Review
Engineering, Chemical
Shuaifei Zhao, Zhipeng Liao, Anthony Fane, Jiansheng Li, Chuyang Tang, Chunmiao Zheng, Jiuyang Lin, Lingxue Kong
Summary: This review analyzes the correlations between membrane properties and antifouling performance, evaluating three key strategies to engineer fouling resistant thin film composite RO membranes. Insights and future outlooks on strategies for engineering next generation of high performance RO membranes with durable fouling resistance are offered.
Article
Chemistry, Physical
Morteza Afsari, Ho Kyong Shon, Leonard D. Tijing
Summary: Membrane distillation (MD) is a promising technology for producing freshwater from seawater or wastewater, but faces challenges such as low flux and fouling. Recently, Janus membranes have shown potential to address these issues and improve performance in desalination and wastewater treatment utilizing MD.
ADVANCES IN COLLOID AND INTERFACE SCIENCE
(2021)
Review
Energy & Fuels
Mostafa Ghasemi, Mehdi Sedighi, Mohammad Mahdi Behvand Usefi
Summary: Increasing populations and urbanization have led to increased pressure on freshwater supplies. The use of seawater as a source of freshwater can meet the increased demand for drinking water. Microbial desalination cells (MDCs) have emerged as a promising technology that can treat wastewater, desalinate seawater, and generate electricity and value-added products. This study examines the effect of membranes on the efficiency and performance of MDCs, with carbon nanotube membranes showing significant improvements compared to other membranes.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2022)
Review
Chemistry, Multidisciplinary
Tianlong Ni, Jiuyang Lin, Lingxue Kong, Shuaifei Zhao
Summary: Membrane distillation (MD) is a promising technology for desalination and water purification, with recent advancements in omniphobic membranes to combat wetting and fouling issues. This paper provides a comprehensive review of the fundamentals, properties, advantages, applications, and engineering methods of omniphobic membranes. Future research on omniphobic membranes will focus on addressing challenges for stable and efficient MD operations.
CHINESE CHEMICAL LETTERS
(2021)
Review
Chemistry, Physical
Ziwen Yuan, Yanxi Yu, Xiao Sui, Yuanyuan Yao, Yuan Chen
Summary: Carbon composite membranes show great potential for addressing the challenges in thermal-driven membrane processes, such as MD and PV. Recent research has focused on developing these membranes and enhancing their performance and stability, creating antifouling properties, and resolving the trade-off between permeability and selectivity. Further studies have also explored new MD processes enabled by carbon materials, highlighting the promising future research directions in this field.
Article
Chemistry, Physical
Yinsheng Yu, Xinyu Xie, Songzhen Tang
Summary: This study establishes the microstructures of pressure-driven seawater desalination based on a porous graphene membrane and investigates its desalination performance through molecular dynamics simulations. The results show that the desalination efficiency can be improved by increasing the external pressure, graphene pore diameter, and temperature.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Engineering, Chemical
P. S. Goh, H. S. Kang, A. F. Ismail, N. Hilal
Summary: Water scarcity is a pressing global issue, and desalination is seen as a sustainable alternative for providing freshwater. Hybridization of desalination processes is recognized as a promising approach to address the shortcomings of traditional desalination methods, and thermal-based hybrid desalination systems are expected to be the future trend in commercial-scale desalination operations.
Article
Biochemistry & Molecular Biology
Subaer Subaer, Hamzah Fansuri, Abdul Haris, Misdayanti Misdayanti, Imam Ramadhan, Teguh Wibawa, Yulprista Putri, Harlyenda Ismayanti, Agung Setiawan
Summary: This research focuses on the quality and suitability of pervaporation membranes for seawater desalination based on Geo-rGO-TiO2 nanocomposite. The membranes achieved a high permeate flux of up to 2.29 kg/m(2)center dot h with a salt rejection of around 91%. However, long-term pressure and temperature feed can lead to significant cracking in the membranes.
