Article
Food Science & Technology
Yaolei Zhang, Mengmeng Li, Yuanxiao Liu, Erqi Guan, Ke Bian
Summary: This study investigated the degradation of AFB(1) by water-assisted microwave irradiation, showing that WMI effectively degrades AFB(1) following pseudo-first-order reaction kinetics. Six new main degradation products were identified, and a possible degradation pathway was proposed using ultra-high-performance liquid chromatography Q-Orbitrap mass spectrometry. The variety and quantity of AFB(1) degradation products and the degradation pathway were influenced by microwave heating conditions.
LWT-FOOD SCIENCE AND TECHNOLOGY
(2021)
Article
Engineering, Environmental
Sreeja S. S. Mole, D. S. Vijayan, M. Anand, M. Ajona, T. Jarin
Summary: In this study, Achromobacter denitrifacians was utilized for the degradation of para nitro-phenol in industrial wastewater. The optimal conditions for phenol removal were determined to be pH 7.5, temperature 35°C, supplemented glucose level of 0.25 g/L, supplemented peptone level of 0.25 g/L, and zinc ion concentration of 0.01 g/L. The native bacterial strain isolated from industrial effluent water played an important role in the bioremediation process of phenol.
WATER SCIENCE AND TECHNOLOGY
(2021)
Article
Environmental Sciences
Junzhi Zhang, Yisi Chen, Yu Liao, Qi Wang, Jianwei Yu
Summary: The study investigated the removal and oxidation kinetics of phenols and indoles in source water by NaClO and KMnO4. The results showed that both chemicals were effective in removing selected chemical odorants, with different kinetics constants and degradation mechanisms observed for each chemical. This study provides a basis for using NaClO and KMnO4 oxidation in treating drinking water to remove trace phenols and indoles.
Article
Nanoscience & Nanotechnology
Lulu Zhu, Baiyu Zhang, Qian Su, Runlu Liu, Jingyi Lin, Hua Wang, Shenmin Zhu, Yao Li
Summary: Introduction of oxygen vacancies can enhance the photocatalytic activity of BiVO4-based heterojunctions and promote the separation of charge carriers.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Engineering, Chemical
Masoud Moradi, Yasser Vasseghian, Alireza Khataee, Motahareh Harati, Hossein Arfaeinia
Summary: FeTiO3/GO nanocomposite was successfully synthesized and used for photocatalytic degradation of phenolic compounds in aqueous solutions. The nanocomposite exhibited high efficiency and stability under optimized conditions, showing promising potential for the removal of phenolic pollutants.
SEPARATION AND PURIFICATION TECHNOLOGY
(2021)
Article
Materials Science, Ceramics
Yunchao Zhao, Liujie Xu, Mingyi Guo, Zhou Li, Tiejun Wang, Zhaoning Xu, Jiahao Ye, Shizhong Wei
Summary: The addition of mineralizer triethanolamine significantly improves the nucleation rate and crystallization rate of nano-ZrO2, with a recommended concentration of at least 0.3 M. The Avrami equation accurately describes the crystallization process of nano-ZrO2 crystallites.
CERAMICS INTERNATIONAL
(2021)
Article
Materials Science, Ceramics
Yeqing Ling, Qiannan Li, Hewen Zheng, Mamdouh Omran, Lei Gao, Kangqiang Li, Guo Chen
Summary: This study investigated the effects of microwave power and sample quality on the microwave drying kinetics and characteristics of zirconia. The results showed that increasing the microwave power and decreasing the sample mass can accelerate the drying process of zirconia and increase its dispersibility. Additionally, microwave drying was found to be fast and efficient, penetrating the product directly and avoiding the disadvantage of slow evaporation caused by temperature gradients.
