Article
Chemistry, Physical
Maoxin Li, Feier Fang, Xiao Huang, Guangyou Liu, Zheng Lai, Zhihao Chen, Jiahao Hong, Yu Chen, Rong-jia Wei, Guo-Hong Ning, Kai Leng, Yumeng Shi, Bingbing Tian
Summary: Chiral molecules have an influence on the crystallization of organometal halide perovskites (OIHPs) and chiral OIHPs can be used in circularly polarized light detectors.
CHEMISTRY OF MATERIALS
(2022)
Article
Materials Science, Multidisciplinary
Yingjie Zhao, Meiqiu Dong, Jiangang Feng, Jinjin Zhao, Yangwu Guo, Yue Fu, Hanfei Gao, Junchuan Yang, Lei Jiang, Yuchen Wu
Summary: This study fabricated lead-free chiral 2D double perovskite single-crystalline microwire arrays with excellent environmental stability, realizing outstanding circularly polarized light photodetectors with high responsivity and detectivity.
ADVANCED OPTICAL MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Zhou Li, Chengmin Ji, Yipeng Fan, Tingting Zhu, Shihai You, Jianbo Wu, Ruiqing Li, Zeng-Kui Zhu, Panpan Yu, Xiaojun Kuang, Junhua Luo
Summary: This study combines chiroptical phenomena and the pyro-phototronic effect in chiral-polar perovskites to achieve unprecedented pyroelectric-based circularly polarized light (CPL) detection. Two novel lead-free chiral-polar double perovskites are successfully synthesized, showing substantially boosted photoresponse and excellent CPL detection capacity.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Materials Science, Multidisciplinary
Tingting Zhu, Hongchun Wu, Chengmin Ji, Xinyuan Zhang, Yu Peng, Yunpeng Yao, Huang Ye, Wen Weng, Wenxiong Lin, Junhua Luo
Summary: By transforming RP-type perovskites, chiral-polar photovoltaic ACI perovskites with remarkable CPPE have been developed, paving the way for self-powered short-wave ultraviolet CPL detection.
ADVANCED OPTICAL MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Dong Li, Wentao Wu, Shiguo Han, Xitao Liu, Yu Peng, Xiaoqi Li, Lina Li, Maochun Hong, Junhua Luo
Summary: By reducing the dimension of CH3NH3PbI3, a polar multilayered perovskite IMP with the narrowest bandgap of 1.71 eV was successfully obtained, leading to an extended self-powered photodetection range of 724 nm with a high on/off ratio and photodetectivity. This innovative research provides a foundation for adjusting the physical properties of hybrid perovskites and expanding their potential for self-powered broad-spectrum detection.
Article
Chemistry, Multidisciplinary
Bing Yao, Qi Wei, Yunqing Yang, Wenjia Zhou, Xianyuan Jiang, Hao Wang, Mingyu Ma, Danni Yu, Yingguo Yang, Zhijun Ning
Summary: Symmetry-broken-induced spin splitting is crucial for selective circularly polarized light absorption and spin carrier transport. Asymmetrical chiral perovskite is emerging as the most promising material for direct semiconductor-based circularly polarized light detection. However, increasing the asymmetry factor and extending the response region remain challenging.
Article
Nanoscience & Nanotechnology
Dong Li, Xiaoying Shang, Wentao Wu, Xiaoqi Li, Zhijin Xu, Lina Li, Maochun Hong, Xueyuan Chen, Junhua Luo
Summary: In this work, a polar multilayered perovskite material with a distinctive two-photon activity is constructed, enabling self-powered visible-infrared dual-modal photodetection. This achievement is attributed to the polar feature and layered quantum-well structure of the material. The high-performance self-powered photodetection of visible and infrared light is realized through the bulk photovoltaic effect.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Multidisciplinary
Jose Mendoza-Carreno, Pau Molet, Clara Otero-Martinez, Maria Isabel Alonso, Lakshminarayana Polavarapu, Agustin Mihi
Summary: The versatile hybrid perovskite nanocrystals (NCs) have tunable bandgaps and high photoluminescence (PL) quantum yields, making them promising materials for optoelectronics. However, their crystalline chemical structure limits their chiroptical properties. This study introduces a scalable approach to produce chiral PL from 2D-chiral metasurfaces, using unmodified colloidal perovskite NC inks patterned by nanoimprinting lithography.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Biao Zhao, Xiaobin Gao, Kai Pan, Jianping Deng
Summary: Chiral perovskites with circularly polarized luminescence (CPL) performance have attracted significant attention. A convenient and universal strategy for constructing chiral helical polymer/perovskite hybrid nanofibers with outstanding CPL properties has been reported in this contribution. The prepared hybrid nanofibers exhibit good long-time stability in air and intense CPL emissions, with the emission color easily tunable by adjusting the precursors of perovskites, providing an efficient technique for various kinds of CPL-active perovskite nanomaterials for both scientific research and future practical applications.