Article
Engineering, Chemical
Dong Zou, Longbo Xia, Ping Luo, Kecheng Guan, Hideto Matsuyama, Zhaoxiang Zhong
Summary: In this study, high-porosity PVDF-PSF membranes were prepared by dissolving PVDF and PSF polymer powders in PolarClean. The addition of PVDF nanoparticles on the membrane surface improved the hydrophobicity and liquid entry pressure of the membrane. These membranes exhibited high water flux and excellent desalination performance.
Article
Chemistry, Multidisciplinary
Kecheng Guan, Yuandong Jia, Yuqing Lin, Shengyao Wang, Hideto Matsuyama
Summary: This study developed chemically converted graphene using a one-step method to achieve more stable and functional nanochannels, which can exclude approximately 90% of NaCl solutes from water in a pressure-driven filtration process.
Review
Engineering, Environmental
Mainak Mukherjee, Sanjukta Roy, Krishanu Bhowmick, Swachchha Majumdar, Indah Prihatiningtyas, Bart Van der Bruggen, Priyanka Mondal
Summary: As urbanization, industrialization, and population growth continue, water scarcity becomes more severe. Pervaporation (PV) desalination, a promising technology, can alleviate the crisis of global drinking water supply. This review provides a comprehensive assessment of PV desalination membrane materials, transport phenomena, and the advantages of crosslinking during membrane preparation.
PROCESS SAFETY AND ENVIRONMENTAL PROTECTION
(2022)
Article
Engineering, Chemical
Giuseppe Genduso, Anton Missinne, Zain Ali, Wojciech Ogieglo, Bart Van der Bruggen, Ingo Pinnau
Summary: The study investigated the pervaporative desalination of synthetic seawater and brines using a PDMS thin-film composite membrane, demonstrating high water permeance and exceptional NaCl rejection. The PDMS composite membrane showed outstanding pure water flux even at high temperatures and with salt presence in the feed water, performing among the best compared with hydrophilic TFC polymer membranes reported previously.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Engineering, Environmental
Shania Sharif, Khuram Shahzad Ahmad, Faisal Rehman, Zubeda Bhatti, Khalid Hussain Thebo
Summary: Membrane-based technology has gained significant interest for its potential applications in water purification and desalination, with two-dimensional graphene oxide (GO) and its derivatives being considered the most suitable material for membrane technology due to their exceptional properties. Challenges and future directions for such membranes will be discussed in detail.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Engineering, Chemical
Dian Zhang, Masakoto Kanezashi, Toshinori Tsuru, Kazuki Yamamoto, Takahiro Gunji, Yohei Adachi, Joji Ohshita
Summary: Epoxy-based reverse osmosis membranes with an organically bridged polysilsesquioxane skeleton were prepared by a sol-gel process. The use of epoxy-containing monomer significantly improved the membrane performance and stability.
JOURNAL OF MEMBRANE SCIENCE
(2022)
Article
Nanoscience & Nanotechnology
Prexa Shah, Youmin Hou, Hans-Juergen Butt, Michael Kappl
Summary: Membrane distillation (MD) is an important technique for brine desalination and wastewater treatment. Researchers have found that depositing a layer of polysiloxane nanofilaments on microporous membranes can increase the distillation rate and reduce membrane wetting and fouling. Compared to conventional hydrophobic membranes, these multiscale porous membranes exhibit superior fouling resistance and achieve higher distillation flux without the use of fluorinated compounds.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Polymer Science
Targol Hashemi, Mohammad Reza Mehrnia, Aydin Marandi, Ahmad Fauzi Ismail
Summary: Novel mixed matrix membranes were prepared using magnetic casting and nanocomposite technology, resulting in increased water flux and improved anti-fouling properties.
JOURNAL OF APPLIED POLYMER SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Yanuardi Raharjo, Ahmad Fauzi Ismail, Mohd Hafiz Dzarfan Othman, Mochamad Zakki Fahmi, Saiful, Djoko Santoso, Mochamad Ifan Nugroho, Diana Merna, Maipha Deapati Arief, Risma Chikita Pratama
Summary: This study aimed to develop a novel imprinted zeolite (IZC) and incorporate it into a polyethersulfone (PES) and poly(vinyl pyrrolidone) (PVP) mixed matrix membrane (HF-MMM) for hemodialysis treatment. The optimized parameters showed that this membrane has the potential to effectively remove uremic toxins.