CERAMICS INTERNATIONAL
(2021)
Article
Engineering, Environmental
Meijie Cai, Shisheng Liu, Junjie Cai, Lei Zhao, Xiaohui Wei, Minjie Guo, Song Lin
Summary: A combination microwave-assisted hydrothermal and calcination method was used to produce serial mesoporous MgO@Carbon (MgO@C) hybrid nanocomposites, which showed high specific surface area and small grain sizes and demonstrated enhanced degradation effect on organophosphorus contaminants.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Biotechnology & Applied Microbiology
Joao Carlos Silva Conceicao, Tatiana Manzini Vieira, Antonio Eduardo Miller Crotti, Jeancarlo Pereira dos Anjos, Daniela Aparecida Chagas-Paula, Andre Alexandre Vieira, Eliane Oliveira Silva
Summary: The study demonstrates that Aspergillus brasiliensis can efficiently transform methyl p-coumarate into two new compounds, providing a potential bioremediation pathway for phenolic compounds. Through the use of analytical techniques such as gas chromatography coupled to mass spectrometry, this research is significant in advancing the understanding and potential applications of biological remediation of phenolic pollutants.
INTERNATIONAL BIODETERIORATION & BIODEGRADATION
(2021)
Article
Environmental Sciences
Amit Kumar Behera, Krushna Prasad Shadangi, Prakash Kumar Sarangi
Summary: This study compares the photocatalytic action of two nanocomposites (TiO2 and TiO2(Ag) doped) on the degradation of phenol from water. The results show that the Ag-doped TiO2 has higher absorbance in the visible range and better phenol degradation performance. Under certain conditions, the maximum phenol degradation rate can reach 98% with a significant decrease in phenol concentration.
ENVIRONMENTAL POLLUTION
(2022)
Article
Chemistry, Applied
Gabriele Grieco, Olivier Blacque
Summary: The reduction of several aromatic nitro compounds to amines using two novel catalytic systems under microwave irradiation showed higher TON and TOF compared to previous systems, but with a narrower reaction scope.
APPLIED ORGANOMETALLIC CHEMISTRY
(2022)
Article
Chemistry, Physical
Yunhe Li, Weibao Liu, Lezhuo Li, Siyuan Jiang, Xiuwen Cheng
Summary: In this study, a nickel ferrite (NiFe2O4) system was developed for purifying phenol solutions in water. The effects of various operating parameters on the system's performance were investigated, including the amount of NiFe2O4, dosage of potassium persulfate (PS), microwave (MW) power, initial pH value, and different natural water anions. The results showed that the system achieved an excellent phenol removal efficiency of 97.74% within 30 minutes. The presence of co-existing anions such as chloride (Cl-), nitrate (NO3-), dihydrogen phosphate (H2PO4-), and bicarbonate (HCO3-) inhibited phenol degradation, while humic acid (HA) facilitated it. Free radical quenching experiments confirmed that sulfate radical (SO4 center dot(-)) and hydroxyl radical (HO center dot) were the primary radicals involved in the reaction mechanism. Stability experiments demonstrated the satisfactory stability of the NiFe2O4 system. Furthermore, mineralization and toxicity analysis confirmed the superiority of the as-constructed system in phenol degradation. The proposed degradation mechanism provides valuable insights for further applications of this system in advanced wastewater treatment.
Article
Food Science & Technology
K. C. Amaro, C. C. Tadini
Summary: The study demonstrated that microwave treatment was an effective method for PME inactivation in orange juice, while maximizing AA retention. The optimal isothermal conditions for orange juice were determined based on the kinetics parameters.
LWT-FOOD SCIENCE AND TECHNOLOGY
(2021)
Article
Materials Science, Ceramics
Mingyi Guo, Guangxin Wang, Yunchao Zhao, Haitao Li, Kun Tang, Yibo Zhao, Kevin Burgess
Summary: The dispersibility of nano-zirconia powders was greatly influenced by the molecular weight of PEG, microwave hydrothermal time and temperature, and the concentration of TEOA. Under optimized conditions, the prepared nano-ZrO2 powder exhibited good crystallinity and crystal forms, consisting mostly of tetrahedral, spherically shaped, highly homogeneous, and well-dispersed 20-30 nm particles.
CERAMICS INTERNATIONAL
(2021)
Article
Engineering, Environmental
Jie Zhang, Lirong Tan, Peter-Leon Hagedoorn, Ruiqi Wang, Li Wen, Siwei Wu, Xuemei Tan, Hui Xu, Xing Zhou
Summary: This study introduces a novel hybrid technique of micro-nano bubbles assisted laccase (MNB-Lac) for the degradation of bisphenols in water. The results showed that MNB-Lac exhibited higher degradation efficiency and removal efficiency compared to other treatment methods. It was also successfully used for treating different types of bisphenols contaminants. This research could provide new insights into the enhancement of oxidizing enzyme performance using MNB technology.
