期刊
DALTON TRANSACTIONS
卷 45, 期 18, 页码 7559-7562出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt05045f
关键词
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资金
- National Natural Science Foundation of China [21301156]
- Qianjiang talents project in Zhejiang province [ZC304015017]
To improve methane adsorption by pore structure optimization, we developed a new organic linker and used it to construct a NbO-type metal-organic framework ZJNU-53 that, after activation, exhibits exceptionally high methane storage and working capacities of 241 and 190 cm(3) (STP) cm(-3) at 298 K and 65 bar, respectively, if the packing loss is not considered, which are among the highest reported for MOF materials.
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