Review
Chemistry, Multidisciplinary
Pei Sean Goh, Zahra Samavati, Ahmad Fauzi Ismail, Be Cheer Ng, Mohd Sohaimi Abdullah, Nidal Hilal
Summary: Membrane technology has gained popularity in industries for separation processes, desalination, and wastewater treatment. The development of nanocomposite membranes that merge nanotechnology and membrane technology has become a rapidly growing research area, motivated by the need for high-performance liquid separation membranes. The unique morphology and topology of nanostructured materials, such as TiO2, have attracted attention due to their hydrophilicity, antibacterial, and photocatalytic properties. This review provides an overview of the modifications of liquid separation membranes using TiO2 as an example of multidimensional nanomaterials, discussing their performance and advantages.
Review
Biochemistry & Molecular Biology
Raed A. Al-Juboori, Muayad Al-Shaeli, Saif Al Aani, Daniel Johnson, Nidal Hilal
Summary: The concerns of exceeding planetary limits on reactive nitrogen levels are well-documented. A significant amount of anthropogenic nitrogen is released in wastewater. Nitrogen removal in wastewater treatment consumes substantial energy, making nitrogen recovery an attractive solution to save energy and meet regulatory discharge limits. Membrane technologies play a crucial role in effective nitrogen recovery systems.
Article
Environmental Sciences
Noresah Said, Woei Jye Lau, Muhammad Nidzhom Zainol Abidin, Amir Mansourizadeh, Ahmad Fauzi Ismail
Summary: In this study, poly(citric acid)-grafted graphene oxide (PGO) was incorporated into single-layer hollow fiber (SLHF) and dual-layer hollow fiber (DLHF) membranes to improve their antifouling properties during water treatment. The optimized PGO loading of 0.7 wt% in SLHF membrane resulted in higher water permeability and bovine serum albumin rejection compared to the neat membrane. Similarly, introducing 0.7 wt% PGO only to the outer layer of DLHF membrane improved its antifouling properties and increased the rejection rate of bovine serum albumin to 97.7%.
ENVIRONMENTAL TECHNOLOGY
(2023)
Article
Chemistry, Multidisciplinary
A. Sumisha, G. Arthanareeswaran, A. F. Ismail
Summary: This study mainly focuses on the analysis of casein protein transport characteristics through ultrafiltration membranes. Polysulfone-based polymer membranes modified with different materials are used. The experimental results show that the transport of casein is controlled by convection.
SEPARATION SCIENCE AND TECHNOLOGY
(2023)
Review
Environmental Sciences
Farah Ahmed, Daniel Johnson, Raed Hashaikeh, Nidal Hilal
Summary: While the water industry has made significant technological strides, it still lags behind other sectors in adopting innovative techniques. Factors such as the long lifetimes and costs of existing water infrastructure, risk aversion due to public health concerns, and limited financing hinder innovation. Regulations and the involvement of environmental, social, and political actors can play a role in accelerating innovation in the water sector.
Article
Engineering, Chemical
Lijo Francis, Nidal Hilal
Summary: In this study, an electrohydrodynamic atomization or electrospraying technique was used to deposit carbon nanotubes (CNT) on a commercially available PTFE membrane for Membrane Distillation (MD) process. The modified PTFE-CNT membrane showed improved water contact angle, liquid entry pressure (LEP), and pore size distribution compared to the PTFE membrane. The functional PTFE-CNT membrane demonstrated superior desalination performance with less cake layer formation and high rejection of inorganic salts during continuous MD process operation.
