期刊
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY
卷 71, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.calphad.2020.102195
关键词
Submerged arc welding; TiO2-Bearing flux; Basic-fluoride flux
类别
资金
- National Natural Science Foundation of China [51622401, 51861130361, 51861145312, 51850410522]
- Newton Advanced Fellowship by the Royal Society [RP12G0414]
- Research Fund for Central Universities [N172502004]
- Xingliao Talents Program [XLYC1807024, XLYC1802024]
- Liaoning Key Industrial Program [2019JH1/10100014]
- Innovation Team of Northeastern University
- Global Talents Recruitment Program by the Chinese government
- National Research Foundation of South Africa [BRICS171211293679]
Gas-slag-metal equilibrium calculations are performed to investigate the transfer of Ti and O to submerged arc welded metals with increasing TiO2 addition in basic-fluoride fluxes. The results indicate that activities of TiO2 and Ti2O3 considering slag-metal reactions alone do not account for Ti transfer behaviors since TiF3 gas tends to form and reduce Ti-oxide activities. Thermodynamic simulation indicates that consideration of gases is essential to improve the prediction accuracy of Ti and O concentrations.
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