JOURNAL OF WATER PROCESS ENGINEERING
(2022)
Review
Polymer Science
Ufana Riaz, Neetika Singh, Fathimath Rashnas Srambikal, Sumbul Fatima
Summary: This review focuses on the recent advancements in conducting polymeric hydrogels based on polyaniline (PANT) and polypyrrole (PPy). The synthesis strategies and common characterization techniques for PANI- and PPy-based hydrogels are discussed. The review also covers the current literature on biomedical and electrochemical applications of these materials.
Article
Chemistry, Multidisciplinary
Anurakshee Verma, Romana Parveen, Tooba Naz Shamsi, Azmat Ali Khan, Sadaf Fatima, Elham S. Aazam, Ufana Riaz
Summary: In this study, intercalation and in-situ polymerization of POPD within MMT were successfully achieved using sonochemical technique. The antimicrobial activity of MMT/POPD nanocomposites against four bacterial strains was examined, and the results indicated that the nanocomposites showed potential as antibacterial agents.
Article
Chemistry, Physical
Aleena Mir, Amit Kumar, Ufana Riaz
Summary: In this study, sodium alginate-based composite hydrogels using polyaniline (PANI), poly(o-phenylenediamine) (POPD), poly(1-naphthylamine) (PNA), and poly(vinylidene fluoride) (PVDF) were synthesized and characterized. The hydrogels were investigated for their spectral, morphological, and rheological properties. Metformin hydrochloride (MFH) was used as a model drug, and the release profiles were studied using intestinal fluid pH of 7.4. The incorporation of conducting polymers as crosslinking agents significantly affected the release behavior, which could be used to optimize and control the release of metformin hydrochloride.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Materials Science, Multidisciplinary
Elham S. Aazam, Naeem Akhtar, Waleed Ahmed El-Said
Summary: A novel bioinspired material, NDA@BM-ZIF, has been designed and fabricated for fuel cell applications. It exhibits excellent electrocatalytic performance with high half wave potential value and high tolerance against methanol poisoning. This material provides more O2 adsorption sites and facilitates the kinetics of the oxygen reduction reaction.
MATERIALS CHEMISTRY AND PHYSICS
(2023)
Article
Polymer Science
Jannatun Zia, Mohd Riyazuddin, Shaila Jackson, Darlene K. Taylor, Ufana Riaz
Summary: The synthesis of nanocomposites of beta-cyclodextrin (beta-CD) with polyaniline (PANI) and polypyrrole (PPy) to design core-shell nanocomposites was reported in this study. The spectral, morphological, and thermal characteristics of the synthesized nanocomposites were investigated. The incorporation of PANI and PPy in beta-CD was confirmed by IR spectra, while UV-visible spectra confirmed the polaronic state of conducting polymers in the nanocomposites. SEM analysis revealed the core-shell like morphology of the nanocomposites. In vitro drug release studies using ciprofloxacin (CIP) showed sustained release behavior of the nanocomposites, indicating their potential as effective antibiotic drug delivery vehicles.
Article
Materials Science, Multidisciplinary
Ufana Riaz, Nuzhat Nabi, Faith R. Nwanze, Fei Yan
Summary: This study for the first time reports the modification of aniline with alanine using ultrasound-assisted polymerization. The formation of Ala-incorporated polyaniline (PANI) was confirmed by various analyses. The binding affinity of Ala/PANI towards BSA and HSA was found to be good, with hydrogen bonding and Van der Waal's forces playing a significant role.
Article
Chemistry, Physical
Ishfaq Ahmad Rather, Ufana Riaz, Rashid Ali
Summary: UV-vis spectroscopy and TD-DFT calculations were used to investigate the anion binding of meso-substituted one-walled phthalimide-based calix[4]pyrrole (m-PC4P, 6) in acetonitrile. The results showed that m-PC4P (6) exhibited higher anion binding affinities compared to the parent C4P system, possibly due to additional weak CH-anion interactions besides four NH-hydrogen bonds of the C4P framework. The binding affinity decreased with the increase in halide size from fluoride to iodide, and m-PC4P (6) showed better binding with nitrate anion compared to simple C4P (1).
