期刊
DALTON TRANSACTIONS
卷 45, 期 6, 页码 2390-2393出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt04528b
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资金
- University of Manchester
- EPSRC [EP/K039547/1, EP/L014416/1, EP/J002208/1]
- Nuclear FiRST DTC
- Engineering and Physical Sciences Research Council [EP/J002208/1, EP/K039547/1, 1225406, EP/L014416/1, EP/J002208/2] Funding Source: researchfish
- EPSRC [EP/J002208/2] Funding Source: UKRI
[Th(Cp '')(3)] (Cp '' = {C5H3(SiMe3)(2)-1,3}) activates P-4 to give [{Th-Cp '')(3)}(2)(mu-eta(1):eta(1)-P-4)] (1), which has an unprecedented cyclo-P-4 binding mode. DFT studies were performed on a model of 1 to probe the bonding in this system.
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