Review
Biochemistry & Molecular Biology
Muzamil Khatri, Lijo Francis, Nidal Hilal
Summary: Obtaining fresh drinking water is a challenge due to changes in agricultural, industrial, and societal demands. This review focuses on the use of electrospun nanofiber-based membranes (ENMs) for improved water reclamation through physical and chemical modifications. The integration of nanomaterials in ENMs shows promise for membrane distillation (MD) processes, enhancing their efficiency and performance. However, further improvements are needed to achieve efficient membranes with enhanced water flux, anti-fouling, and anti-scaling characteristics.
Article
Engineering, Chemical
Komathi Kannathasan, Juhana Jaafar, Nuor Sariyan Suhaimin, Nurul Natasha Mohammad Jafri, Sadaki Samitsu, N. H. Alias, A. F. Ismail, T. Matsuura, M. H. D. Othman, Mukhlis A. Rahman, Farhana Aziz, Norhaniza Yusof, Mohammed Rasool Qtaishat, M. I. Ismail
Summary: A novel method of fabricating translucent photocatalytic membrane using a modified morphological structure as a photocatalyst has been developed. The study highlights the effect of translucency on the efficiency of photocatalytic reactions.
CHEMICAL ENGINEERING RESEARCH & DESIGN
(2023)
Article
Engineering, Environmental
Nor Akalili Ahmad, Lih Jang Tam, Pei Sean Goh, Nurfirzanah Azman, Ahmad Fauzi Ismail, Khairulnadzmi Jamaluddin, Gangasalam Arthanareeswaran
Summary: In this study, a thin film composite (TFC) reverse osmosis (RO) membrane with high long-term stability and antifouling properties was developed by spray coating the polyamide (PA) layer with oppositely charged titania nanosheets (TNS). The manufactured membranes showed improved permeability and radionuclide rejection, making them suitable for treating radionuclide-containing wastewater. The findings highlight the potential of tailored TFC RO membranes in the treatment of radioactive wastewater.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Article
Multidisciplinary Sciences
Noor Fauziyah Ishak, Nur Hidayati Othman, Najihah Jamil, Nur Hashimah Alias, Fauziah Marpani, Munawar Zaman Shahruddin, Lau Woei Jye, Ahmad Fauzi Ismail
Summary: Modifying polymeric membranes using ZIF-8 functionalized-2D nanofillers showed improved gas permeability and selectivity performance. The rGO/ZIF-8 and MoS2/ZIF-8 nanofillers were successfully synthesized and characterized. Addition of 10 wt% of each nanofiller to the PES solution resulted in MMMs with enhanced thermal stability. Compatibility between the 2D nanofillers and PES matrix was confirmed by FTIR and XRD analysis. The obtained MMMs exhibited significantly improved gas separation properties, demonstrating the potential of using 2D nanofillers for high-performance membranes.
PERTANIKA JOURNAL OF SCIENCE AND TECHNOLOGY
(2023)
Article
Engineering, Environmental
Nurul Syazana Fuzil, Nur Hidayati Othman, Nur Hashimah Alias, Fauziah Marpani, Muhammad Shafiq Mat Shayuti, Munawar Zaman Shahruddin, Mohd Rizuan Mohd Razlan, Norazah Abd Rahman, Woei Jye Lau, Mohd Hafiz Dzarfan Othman, Ahmad Fauzi Ismail, Tutuk Djoko Kusworo, Anwar Ul-Hamid
Summary: In this study, the performance of membrane distillation (MD) was improved by coating MoS2-TiO2 on a PVDF-based hollow fiber membrane. The MoS2-TiO2/PP20 membrane showed enhanced hydrophobicity and porosity, leading to significantly improved MD performances. This work suggests that the MoS2-TiO2 coating can overcome the typical permeability/rejection rate trade-off effect and play a significant role in enhancing MD performances.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Review
Engineering, Environmental
Nur Fajrina, Norhaniza Yusof, Ahmad Fauzi Ismail, Farhana Aziz, Muhammad Roil Bilad, Meshel Alkahtani
Summary: This article summarizes recent developments in membrane technology tailored for biogas upgrading, including the structure and classification of membrane materials as well as effective approaches to overcome the trade-off between permeability and selectivity. Additionally, other challenges are comprehensively discussed, and future research required to tackle biogas upgrading issues is projected.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Article
Engineering, Chemical
Arvin Sohrabi, Mousa Meratizaman, Shuli Liu
Summary: This paper simulates and discusses possible solutions to improve the economic and technical performances of a battery-less renewable energy-powered BWRO system under real climate conditions. The study finds that the photovoltaic-based system performs better in terms of specific energy consumption and unused energy ratio.