Article
Chemistry, Multidisciplinary
Ruiqing Li, Zirui Wang, Tingting Zhu, Huang Ye, Jianbo Wu, Xitao Liu, Junhua Luo
Summary: Bulk photovoltage has been achieved by introducing stereochemically active lone pair perovskitizer to construct a polar tri-layered hybrid perovskite, leading to highly sensitive polarized photodetection in self-powered mode.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Multidisciplinary Sciences
Shangpu Liu, Mikael Kepenekian, Stanislav Bodnar, Sascha Feldmann, Markus W. Heindl, Natalie Fehn, Jonathan Zerhoch, Andrii Shcherbakov, Alexander Poethig, Yang Li, Ulrich W. Paetzold, Aras Kartouzian, Ian D. Sharp, Claudine Katan, Jacky Even, Felix Deschler
Summary: This study reveals the unique photoluminescence properties of hybrid perovskite semiconductor materials, which can achieve high luminescence yields and circularly polarized photoluminescence at room temperature. The excellent photoluminescence performance is attributed to the suppression of nonradiative loss channels and the high rates of radiative recombination. These findings pave the way for high-performance solution-processed photonic systems and chiral-spintronic logic at room temperature.
Article
Chemistry, Physical
Lutao Tao, Hongmei Zhan, Yanxiang Cheng, Chuanjiang Qin, Lixiang Wang
Summary: Hybrid organic-inorganic perovskites have potential in circularly polarized light source applications with chirality. Circularly polarized photoluminescence is important for investigating the chiroptical properties of perovskites. However, further research is needed for optimization. Chiral ligands can influence the electronic structure of perovskites, increasing asymmetry and emitting circularly polarized photons. Modifying with chiral amines leads to passivation of film defects, enhancing radiation recombination and emitting more circularly polarized photons. This approach offers the possibility of fabricating and refining circularly polarized light-emitting diodes.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2023)
Article
Chemistry, Multidisciplinary
Abhishek Maiti, Prof Amlan J. Pal
Summary: A pair of zero-dimensional lead-free chiral perovskites is introduced for the detection of circularly polarized light (CPL). Due to the intrinsic chirality, these perovskites exhibit chirality-induced spin-selectivity, making them suitable for CPL detection. Although the self-powered CPL detector shows a limited anisotropy factor, the factor increases under bias.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Multidisciplinary
Ming Li, Yumin Wang, Liangwei Yang, Zhifang Chai, Yaxing Wang, Shuao Wang
Summary: In this study, a new type of chiral scintillator that displays circularly polarized radioluminescence (CPRL) was discovered. These compounds exhibit high quantum yield and luminescence dissymmetric factors, as well as high X-ray absorption coefficients. The assembly of polarized scintillator crystals provides a new strategy to enhance X-ray imaging quality by controlling the radioluminescence propagation.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Nanoscience & Nanotechnology
Hongmei Zhu, Qingqian Wang, Kun Sun, Wei Chen, Jun Tang, Junjie Hao, Zhaojin Wang, Jiayun Sun, Wallace C. H. Choy, Peter Muller-Buschbaum, Xiao Wei Sun, Dan Wu, Kai Wang
Summary: The chirality of 2D chiral perovskite films has been significantly enhanced by a solvent modulation strategy, leading to the formation of CPL-active materials. By creating chiral perovskite/quantum dot composites, an increase in the CPL intensity was observed, attributed to the generation and transportation of spin-polarized charge carriers as well as the enlarged lattice distortion of the chiral perovskite films achieved through solvent modulation. This approach provides an effective way to construct CPL-active materials.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Review
Chemistry, Physical
Weiqi Huang, Sangen Zhao, Junhua Luo
Summary: This article introduces the research progress of deep-UV non-linear optical (NLO) materials, including the properties and structure relationship of p-conjugated and non-pi-conjugated deep-UV NLO crystals, as well as new functional groups. It is found that non-pi-conjugated deep-UV NLO materials are divided into six categories, which are important for balancing performance.
