4.7 Article

A four-fold interpenetrated metal-organic framework as a fluorescent sensor for volatile organic compounds

期刊

DALTON TRANSACTIONS
卷 45, 期 38, 页码 14888-14892

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6dt02169g

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资金

  1. National Natural Science Foundation of China [51522303]
  2. National Key Basic Research Program of China [2015CB856500]
  3. open project of the State key laboratory of supramolecular structures and materials, Jilin University [SKLSSM201606]
  4. Tianjin Municipal Science and Technology Commission Grant [15JCYBJC53000]
  5. Thousand Youth Talents Plan
  6. MOE Innovation Team of China [IRT13022]

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A four-fold interpenetrated three dimensional (3D) metal-organic framework, [Cd-2(tppe)(bpdc)(2)(H2O)]center dot solvent (1), was synthesized with a tetraphenylethene (TPE)-based ligand, 1,1,2,2-tetrakis(4-(pyridin-4-yl) phenyl) ethene (TPPE). This complex exhibits intense blue luminescence and is sensitive to toxic volatile organic compounds (VOCs).

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