Article
Engineering, Chemical
Chunlan Pan, Xiaoyin Hu, Vishal Goyal, Theyab R. Alsenani, Salem Alkhalaf, Tamim Alkhalifah, Fahad Alturise, Hamad Almujibah, H. Elhosiny Ali
Summary: This paper introduces a novel waste heat recovery method using the hot flue gas from a ship's engine to produce liquefied hydrogen while meeting the ship's air-conditioning requirement. A comprehensive feasibility assessment is conducted and an artificial neural network with a multiobjective grey wolf optimization method is used for optimization. The findings indicate the highest mean sensitivity index of the flash temperature and the best optimization scenario for exergy efficiency, CO2 emission reduction, and liquefied hydrogen cost.
Article
Engineering, Chemical
Daniele Chinello, Jan Post, Louis C. P. M. de Smet
Summary: In this study, PVDF-based anion-exchange membranes were designed to selectively separate nitrate from chloride. Experimental data showed that increasing the concentration of PVDF enhanced nitrate transport but also increased the membrane electrical resistance. The selectivity of nitrate was found to be independent of the membrane thickness and mainly driven by the increased affinity between the anion and the membrane.
Article
Engineering, Chemical
Umar Noor, Muhammad Fayyaz Farid, Ammara Sharif, Amna Saleem, Zubair Nabi, Muhammad Furqan Mughal, Kiran Abbas, Toheed Ahmed
Summary: Global water scarcity is increasing, and water desalination is an important solution. Multifunctional advanced materials, such as membrane materials and solar-driven desalination, play a crucial role in water desalination. Additionally, these materials can be used for water purification, wastewater treatment, and pollutant elimination.
Article
Engineering, Chemical
Emrah Gumus
Summary: With growing global concerns about climate change and environmental impacts, the use of nuclear energy in naval vessels offers a cleaner and more efficient solution to reduce emissions and address water and energy supply challenges. This study explores a novel system that combines a nuclear-driven supercritical carbon dioxide power cycle with reverse osmosis cogeneration to meet the water and electricity demands in maritime operations, enhancing the sustainability, efficiency, and self-sufficiency of naval vessels. The results indicate that the system has the potential to be a viable and effective solution for naval operations.
Article
Engineering, Chemical
Dao Thi Thanh Huyen, Saikat Sinha Ray, Young -Nam Kwon
Summary: This study focuses on the modification of a commercially available polyamide thin-film composite membrane with a zwitterionic material to enhance its fouling resistance. The modified membrane shows improved salt rejection and reduced permeability compared to the pristine membrane. Fouling tests demonstrate that the modified membrane has a lower fouling ratio and higher recovery ratio. The enhanced antifouling characteristics are attributed to the improved hydrophilicity resulting from the zwitterionic brushes and the salting-in effect.
Article
Engineering, Chemical
Niklas Koeller, Lukas Mankertz, Selina Finger, Christian J. Linnartz, Matthias Wessling
Summary: This study presents a methodology to scale up Flow-electrode Capacitive Deionization (FCDI) technology from lab-scale to pilot-scale systems. By increasing membrane area and using a stacking approach, the FCDI modules were successfully scaled up and achieved a salt transfer rate comparable to lab-scale systems. This provides a foundation for future assessments of energy demand and economics.
Article
Engineering, Chemical
Mona Gulied, Sifani Zavahir, Tasneem Elmakki, Hyunwoong Park, Guillermo Hijos Gago, Ho Kyong Shon, Dong Suk Han
Summary: This study introduces a novel hybrid system that combines direct contact membrane distillation (DCMD) and electrically switched ion exchange (ESIX) to facilitate seawater reverse osmosis (SWRO) brine enrichment and selective lithium recovery.
