期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 278, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.apcatb.2020.119284
关键词
Dual zerovalent nonmetal doping; Nickel phosphide; Hydrogen evolution reaction; pH universal; Adsorption free energy
资金
- National Natural Science Foundation of China [51671094, 21803031]
- Shandong Provincial Natural Science Foundation [ZR2019BEM007]
- Shandong postdoctoral innova talents support plan
- UJN
- Natural Science Foundation of the Jiangsu Higher Education Institution of China [18KJB150022]
The large-scale implementation of hydrogen by electrochemical water splitting demands highly active, durable and inexpensive platinum-free catalysts. Nevertheless, developing efficient non-noble metal based hydrogen evolution reaction (HER) electrocatalysts that can work in all pH solutions still remains as a huge uphill. Herein, we report dual zerovalent nonmetal (N and B) doped Ni2P nanoparticles hybridized with N, B-graphene (N, B-Ni2P/G) could function as electrocatalyst for hydrogen evolution in all pHs with high activity and stability. In-situ phosphidation of a 2D/2D heterojunction of Ni-B-i nanosheets/graphene (Ni-B-i NS/G) under ammonia atmosphere results in a strongly couple N, B-Ni2P/G hybrid electrocatalyst with (i) the enhanced intrinsic catalytic activity from dual zerovalent doped Ni2P structure, (ii) 0D architectures with a high surface area exposure yield, and (iii) the enhanced charge transport ability by N, B-graphene support. As a result, the designed N, B-Ni2P/G exhibits superior electrocatalytic HER performance and remarkable stability at all pH ranges. Our protocol may open up new ways to design progressive electrocatalysts for energy-related applications.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据