An Iminophosphonamido‐Chlorosilylene as a Strong σ‐Donating NHSi Ligand: Synthesis and Coordination Chemistry

Facile Access to Dative, Single and Double Silicon–Metal Bonds Through M–Cl Insertion Reactions of Base‐stabilized Si(II) cations

(2020) Shigeyoshi Inoue et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of a Stable N‐Hetero ‐ Rh I ‐Metallacyclic Silanone

(2020) Shintaro Takahashi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Stable N-Hetero-Rh-Metallacyclic Silylene

(2019) Tsuyoshi Kato et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An H‐Substituted Rhodium Silylene

(2019) Connor S. MacNeil et al.   CHEMISTRY-A EUROPEAN JOURNAL

An isolable β-diketiminato chlorosilylene

(2018) Yun Xiong et al.   DALTON TRANSACTIONS

A β-Diketiminate-Stabilized Sila-Acyl Chloride: Systematic Access to Base-Stabilized Silicon Analogues of Classical Carbonyl Compounds

(2018) Dinh Cao Huan Do et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chelate Silylene-Silyl Ligand Can Boost Rhodium-Catalyzed C−H Bond Functionalization Reactions

(2018) Zhenbo Mo et al.   CHEMISTRY-A EUROPEAN JOURNAL

Isolable Silylene Ligands Can Boost Efficiencies and Selectivities in Metal-Mediated Catalysis

(2018) Yu-Peng Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Improving the Catalytic Activity in the Rhodium-Mediated Hydroformylation of Styrene by a Bis(N-heterocyclic silylene) Ligand

(2017) Marcel Schmidt et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

N-heterocyclic silylenes as powerful steering ligands in catalysis

(2017) Saeed Raoufmoghaddam et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Divalent Silicon-Assisted Activation of Dihydrogen in a Bis(N-heterocyclic silylene)xanthene Nickel(0) Complex for Efficient Catalytic Hydrogenation of Olefins

(2017) Yuwen Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Bis(silylene)-Substituted ortho -Carborane as a Superior Ligand in the Nickel-Catalyzed Amination of Arenes

(2016) Yu-Peng Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reactivity of an NHC-Stabilized Silylene towards Lewis Acids and Lewis Bases

(2016) Haiyan Cui et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Silacyclopropylideneplatinum(0) Complex as a Robust and Efficient Hydrosilylation Catalyst

(2016) Thibault Troadec et al.   INORGANIC CHEMISTRY

The transition-metal chemistry of amidinatosilylenes, -germylenes and -stannylenes

(2015) Lucía Álvarez-Rodríguez et al.   COORDINATION CHEMISTRY REVIEWS

Amidinate-Stabilized Group 9 Metal–Silicon(I) Dimer and −Silylene Complexes

(2015) Sabrina Khoo et al.   INORGANIC CHEMISTRY

Can low-valent silicon compounds be better transition metal ligands than phosphines and NHCs?

(2015) Zsolt Benedek et al.   RSC Advances

An overview of N-heterocyclic carbenes

(2014) Matthew N. Hopkinson et al.   NATURE

Synthesis and Reactivity of Three-Coordinate (dtbpe)Rh Silylamides: CO2 Bond Cleavage by a Rhodium(I) Disilylamide

(2014) Matthew T. Whited et al.   ORGANOMETALLICS

A Base-Stabilized Silyliumylidene Cation as a Ligand for Rhodium and Tungsten Complexes

(2014) Hui-Xian Yeong et al.   ORGANOMETALLICS

N-Heterocyclic Silylene (NHSi) Rhodium and Iridium Complexes: Synthesis, Structure, Reactivity, and Catalytic Ability

(2013) Miriam Stoelzel et al.   AUSTRALIAN JOURNAL OF CHEMISTRY

From Bis(silylene) and Bis(germylene) Pincer-Type Nickel(II) Complexes to Isolable Intermediates of the Nickel-Catalyzed Sonogashira Cross-Coupling Reaction

(2013) Daniel Gallego et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Osmium–Silicon Triple Bond: Synthesis, Characterization, and Reactivity of an Osmium Silylyne Complex

(2013) Paul G. Hayes et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Investigations of the Rhodium Catalyzed Propargylic CH Activation

(2013) Urs Gellrich et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pushing the σ-Donor Strength in Iridium Pincer Complexes: Bis(silylene) and Bis(germylene) Ligands Are Stronger Donors than Bis(phosphorus(III)) Ligands

(2012) Andreas Brück et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silylation of N-heterocyclic carbene with aminochlorosilane and -disilane: dehydrohalogenation vs. Si–Si bond cleavage

(2011) Haiyan Cui et al.   DALTON TRANSACTIONS

Syntheses of Group 7 Metal Carbonyl Complexes with a Stable N-Heterocyclic Chlorosilylene

(2011) Ramachandran Azhakar et al.   INORGANIC CHEMISTRY

A Brief Survey of Our Contribution to Stable Carbene Chemistry

(2011) David Martin et al.   ORGANOMETALLICS

Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes

(2010) Mohand Melaimi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Structure of a Base-Stabilized C-Phosphino-Si-Amino Silyne

(2010) David Gau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stable N-Heterocyclic Carbene Adducts of Arylchlorosilylenes and Their Germanium Homologues

(2010) Alexander C. Filippou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Lewis Base Stabilized Dichlorosilylene

(2009) Rajendra S. Ghadwal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION