed superior ORR activity and stability compared to Pt/C, with onset potentials indicating better performance. The use of melamine as a precursor resulted in the best performing N-CNT catalyst with excellent methanol tolerance.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Energy & Fuels
Phiralang Marbaniang, Samadhan Kapse, Sagar Ingavale, Ranjit Thapa, Bhalchandra Kakade
Summary: A cost-effective electro-catalyst for oxygen reduction reaction (ORR) was developed by creating a composite of nitrogen-doped carbon nanotubes and graphene oxide. This composite showed enhanced efficiency and durability in ORR performance compared to commercial catalysts, thanks to improved active adsorption sites and corrosion resistance.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2021)
Article
Energy & Fuels
Suresh Pavithra, Vinoth Kumar Jothi, Arulmozhi Rajaram, Sagar Ingavale, Abirami Natarajan
Summary: A bimetallic metal-organic framework (MOF) codoped with carbon nanodots (CNDs) was synthesized via solvothermal treatment. The composite material exhibited efficient oxygen evolution reaction (OER) electrocatalytic activity.
Article
Chemistry, Multidisciplinary
Sagar Ingavale, Phiralang Marbaniang, Manoj Palabathuni, Vaibhav Namdev Kale, Nimai Mishra
Summary: Clean water and sanitation are major global challenges, with groundwater being the main source of freshwater. However, human activities have led to water pollution, particularly with the presence of nitrates in groundwater due to intensive fertilizer use and wastewater discharge. This study focuses on the electrochemical reduction of nitrates to ammonia using an efficient catalyst, a composite of amorphous boron with graphene oxide (B@GO). The B@GO catalyst exhibited excellent nitrate reduction performance with a high faradaic efficiency and ammonia formation rate.
Article
Chemistry, Physical
Carolin Mercy Enoch, Sagar Ingavale, Phiralang Marbaniang, Indrajit Patil, Anita Swami
Summary: We report a molten-salt pathway for the synthesis of strontium manganese perovskite oxide (SMO) and investigate its phase transition with temperature variation. We also demonstrate the intrinsic catalytic behavior of different phases towards the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER). The results show that the temperature-dependent structural transition of SMO affects its electrocatalytic activity.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)