CHEMISTRY OF MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Yi Liu, Xiong Pan, Xitao Liu, Shiguo Han, Jiaqi Wang, Lei Lu, Haojie Xu, Zhihua Sun, Junhua Luo
Summary: The authors developed a series of 2D ferroelectric photonic materials by tailoring the interlayered spacers, showing remarkable ferroelectric-photopyroelectric-photovoltaic (FPP) effects. Among them, (n-hexylammonium)2CsPb2Br7 exhibited a giant contrast of 1500% for photopyroelectric current to photovoltaic signal, surpassing most inorganic oxide counterparts like BaTiO3 with 110%.
Article
Chemistry, Multidisciplinary
Huang Ye, Yu Peng, Xiaoying Shang, Lina Li, Yunpeng Yao, Xinyuan Zhang, Tingting Zhu, Xitao Liu, Xueyuan Chen, Junhua Luo
Summary: This study reports the successful realization of self-powered visible-infrared polarization photodetection using a newly developed layered hybrid ferroelectric material. The material exhibits fascinating ferroelectric characteristics and a giant two-photon absorption coefficient, and shows high sensitivity to the polarization of illuminated light.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Weiqi Huang, Xu Zhang, Yanqiang Li, Yang Zhou, Xin Chen, Xiaoqi Li, Fafa Wu, Maochun Hong, Junhua Luo, Sangen Zhao
Summary: This study reports a new type of organic-inorganic hybrid halide perovskite crystal with high birefringence. Compared to all commercial birefringent crystals, this crystal exhibits higher birefringence. Additionally, first-principles calculations reveal the underlying reasons for its birefringent performance.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Multidisciplinary
Qingran Ding, Xingyu Zhang, Zheshuai Lin, Zheyao Xiong, Yusong Wang, Xifa Long, Sangen Zhao, Maochun Hong, Junhua Luo
Summary: Hexagonal tungsten oxides (HTO) are an important family of compounds with various functional properties, but they lack transparency in the deep-UV spectral region, limiting their applications. This study reports the first HTO-type phosphate compound with deep-UV transparency, showcasing its potential in nonlinear optics.
SCIENCE CHINA-CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Minjuan Li, Xu Zhang, Zheyao Xiong, Yanqiang Li, Yang Zhou, Xin Chen, Yipeng Song, Maochun Hong, Junhua Luo, Sangen Zhao
Summary: This study reports a new polar crystal with an antiperovskite structure that exhibits a very strong nonlinear optical response and exceptionally large birefringence. The findings provide a new structural platform for the rational design of integrated optoelectronic materials with linear and second-order nonlinear optical responses.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Multidisciplinary
Tingting Zhu, Kun Zhang, Chengmin Ji, Xinyuan Zhang, Huang Ye, Yuanchen Zou, Junhua Luo
Summary: Multilayered chiral hybrid perovskites, designed through pairing achiral and chiral compounds in the interlayer space, exhibit high sensitivity for circularly polarized light (CPL) detection.
Article
Materials Science, Multidisciplinary
Yu Peng, Xing Wang, Lina Li, Huang Ye, Shuang Yang, Hua Gui Yang, Junhua Luo, Yu Hou
Summary: Circularly polarized luminescence (CPL) has gained increasing attention due to its wide-ranging applications. This study reports moisture-resistant 1D hybrid perovskites with white-CPL, which exhibit excellent structural flexibility and optoelectronic properties. These materials hold great potential for multifunctional applications due to their moisture resistance.