Article
Engineering, Chemical
Zhiqiang Zhang, Ruifeng Deng, Jiao Zhang, Lu She, Guangfeng Wei, Renyong Jia, Pengyu Xiang, Siqing Xia
Summary: A transmembrane electro-chemisorption system with authigenic acid and base was developed for enhancing ammonia recovery from strong ammonia wastewater. The system efficiently transformed ammonium into free ammonia, which was then adsorbed and recovered through transmembrane chemisorption. This system yielded pure (NH4)2SO4 product and produced valuable byproducts of pure hydrogen and oxygen. Higher applied voltage resulted in better ammonia recovery.
Article
Engineering, Chemical
Alena Popova, Sandrine Boivin, Takuji Shintani, Takahiro Fujioka
Summary: This study aimed to produce a high-integrity RO membrane by forming a polyamide skin layer on a TE support layer, in order to enhance the integrity of the membrane and improve the microbiological safety of potable water reuse.
Article
Engineering, Chemical
Sanjana Yagnambhatt, Saber Khanmohammadi, Jonathan Maisonneuve
Summary: This study investigates the concept of using heat to enhance reverse osmosis (RO) desalination. The effect of temperature on water permeate flux, specific energy, permeate quality, and applied operating pressures is evaluated using an analytical model. The results suggest that under specific conditions, the tradeoff between savings in mechanical pump work and thermal energy input in thermally-enhanced RO can be favorable, leading to overall energy savings.
Article
Engineering, Chemical
Jiangju Si, Chenrui Xue, Shun Li, Linchao Yang, Weiwei Li, Jie Yang, Jihong Lan, Ningbo Sun
Summary: To meet the huge demand for lithium resources, there is an urgent need to develop a new efficient technology for lithium recovery from salt-lake brines. In this study, a selective membrane capacitive deionization system is reported, which achieves high lithium recovery capacity and rate through the use of materials with efficient intercalated pseudo-capacitance and a high specific area porous carbon. The use of a modified thin-coated membrane allows for selective Li+ recovery, and adjusting the concentrations of Li+ and Mg2+ in the feed solution enables higher Li+/Mg2+ selectivity.
Article
Engineering, Chemical
Mohamed R. Salem, R. Y. Sakr, Ghazy M. R. Assassa, Omar A. Aly
Summary: This research proposes a new method of using wasted thermal energies as an additional heating source for solar still distillation units (SSDUs) to increase productivity and reduce pollution and global warming. By testing two SSDUs, the study shows that heating airflow can raise temperatures, enhance freshwater production, and improve system thermal efficiency.
Article
Engineering, Chemical
Qimeng Sun, Miao Sun, Linyan Yang, Yuan Gao, Xinghai Zhou, Lihua Lyu, Chunyan Wei
Summary: This study presents an innovative design and fabrication of a fabric-based conical roll (FCR) evaporator, which enables low-temperature evaporation and achieves high evaporation efficiency with excellent thermal management ability. The evaporator has demonstrated advanced light-harvesting capability and can produce freshwater that meets drinking water standards, showing great potential for applications in desalination and sewage treatment.
Article
Engineering, Chemical
Yidong Zhang, Wangfang Deng, Meiyan Wu, Chao Liu, Guang Yu, Qiu Cui, Pedram Fatehi, Chunlin Xu, Bin Li
Summary: In this study, a novel polydopamine-functionalized lignin-containing pulp foam evaporator with high-efficiency desalination and multi-contaminant adsorption capabilities was designed. The foam evaporator showed excellent light absorption, water absorption, thermal conductivity, and chelation abilities, allowing for solar evaporation and contaminant adsorption synergistically. It also exhibited potential applications in metal ion concentration and contaminated seawater treatments, and demonstrated superior biodegradability compared to poly-styrene foam. This foam material holds promise for developing multifunctional photo-thermal systems for solar-driven water purification.