Consolidation of cellulose nanofibrils with lignosulphonate bio-waste into excellent flame retardant and UV blocking membranes

The use of biomass to produce value-adding materials is a core objective of the circular economy, which has attracted great research interest in recent decades. In this context, we present here a simple dispersion-casting process for consolidation of cellulose nanofibrils (CNF), lignosulphonate (LS)-rich bio-waste and CaCl2 in composite membranes. The addition of CaCl2 to CNF and LS dispersions reduces the potential, due to an electrostatic screening, which promotes the aggregation of CNF, increases its moisture content and promotes LS deposition on CNFs already in the dispersion phase. Addition of both the LS and CaCl2 to CNF dispersion has an adverse effect on the mechanical properties of the final membranes. The effectiveness of the new composite membranes has been described in terms of their passive (charring) flame retardancy and 100 % UVA/UVB shielding capacity, both identified for membranes with the highest LS content, as well as high electronic resistance.

Automated summary

The study presents a simple dispersion-casting process for consolidation of cellulose nanofibrils, lignosulphonate-rich bio-waste and CaCl2 in composite membranes. The addition of CaCl2 to CNF and LS dispersions leads to aggregation of CNF and deposition of LS, affecting the mechanical properties of the final membranes. The new composite membranes show effective passive flame retardancy, UV shielding capacity, and high electronic resistance.