ADVANCED OPTICAL MATERIALS
(2023)
Article
Chemistry, Inorganic & Nuclear
Kai Li, Huang Ye, Xiaoqi Li, Xinqiang Wang, Junhua Luo, Xitao Liu
Summary: Impressive progress has been made recently in the design of solid-state quadratic nonlinear optical (NLO) switches. A highly efficient hybrid halide NLO switching material has been developed using a rational design approach. The material exhibits highly efficient modulation of the quadratic NLO property and a high phase transition temperature.
INORGANIC CHEMISTRY FRONTIERS
(2023)
Article
Chemistry, Multidisciplinary
Shihai You, Panpan Yu, Jianbo Wu, Zeng-Kui Zhu, Qianwen Guan, Lina Li, Chengmin Ji, Xitao Liu, Junhua Luo
Summary: Researchers reported a 2D bilayered lead iodide hybrid perovskite, (2IPA)(2)FAPb(2)I(7), by alloying iodine-substituted short-chain cations into the 3D FAPbI(3). This material exhibits exceptional performance in detecting broadband weak lights and X-rays, with high responsivities, significant detectivities, and ultralow detection limits. Its outstanding attributes make it a promising candidate for next-generation optoelectronic devices.
Article
Chemistry, Multidisciplinary
Ruiqing Li, Zirui Wang, Tingting Zhu, Huang Ye, Jianbo Wu, Xitao Liu, Junhua Luo
Summary: Bulk photovoltage has been achieved by introducing stereochemically active lone pair perovskitizer to construct a polar tri-layered hybrid perovskite, leading to highly sensitive polarized photodetection in self-powered mode.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Multidisciplinary Sciences
Yanqiang Li, Qingchen Wu, Zheshuai Lin, Youchao Liu, Yang Zhou, Xin Chen, Minjuan Li, Maochun Hong, Junhua Luo, Sangen Zhao
Summary: This study successfully synthesized Cs3C6N9·H2O crystal with bi-functional optical responses and found that it exhibits excellent nonlinear optical and linear optical anisotropic responses, demonstrating its great potential as a bi-functional optical crystal.
FUNDAMENTAL RESEARCH
(2023)
Article
Chemistry, Multidisciplinary
Qianwen Guan, Huang Ye, Shihai You, Zeng-Kui Zhu, Hang Li, Xitao Liu, Junhua Luo
Summary: This study utilizes chirality to induce radiation photovoltaics in multilayered chiral OIHPs, achieving efficient self-driven X-ray detection with high sensitivity and low detection limit.
Article
Chemistry, Inorganic & Nuclear
Yaoguo Shen, Yingwu Zhou, Xiaoling Xue, Hualiang Yu, Sangen Zhao, Junhua Luo
Summary: In this study, a new crystal with a large birefringence was reported. The energy gap of the crystal exceeds the limit of organic materials due to the regulation of a SiF6 octahedron. This finding provides a method to enhance the band gap of organic materials.
INORGANIC CHEMISTRY FRONTIERS
(2022)
Article
Chemistry, Multidisciplinary
Zhang Fen, Li Xiaoqi, Han Shiguo, Wu Fafa, Liu Xitao, Sun Zhizhua, Luo Junhua
Summary: Low-dimensional semiconductors, especially two-dimensional halide perovskites, have shown great potential in optoelectronic applications due to their large structural anisotropy, unique quantum well effect, and excellent semiconductor properties. This work focuses on the development of low-dimensional halide perovskite ferroelectric crystals with excellent photoelectric response. Single crystals of ferroelectric (iPA)(2)EA(2)Pb(3)I(10) with dimensions up to 15 mm x 15 mm x 3 mm have been successfully grown. The fabricated photodetectors based on these crystals show excellent photoelectric features, surpassing most photodetectors based on intrinsic optical anisotropy of 2D materials. This work lays a foundation for further exploration of multifunctional halide perovskites and promotes their applications in highly polarized-sensitive photodetection.
ACTA CHIMICA SINICA
(2022)