4.7 Article

Si3N4-BN-SiCN ceramics with unique hetero-interfaces for enhancing microwave absorption properties

期刊

CERAMICS INTERNATIONAL
卷 47, 期 9, 页码 12261-12268

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2021.01.075

关键词

Microstructure; Dielectric properties; Microwave absorption properties

资金

  1. National Natural Science Foundation of China [51902257, 51802263]
  2. China Postdoctoral Science Foundation [2019M653732]

向作者/读者索取更多资源

SiCN-based ceramics with broadband and strong microwave absorption properties exhibit outstanding electromagnetic wave absorption performance through the unique hetero-interface of Si3N4-BN, Si3N4-SiCN, and BN-SiCN in the ceramics synthesized using the CVI method. This leads to an effective absorption bandwidth covering the entire X-band.
SiCN-based ceramics with broadband and strong microwave absorption properties are desired for the structural and functional integration of ceramic matrix composites. The elemental composition and thermal expansion coefficients of the ceramics matrix crucially affect its microstructure and electromagnetic wave (EMW) absorption properties. BN layer with lower electrical conductivity and higher specific area, exhibits both the impedance matching characteristic and EMW attenuation in the process of multiple reflections, electrical conductivity loss, dipole polarization and interfacial polarization. Therefore, Si3N4-BN-SiCN ceramics, which were synthesized using chemical vapor infiltration (CVI) method, construct unique hetero-interface of Si3N4-BN, Si3N4?SiCN and BN-SiCN. Therefore, the Si3N4-BN-SiCN ceramics have outstanding EMW absorption performance and realize an effective absorption bandwidth (EAB) that covers the whole X band and the minimum reflection coefficient (RC) reaches -18.43 dB at a thickness of 3.37 mm.

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