期刊
DALTON TRANSACTIONS
卷 45, 期 17, 页码 7312-7319出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6dt00252h
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资金
- Agency for Science, Technology and Research (A*Star) of Singapore [R-143-000-566-305]
Cyclopentadienyl (Cp) Ni(II) complexes [CpNiL][PF6] containing hybrid N,C chelating benzothiazolyl NHC ligands (L-1 = 1-(2-benzothiazolyl)-3-methylimidazol-2-ylidene, 3a; L-2 = 1-(2-benzothiazolyl)-3-allylimidazol-2-ylidene, 3b; L-3 = 1-(2-benzothiazolyl)-3-benzylimidazol-2-ylidene, 3c) have been synthesized and fully characterized. The catalytic activity of 3a-3c in some C-C bond formation reactions has been examined. They are efficient catalysts for the homo-coupling of benzyl bromide in the presence of MeMgCl at r.t. with good functional group tolerance. Complex 3a is active in the catalytic oxidative homo-coupling of Grignard reagents with 1,2-dichloroethane as an oxidant at r.t.
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