4.5 Article

FeNi doped porous carbon as an efficient catalyst for oxygen evolution reaction

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出版社

SPRINGER
DOI: 10.1007/s11705-020-1965-2

关键词

OER; polystyrene salt; porous carbon; FeNi alloy; p/n junction

资金

  1. National Natural Science Foundation of China [21421001, 21875118]
  2. 111 Project [B12015]

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Polymer-derived porous carbon was utilized as a support for iron and nickel species to create an efficient oxygen reduction reaction (OER) catalyst. By modifying the carbon with FeNi, a low overpotential for OER was achieved, comparable to that of the noble metal catalyst IrO2. This work represents a significant advancement in the development of low-cost, environmentally-friendly, and highly-efficient OER catalysts.
Polymer-derived porous carbon was used as a support of iron and nickel species with an objective to obtain an efficient oxygen reduction reaction (OER) catalyst. The surface features were extensively characterized using X-ray diffraction, X-ray photoelectron spectroscopy and high-resolution transmission electron microscopy. On FeNi-modified carbon the overpotential for OER was very low (280 mV) and comparable to that on noble metal catalyst IrO2. The electrochemical properties have been investigated to reveal the difference between the binary alloy- and single metal-doped carbons. This work demonstrates a significant step for the development of low-cost, environmentally-friendly and highly-efficient OER catalysts.

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