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Multidisciplinary Sciences
Ufana Riaz, Shayista Gaffar, Kristen Hauser, Fei Yan
Summary: This study presents a facile synthesis of CuFe2O4 nanoparticles and their formulation as nanohybrids with polythiophene (PTh). The structural and morphological properties were characterized using FT-IR, XRD, SEM-EDS, and UV-Vis spectroscopy. The nanohybrids exhibited a decrease in band gap with increasing PTh loading. The nanohybrids were applied as photocatalysts for the degradation of diphenyl urea and polyethylene under visible light and microwave irradiation, with promising catalytic efficiency observed.
SCIENTIFIC REPORTS
(2023)
Article
Chemistry, Physical
Shayista Gaffar, Aleena Mir, Amit Kumar, Javed Alam, Ufana Riaz
Summary: This study reports for the first time the microwave-assisted catalytic degradation of isoniazid drug using organic-inorganic hybrids of PTh decorated ZnFe2O4 nanoparticles. The nanohybrids demonstrated high efficiency in degrading the drug within a short period of time, and a tentative mechanism of degradation was proposed.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Biochemistry & Molecular Biology
Elham S. Aazam, Maryam A. Majrashi
Summary: This study reports the cytotoxicity and structural characterizations of a newly synthesized Schiff base and its metal complexes. The Cu(II) and Zn(II) complexes exhibited the highest activity against breast cancer cells.
Article
Chemistry, Multidisciplinary
Aaliyah Farooq, Javed Alam, Ufana Riaz
Summary: This study reports the use of Polypyrrole/Polythiophene Co-Oligomers as photocatalysts for the degradation of Bisphenol A. The results show that the organic photocatalysts achieved efficient degradation within 120 minutes, even for high concentrations of Bisphenol A.
Article
Chemistry, Physical
Ufana Riaz, Syed Marghoob Ashraf
Summary: This study reports the synthesis of a dye-incorporated o-phenylenediamine oligomer and analyzes its structure and electronic transitions. The results demonstrate that the dye-modified oligomer exhibits higher fluorescence intensity and can be used for near infra-red imaging. Density functional theory (DFT) studies predict the theoretical properties of the oligomer and suggest its potential application as a drug sensor.
ACS PHYSICAL CHEMISTRY AU
(2023)
Article
Chemistry, Multidisciplinary
Ufana Riaz, Aaliyah Farooq, Nuzhat Nabi, Faith R. Nwanze, Fei Yan
Summary: This study reports the synthesis and characterization of water-dispersible polypyrrole (WD-PPy) and polythiophene (WD-PTh) copolymers in different weight ratios using experimental and theoretical techniques. Spectroscopic characterization of the copolymers was conducted using experimental C-13-NMR, FTIR, and UV-visible studies, as well as theoretical FTIR and UV-visible studies. Furthermore, biophysical interaction studies with bovine serum albumin (BSA) and human serum albumin (HSA) were performed, revealing strong binding with potential applications in designing inhibitors and biosensors.
NEW JOURNAL OF CHEMISTRY
(2023)
Article
Polymer Science
Aaliyah Farooq, Nuzhat Nabi, Javed Alam, Ufana Riaz
Summary: Water-soluble polyfuran and polythiophene co-oligomers were synthesized and their biophysical interactions with bovine serum albumin and human serum albumin were studied. The interactions were found to be higher with human serum albumin, and were mediated through hydrogen bonding and pi-alkyl interaction. These co-oligomers showed high binding affinity towards human serum albumin, suggesting their potential use in protein sensors.
POLYMERS FOR ADVANCED TECHNOLOGIES
(2023)
Article
Environmental Sciences
Shayista Gaffar, Amit Kumar, Javed Alam, Ufana Riaz
Summary: In this study, CuFe2O4 and CuFe2O4/polyaniline (PANI) nanohybrids were used as photocatalysts for the degradation of TC-HCl. The nanohybrids showed superior photocatalytic performance compared to pristine CuFe2O4, with a maximum degradation rate of 86%. The degraded fragments were analyzed and a tentative degradation mechanism was proposed.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)